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375 W E Lamb Jr, W P Schleich, M O Scully, and C H Townes Laser physics: Quantum controversy in action Reviews of Modem Physics, 71(2):S263-S273, Centenary 1999 376 W E Lamb Jr and M O Scully The photoelectric effect without photons In Polarisation, Matiere, et Rayonnement: Volume Jubilaire en l'Honneur d'Alfred Kastler, pp 363-369 La Societe Fran aise de Physique, Presses Universitaires de France, Paris, 1969 377 S K Lamoreaux Resource letter cf-l: Casimir force American Journal of Physics, 67(1O):850-861,October 1999 378 C Lamprecht, M K Olsen, M Collett, and H Ritsch Excess-noise-enhanced parametric down conversion Physical Review A, 64(3):033811, September 2001 379 C Lamprecht, M K Olsen, P D Drummond, and H Ritsch Positive-P and Wigner representations for quantum-optical systems with non orthogonal modes Physical Review A, 65(5):053813, May 2002 380 C Lamprecht and H Ritsch Quantized atom-field dynamics in unstable cavities.



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3-147

Physical Review Letters, 82(19):3787-3790, May 10, 1999 381 C Lamprecht and H Ritsch Unexpected role of excess noise in spontaneous emission Physical Review A, 65(2):023803, February 2002 382 C Lamprecht and H Ritsch Theory of excess noise in unstable resonator lasers Physical Review A, 66(5):053808, November 2002 383 C Lanczos Die Funktionentheoretischen Beziehungen der Maxwellschen Aethergleichungen: Ein Beitrag zur Relativiti1ts- und Elektronentheorie Verlagsbuchhandlung Josef Nemeth, Budapest, 1919 This is Lanczos's PhD dissertation (from Szeged University) It was reprinted in [145], volume VI, pp A-I to A-82 384 C Lanczos Die Tensoranalytischen Beziehungen der Diracschen Gleichung Zeitschrift for Physik, 57:447-493, 1929 Reprinted and translated in [145], volume III, pp 2-1133 to 2-1225 385 C Lanczos The Poisson bracket In A Salam and E P Wigner, editors, Aspects of Quantum Theory, pp 169-178 Cambridge University Press, Cambridge, 1972 386 C Lanczos The Variational Principles of Mechanics.





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probably a consequence of the transfer reaction (Eq. 3-148) being faster than the reaction in Eq. 3-146; that is, phenols scavenge peroxy radicals more effectively than do alkyl (carbon) radicals. Most phenols have y values close to 3, indicating that the peroxy radical formed in Eq. 3-148 reacts with propagating radicals (carbon and/or peroxy). This probably involves

3-148

Dover, New York, 4th edition, 1986 387 L Landau and R Peierls Quantenelektrodynamik im Konfigurationsraum Zeitschriftfor Physik, 62: 188-200, 1930 An English translation of this paper appears in Selected Scientific Papers of Sir Rudolf Peierls with Commentary, edited by.

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the propagating radical adding to the ring or abstracting hydrogen from a methyl group on the ring for methyl-substituted phenols. In contrast to phenol and substituted phenols, di- and trihydroxybenzenes such as hydroquinone, t-butylcatechol (1,2-dihydroxy-4-t-butylbenzene), and pyrogallol (1,2,3-trihydroxybenzene) are generally stronger retarders or inhibitors. The mechanism for their action may involve oxidation by adventitious oxygen to quinones instead of or in addition to the reactions described by Eqs. 3-147 and 3-148 [Georgieff, 1965]. Substituted anilines behave similarly to the phenols, although relatively little data are available. N-phenyl-N0 -isopropyl-p-phenylenediamine is an ef cient inhibitor in the polymerization of styrene only in the presence of oxygen [Winkler and Nauman, 1988]. However, the effectiveness of phenothiazine as an inhibitor in the polymerization of acrylic acid is independent of oxygen [Levy, 1985]. Aromatic nitro compounds terminate propagating chains, with a greater effect for more reactive and electron-rich radicals. Nitro compounds inhibit vinyl acetate, retard styrene, but have little effect on methyl acrylate and methyl methacrylate [Eastmond, 1976a,b,c; Schulz, 1947; Tabata et al., 1964]. The effectiveness increases with the number of nitro groups on the ring. 1,3,5-Trinitrobenzene has z values that are 1 2 orders of magnitude greater than nitrobenzene (Table 3-8). The mechanism of radical termination involves attack on both the aromatic ring and the nitro group. Attack on the aromatic ring yields radical XXXII, which reacts with another propagating radical (Eq. 3-149) or with monomer (Eq. 3-150).

8~ /

Show Markup button, 79 Shrink Font button, 44 slide layout, 131 slide objects, 143 slide shows, 147 149 Slide Sorter view (PowerPoint), 129, 145 slides adding objects to, 140 141 text/text boxes, 132, 139 deleting, 145 editing text, 133 hiding, 145 inserting, 130 magnification of, 129 reorganising, 144 145 Slides view (PowerPoint), 128 sorting, 106 107, 172 173 Special Characters tab, 43 Spelling & Grammar button, 74 Start menu, 4 styles, 56 57, 70, 71 Symbol button, 42 Synchronous Scrolling button, 25

NO2 + Mn H 3-149

{E2 + :8 2}

3-150

a!( -k)][a!(k) - a s( -k)]

Attack on the nitro group leads to radical XXXIII, which can react with other propagating O radicals (Eqs. 3-151 and 3-152) or cleave to nitrosobenzene and Mn radical (Eq. 3-153). Both nitrosobenzene and Mn can react with and terminate other propagating radicals. O

n~k 2: {[as(k) -

3-151

+ [&s(k) + a!( -k)][a!(k) + as( -k)]}

3-152 3-153

2: {a!c -k)as( -k) + as (k)a!(k) }

The reaction in Eq. 3-152 probably also involves disproportionation hydrogen atom transfer from the propagating radical to XXXII. Overall, one observes high y values up to 5 or 6 for 1,3,5-trinitrobenzene. Oxidants such as FeCl3 and CuCl2 are strong inhibitors, terminating radicals by the reactions [Billingham et al., 1980; Chetia and Dass, 1976; Matsuo et al., 1977]:

Reductants also terminate propagating radicals, but much less effectively. Other inhibitors include sulfur, carbon, aromatic azo compounds, and chlorophosphines [Nigenda et al., 1977; Uemura et al., 1977].

2: {a!(k)as(k) + as(k)al(k)}.

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