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pray to many pitfalls. The latter is often difficult to follow, leaving readers when doing practical calculations to work out for themselves how to connect to their real needs the abstract theorems proved. This appendix intends to be different. Here we present a number of nonrigorous physicist-type derivations that connect together many key results regarding delta functions, step functions, principal parts, and their various representations. But rather than presenting only a superficial treatment, our aim is to guide the reader through a number of subtleties and pitfalls that often arise in real calculations involving these generalized "functions." This appendix is a "bag of tools" that, to the best of our knowledge, could so far only be found scattered in the literature.



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Let us start with the ugly. Even though it was Dirac [159] who introduced the now famous notation 8(x) and who stated some of the most important properties of the delta junction, the idea of a delta function is much older than Dirac. At the end of the nineteenth century, Oliver Heaviside was using delta functions in his operational calculus [282, 283, 419], which later became a standard technique in electrical engineering. It might be no coincidence that Dirac, who popularized the delta function in physics, was also an electrical engineer by training. But long before, Heaviside, Cauchy, Poisson, Kirchhoff, Helmholtz, and Hermite had already used a delta function. I According to Liitzen [420], the idea behind the delta function can even be traced back to Ancient Greece, but a mathematical expression describing it probably appeared for the first time in Fourier's 1822 book Theorie anaLytique de La chaleur. 2 The main feature of the delta function is the sampling or sifting property, where for an arbitrary continuous3 function f(x),

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The former gives a mixture of the block copolymer with the two homopolymers since the polymer radicals combine randomly. The latter yields the block copolymer along with the homopolymer of M1 . Treatment of polyisobutylene (which contains terminal double bonds) with ozone followed by thermolysis produces polymeric radicals. Isobutylene styrene block copolymer is formed when thermolysis is performed in the presence of styrene, but the process is not ef cient because polystyrene and polyisobutylene homopolymers constitute more than half of the product [Cunliffe et al., 2001]. The synthesis of special initiators is another route to block copolymers. Reaction of XXXVI with an HO-terminated polyester or polyether yields a polymeric azonitrile, which initiates polymerization of a monomer such as styrene [Laverty and Gardland, 1977; Walz and Heitz, 1978].

9-11

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The use of a polymer as a carrier or support for some component of a reaction system is discussed in the remainder of this chapter. Three classes of polymer supports are encountered polymer reagents, polymer catalysts, and polymer substrates [Kirschning et al., 2001; Sherrington, 2001]. Polymers that serve as reagents, catalysts, or substrates are functional polymers; that is, they contain a functional group that performs a particular chemical function. The term reactive polymer is also used. A polymer reagent is a polymer containing a functional group that acts as the reagent to bring about a chemical transformation on some small (i.e., low-molecular-weight) molecule. A polymer substrate has an attached molecule on which some transformation is carried out using a small-molecule reagent. A polymer catalyst contains a group that performs a catalytic function in some reaction usually a reaction between small molecules.

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There are two general approaches to the synthesis of a polymer reagent, catalyst, or substrate [Hodge, 1978; Mathur et al., 1980; Neckers, 1978; Sherrington, 1980, 1988]. In the functionalization of polymer approach the required functional group, which is to perform the reagent, catalyst, or substrate function, is attached to a readily available polymer by an appropriate reaction. The attachment is usually through a covalent bond, but ionic bonding has also been employed. In the functionalization of monomer approach an appropriate monomer with the desired functional group is synthesized and then polymerized or copolymerized.

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9-11a-1

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This approach can be illustrated by describing the preparation of the polymer rhodium catalyst II (Sec. 9-1g). The synthesis is based on a nucleophilic substitution reaction of chloromethylated polystyrene [Grubbs and Kroll, 1971]:

To be "mathematically correct," the d.elta function is not really a function because it does not map numbers into numbers but rather is a distribution that maps functions into numbers. It can, however, be seen as a limit of certain ordinary functions. Physics textbooks frequently mention the rectangular barrier, the sinc function, the Lorentzian, and the Gaussian as functions that become a delta function when we keep their area constant but decrease their widths to zero. In practical calculations, it is important to know which functions become delta functions this way. In this section we present simple physicist-type derivations that connect the most common representations of

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