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c# code to save excel file as pdf: Excel file to PDF...is there a way? | The ASP.NET Forums



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8-4 TRADITIONAL ZIEGLER NATTA POLYMERIZATION OF NONPOLAR ALKENE MONOMERS Since the original discoveries of Ziegler and Natta, there have been many hundreds of different combinations of transition and group 1 III metal components, often together with an added electron donor, studied for use in alkene polymerizations. The resulting initiators exhibit a range of behaviors in terms of activity (reactivity) and stereoselectivity. Activity is often expressed as kg polymer formed per gram (or mole) of transition metal (or transition metal compound). Sometimes it is given as the activity per hour and sometimes it is given as the activity per polymerization run. The term productivity is often used as a synonym for activity. Modi cation of an initiator system to increase activity has often come at the expense of stereoselectivity. The great utility of the Ziegler Natta initiator system is the ability to change one or another of the components, or to add additional components (usually electron donors) to achieve very high stereoselectivity with high activity. The choice of the initiator components evolved in an empirical manner because of a less-than-complete understanding of the detailed structure of these initiators and the mechanism of their stereoselectivity. 8-4a Historical Development of Ziegler Natta Initiators



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Thus, in the steady state, the evolution operator is a product of Glauber displacement operators (the Glauber displacement operator was introduced in 4), lim UI(t)





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Various mechanisms have been proposed to explain the stereoselectivity of Ziegler Natta initiators [Boor, 1979; Carrick, 1973; Corradini et al, 1989; Cossee, 1967; Ketley, 1967a,b; Tait and Watkins, 1989; Zambelli and Tosi, 1974] Most mechanisms contain considerable details that distinguish them from each other but usually cannot be veri ed In this section the mechanistic features of Ziegler Natta polymerizations are considered with emphasis on those features that hold for most initiator systems The major interest will be on the titanium aluminum systems for isoselective polymerization, more speci cally, TiCl3 with Al(C2 H5 )2 Cl and TiCl4 with Al(C2 H5 )3 probably the most widely studied systems, and certainly the most important systems for industrial polymerizations Before proceeding with the mechanistic consideration it is useful to review the evolution of the Ti-Al initiator system for industrial applications.

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The original initiator used by Ziegler for ethylene polymerization was obtained in situ as a precipitate on mixing the components TiCl4 and Al(C2 H5 )3 in a hydrocarbon solvent The mixture was used directly for initiating polymerization Natta, recognizing that the major product of the reaction was b-TiCl3 (brown in color), explored various methods of preforming it outside the polymerization system, for example, by reduction of TiCl4 with hydrogen, aluminum, and various alkylaluminum compounds The stereoselectivity of these early initiator systems was low with isotactic indices of only 20 40% for polypropene The isotactic index, a measure of the isotactic content of a polymer, is the percentage of the sample insoluble in a hydrocarbon solvent such as boiling n-heptane This is not as informative a technique as high-resolution NMR since insoluble molecules may contain some syndiotactic and atactic sequences and soluble molecules may contain some isotactic sequences.

It does, however, give a simple measure of isotacticity that is usually within about 10% of the value obtained from NMR, especially for highly isotactic samples..

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There was a dramatic increase in stereoselectivity when the a-, d-, or g-crystalline form of TiCl3 (all violet in color) was used directly The early generations of industrial processes used TiCl3 together with Al(C2 H5 )3 and/or Al(C2 H5 )2 Cl Over a two decade period starting in the late 1950s, the isotactic indices for polypropene increased to the low 90 percentile range The initiator activity was enhanced by various ball milling and heat treatments of the initiator components before and after mixing Ball milling involves mechanical grinding and not only increases surface area but also facilitiates reactions between the initiator components However, the activities were too low to allow the polymer products to be used without puri cation (by treatment with base or acid) to remove the residual metals, a process referred to as deashing.

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Steps to convert excel document to PDF programmatically:
Steps to convert excel document to PDF programmatically:

how to save excel file as pdf using c#

How to convert Entire Excel Workbook into PDf in C# - C# Corner
Hi All, My below code is working fine for convert excel document to PDF but its not Convert Entire Excel Doc Some Large excel Content Are cut ...












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