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For moderately crystalline or oriented polymers, there is the possibility of achieving the required orientation by mechanical stretching Liquid crystal polymers would be especially advantageous for electrical conduction because of the high degree of chain orientation that can be achieved A problem encountered with some doped polymers is a lack of stability These materials are either oxidants or reductants relative to other compounds, especially water and oxygen The rst polymer shown to have conducting behavior was polyacetylene (Sec 8-6c) Some of the polymers investigated as heat-resistant polymers have conjugated p-electron systems and offer potential as conducting polymers Among the polymers we have covered up to this point, poly(p-phenylene sul de), polyquinoline, and polyquinoxaline have shown some promise as conducting polymers We now consider a number of other polymers which are more promising as conducting polymers..



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Convert Image to PDF in C#, VB.NET. Step1: Use C#/VB.NET to create a PDF document. In this step, you need to create a new PDF file first, then, add a section in the newly built PDF, at last, add a page in the section that you just added. Step2: Load an image to PDF and set image location. Step3: Save the image to PDF ...

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2-14j-1 Oxidative Polymerization of Aniline Passage of current through a solution results in oxidation (electron loss) at the anode and reduction (electron gain) at the cathode. This process is referred to as electrochemical polymerization when polymer is formed. Polyaniline [IUPAC: poly(imino-1,4-phenylene)] is obtained by the oxidative polymerization of aniline in aqueous HCl solution, either by electrochemical polymerization or by using a chemical oxidant such as ammonium persulfate, (NH4)2S2O8 [Macdiarmid et al., 1987; Mav and Zignon, 2001; Tejskal and Gilbert, 2002; Wei, 2001; Wei et al., 1989, 1990]. Polymerization proceeds by a chain polymerization mechanism, but is included in this section on conjugated polymers for convenience. Initiation involves a loss of two electrons and one proton from aniline to form a nitrenium ion (Eq. 2-223), which subsequently attacks aniline by electrophilic substitution (Eq. 2-224). Propagation proceeds in a similar manner by oxidation of the primary amine end of a growing polymer chain (Eq. 2-225) followed by electrophilic substitution (Eq. 2-226). The process has been referred to as reactivation chain polymerization to highlight the fact that the chain end formed after each addition of aniline must be reactivated to the nitrenium

-YI\.E(x,O,z,t) =0 xI\.E(L,y,z,t) = 0,

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By default, when you type text in a Word 2010 document, the program uses 11-point Calibri font. You can change the text font, size and colour to alter the appearance of text in a document. For example, you might change the font, size, and colour of your document s title text to emphasise it. You can also change the font that Word 2010 applies by default.

2e

-x I\. E(O, y, z, t) =

2-223

Using the ansatz X = xfx(x, y, z)

2-224

fAx, y, z) = N x cos kxx sin kyy sin kzz, fy(x, y, z) = Ny sin kxx cos kyysin kzz, fz(x, y, z) = N z sinkxxsin kyy cos kzz show that these boundary conditions and (A.tO) imply that kx = n x 7r/L, ky = n y7r/ L, and kz = n z7r/l, wheren x, ny, andn z are integers. Now use the divergence condition V X= 0 to show that if anyone of k x , ky, and kz vanishes, there is only one polarization, but otherwise there are two polarizations. See Sec. to.2 of [537] for a nice pedagogical account of the modes in a box. 2.10 Use the well-known delta function identity

2e

kzl,~.L = 7r,

2-225

0 to obtain (2.190) from (2.189).

2-226

ion by oxidation and proton loss. The product formed directly from oxidative polymerization is not the neutral structure shown in Eq. 2-226. The polymer has the positively charged structure LVI, which is referred to as emeraldine salt, and it is the conducting form of polyaniline. Other forms of polyaniline can be obtained after synthesis by varying the applied voltage and pH [Sherman et al., 1994]. Polyaniline offers considerable promise for commercialization. There have been extensive studies using substituted anilines alone or in copolymerization with aniline to alter the conducting and optoelectronic properties of the polymer as well as their solubility characteristics.

2.11 Derive the expressions (2.198) and (2.199) for the positive-frequency part of the quantized magnetic fields from the corresponding expressions (2.187) and (2.197) for the electric fields using Faraday's law. The calculation becomes qui te simple, once you notice that the positive-frequency components (2.187) and (2.197) of the electric

Click the Home tab on the Ribbon. Click the Font Size Click a size. Word applies the font size to the text, in this case, 48 points.

Oxidative polymerizations of thiophene and pyrrole and their derivatives are also under study to obtain polymers with conducting and optoelectronic properties [Jin et al., 2000;

{(xn' Ecav) (X3' Ecav)

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