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hexagonal arrangements of the microspheres were obtained from the corresponding templates, as shown in Fig. 9.19 (right-hand side), though there are a few defects present and also a multilayered area. The hexagonal arrangement of colloidal crystals on the template had an approximately unity structure without being multidomain, compared with the self-assembled arrangement on the at lm, as shown in the small image in Fig. 9.19b. The combination of both the arrangement on the template and the photoinduced immobilization provides an excellent method for fabricating large area 2-D colloidal crystals with controlled lattices and low defect densities. Finally, the area-selective photoimmobilization of 2-D arrays of colloidal spheres on templates formed in azobenzene-containing polymer lms was demonstrated. Area-selective photoimmobilization was combined with the process whereby microspheres can be arranged on a template. Similar to the processes described earlier, area-selective photoimmobilization was performed by setting the template containing the array of spheres onto a moveable sample stage. After an ultrasonic wash, the 2-D colloidal crystals were examined. Figure 9.20 shows waveguide-type 2-D crystals with a hexagonal arrangement. Several other types of patterns were also examined, such as bending waveguides and cross-type waveguides. To conclude, the authors have succeeded in forming 2-D photonic crystal slabs that include deliberately introduced defects or waveguides. This was accomplished by a newly proposed method comprising two processes, the arrangement and the area-selective immobilization of microspheres. These processes were made possible by utilizing two different photoresponsive properties of azobenzene-containing polymers; namely, photodeformation and photoimmobilization.



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However operator maintenance practices affecting system reliability and operating practices also have a signi cant effect Operators with larger eets of the same aircraft-engine model have an advantage as they can more quickly generate the in-service engine hours necessary to secure more stringent ETOPS approvals For example a large airline operator with a eet of 50 aircraft ying 4000 hours per year would establish an annual useage of 400 000 engine hours; 4 IFSDs or less in a 12 month operating period.

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Among a number of photochromic materials, azobenzene derivatives have a distinguished property that induces a spatially extended change in form because of





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Let us now take a look at the code The first half the program is almost identical to TCPServerjava As with TCPServerjava, we import the javaio and javanet packages In addition to these two packages we also import the javautil package, which contains the StringTokenizer class, which is used for parsing HTTP request messages Looking now at the lines within the class WebServer, we define two string objects: String requestMessageLine; String fileName; The object requestMessageLine is a string that will contain the first line in the HTTP request message The object fileName is a string that will contain the file name of the requested file The next set of commands is identical to the corresponding set of commands in TCPServerjava ServerSocket listenSocket = new ServerSocket(6789); Socket connectionSocket = listenSocketaccept(); BufferedReader inFromClient = new BufferedReader(new InputStreamReader(connectionSocket getInputStream())); DataOutputStream outToClient = new DataOutputStream(connectionSocketgetOutputStream()); Two socket-like objects are created The first of these objects is listenSocket, which is of type ServerSocket The object listenSocket is created by the server program before receiving a request for a TCP connection from a client It listens at port 6789, and waits for a request from some client to establish a TCP connection When a request for a connection arrives, the accept() method of listenSocket creates a new object, connectionSocket, of type Socket Next two streams are created: the BufferedReader inFromClient and the DataOutputStream outToClient The HTTP request message comes from the network, through connectionSocket and into inFromClient; the HTTP response message goes into outToClient, through connectionSocket and into the network The remaining

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their geometric isomerization. The SRG-related investigations inspired by the Natansohn and Tripathy groups take an advantage of this characteristic property effectively. The authors have introduced the principles of a newly created photoimmobilization technology using photoresponsive azopolymers and reviewed its application to the fabrication of immunochips and the arrangement of microspheres. Although there have been a number of investigations into the photoinduced functionality of azopolymers, further interesting problems remain to be solved from the viewpoint of basic research. The authors consider two important factors in their approach: the deformation process that is induced by interaction between the microobjects and the azopolymer surface and the immobilization process that resulted from the deformation process. In the rst case, a novel aspect should be added, such as surface energy, radiation force, and intermolecular force as the moving force. The established knowledge accumulated by investigations concerning SRG, photoinduced orientation, and photoisomerization is obviously important to understand the mechanism. The photoresponse process would be controlled by the interaction, and this interaction would be affected by photoresponse conversely. In the latter case, the research eld could enlarge by considering how to use the immobilized surface such as biochip and bioreactor. In particular, the interaction from the position of adsorption in biological engineering should also be reconsidered. The interaction concerning the adsorption would involve controlling the arrangement and orientation of microobjects. Not only the behavior and application of azopolymer by itself but also the relevant interaction with microobjects on the surface should be considered. The authors believe that there is further potential to develop this technique more widely; for instance, applications involving biological molecules are an intriguing eld with high potential for future growth, including aspects of molecular orientation and the formation of organized structures. This novel approach would serve as a steppingstone to further development.

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