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2 shows the reaction scheme to prepare amphiphilic azo copolymers through postpolymerization Schotten Baumann reaction In this case, a very reactive precursor polymer, poly(acryloyl chloride) (PAC), is prepared through the radical polymerization of acryloyl chloride Various azo polymers can be obtained through the Schotten Baumann reactions between the precursor polymer and azo compounds containing reactive groups such as HO groups After the reaction, unreacted acyl groups were transformed to carboxyl groups through hydrolysis According to the spectral features and isomerization behavior, the aromatic azo compounds have been classi ed as azobenzene type, aminoazobenzene type, and pseudostilbene type (Rau, 1990) For the azobenzene-type molecules, the p p* transition band (320 nm) appears at shorter wavelength than n p* transition band (430 nm) (Kumar and Neckers, 1989) The cis-to-trans isomerization is relatively slow at room temperature, and the existence of cis isomers can be easily identi ed by the spectroscopic method.



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The simplest firewall consists of a packet filter More sophisticated firewalls consist of combinations of packet filters and application gateways

The Thermal and Energy Management Module (T/EMM) combines the function of a traditional APU, emergency power unit and environmental control

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For aminoazobenzene-type and pseudostilbene-type molecules, the p p* and n p* transition bands are overlapped The cis state of the molecules is unstable, which relaxes back to the trans state quickly According to the de nition, the azo polymers given in Figs 51 and 52 can be assigned to contain pseudostilbene-type and azobenzene-type chromophores, respectively..





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An organization typically has a router that connects its internal network to its ISP (and hence to the Internet) All traffic leaving and entering the internal network passes through this router Most router manufacturers provide options for filtering; when these options are turned on, the router becomes a filter in addition to a router As the name implies, a filter lets some datagrams pass through the router and filters out other datagrams Filtering decisions are typically based on:

COOH (BP-AZ- CA)

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You might be wondering why a packet doesn't just keep the same VC number on each of the links along its route The answer to this question is twofold First, by replacing the number from link to link, the length of the VC field is reduced Second, and more importantly, by permitting a different VC number for each link along the path of the VC, a network management function is simplified Specifically, with the multiple VC numbers, each link in the path can choose a VC number independently of what the other links in the path chose If a common number were required for all links along the path, the switches would have to exchange and process a substantial number of messages to agree on the VC number to be used for a connection If a network employs virtual circuits, then the network's switches must maintain state information for the ongoing connections Specifically, each time a new connection is established across a switch, a new connection entry must be added to the switch's VC-number translation table; and each time a connection is released, an entry must be removed from the table Note that even if there is no VC number translation, it is still necessary to maintain state information that associates VC numbers to interface numbers The issue of whether or not a switch or router maintains state information for each ongoing connection is a crucial one - one which we return to shortly below

Figure 5.1. Chemical structure and synthetic route of some epoxy-based azo polymers prepared by the postpolymerization azo coupling reaction.

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(PAC)

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