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Physical Review Letters, 59(17):1899-1902, October 26, 1987 82 M Brune, F Schmidt-Kaler, A Maali, J Dreyer, E Hagley, J M Raimond, and S Haroche Quantum Rabi oscillation: A direct test of field quantization in a cavity Physical Review Letters, 76( 11): 1800-1803, March 11, 1996..

PDI 2 a 2 2 b2 g2 =2a 2-115

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83. E. Buks and M. L. Roukes. Casimir force changes sign. Nature, 419:119-120, September 12, 2002. 84. V. S. Buldyrev and E. E. Fradkin. Integral equations for open resonators. Optics and Spectroscopy USSR,17(4):314-320, 1964. This is an English translation of the Russian original: V. S. Buldyrev and E. E. Fradkin, Optika i Spectroskopiya 17(4):583-596,1964. 85. P. Bush. The time energy uncertainty relation. In J. G. Muga, R. Sala Mayato, and I. L. Egusquiza, editors, Time in Quantum Mechanics, pp. 69-98. SpringerVerlag, Berlin, 2002. Also available at the LANL site (http://xxx.lanl.govl)under the eprint reference quant-phl0105049. 86. M. G. Calkin, D. Kiang, and Y. Nogami. Proper treatment of the delta function potential in the one-dimensional Dirac equation. American Journal of Physics, 55(8):737-739, August 1987. 87. L. Campbell. The Life ofJames Clerk Maxwell with a Selectionfrom His Correspondence and Occasional Writings and a Sketch ofHis Contributions to Science. Macmillan, London, August 1882. VIII contains a reprint of Maxwell's essay on analogies in nature (Analogies: Are there real analogies in nature ) read on February 1856 to the "Apostles" club at Cambridge. Maxwell saw William Thomson's (Lord Kelvin) work on the heat flow analogy to electrostatics as the invention of an altogether new method for discovery in physics, which he (Maxwell) called the method of "physical analogy." Campbell's book is also available online at http://www.hrshowcase.comimaxweillpreface.htmi. 88. H. Carmichael. An Open Systems Approach to Quantum Optics, volume 18 of Lecture Notes in Physics. Springer-Verlag. Berlin. 1993. 89. P. Carruthers and M. M. Nieto. Phase and angle variables in quantum mechanics. Reviews of Modem Physics. 40(2):411-440. April 1968.





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Equation 2-115 yields PDI as a function of conversion in a straightforward manner without having to solve differential equations to obtain the number- and weight-average molecular weight distributions. One need only take a set of b values and then calculate the corresponding g, a, and PDI values from Eqs. 2-114 and 2-115. The limit of PDI at complete conversion pA 1; a 0 is 2 as for the Flory distribution. The Macosko-Miller method has also been applied to other polymerizations, including the A plus A0 0 system. In B B addition to being a simpler method for obtaining the average properties compared to the Flory and similar methods, it more readily allows an evaluation of the effect of various reaction parameters such as unequal group reactivity or nonstoichiometric amounts of reactants on M n , M w , and PDI (see Sec. 2-7e).

90. W. B. Case. The field oscillator approach to classical electrodynamics. American Journal of Physics, 68(9):800-811, September 2000.

2-7e 2-7e-1

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91. H. B. G. Casimir. On the attraction between two perfectly conducting plates. Proceedings of the Koninklijke Nederlandse Akademie van Wetenschappen, 51(7): 793-795,1948. 92. H. B. G. Casimir. Haphazard Reality. Harper & Row, New York, 1983. 93. P. C. Caussee. L'Album du marin. Charpentier, Nantes, 1836. 94. C. M. Caves. Amplitude and phase in quantum optics. In F. Haake, L. M. Narducci, and D. Walls, editors, Coherence, Cooperation and Fluctuations, pp. 192-205. Cambridge University Press. Cambridge. 1986.

The molecular weight distribution and/or PDI has been described for several cases where the assumption of equal reactivity of functional groups is not valid. Unequal reactivity is easily B handled by the Macosko Miller method. For the A B B0 0 system described in A B the previous section, we simply rede ne the relationship between b and g by

and B(r)

g bs 2-47

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