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Some special reaction with a particularly designed route can be used to synthesize azo BCs. For instance, a series of poly(vinyl ether)-based azo LCBCs were synthesized by using living cationic polymerization and free-radical polymerization techniques (Serhatli and Serhatli, 1998). As shown in Scheme 12.8, 4.4uazobis(4-cyano pentanol) (ACP) was used to couple quantitatively two wellde ned polymers of LC living poly(vinyl ether), initiated by the methyl tri uoromethane sulfonate/tetrahydrothiophene system. Then the ACP in the main chain was thermally decomposed to produce polymeric radical, which was used to initiate the polymerization of MMA or styrene to obtain PMMA-based or PS-based azo BCs (AB or ABA types).



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file:///D|/Downloads/Livros/computa o/Computer%20Newn%20Approach%20Featuring%20the%20Internet/mcasthtm (20 of 20)20/11/2004 15:52:28

49 Summary

Azo BCs are multifunctional polymeric materials, which combine the photochemical properties of azo polymers and the microphase separation of functional BCs. On the one hand, the azo block and the other segments cannot be miscible, unlike statistically random copolymers in which the azo moieties are dispersed homogeneously over the whole bulk lms. On the other hand, the azo BCs cannot form macroscopically phase-separated structures like polymer blends (Bates and Fredrichson, 1999). The azo moiety may play the roles of both mesogen and photosensitive chromophore, when it is attached to the polymer main chain by a longer soft spacer. Both the photoisomerization and the phase transition of the LC to the isotropic phase are involved in the process of microphase separation because of

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Scheme 12.8 Preparation of azo BCs by using living cationic polymerization and free-radical polymerization techniques. Source: Reproduced from Serhatli and Serhatli, 1998.

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Design Considerations Although the aircraft is ostensibly a sealed vessel, there are many opportunities for moisture to enter the aircraft and its equipment. The aircraft exterior will be subject to rain when it is parked in the open and seals must be provided to prevent ingress when the aircraft is closed up In ight rain is experienced as driving rain and may have an erosive effect on externally mounted items Military pilots often taxy with the canopy open and water will pool on the cockpit oor unless drains are provided which do not compromise pressurisation Rapid descent from high altitude may cause mist or excessive humidity to form Operation in tropical climates with high relative humidity may lead to moisture or free water in the aircraft Equipment installed in the undercarriage bays will be subject to contaminated water from the rotating wheel as the gear is stowed, and may also be subject to spray during take-off and landing All equipment must be provided with drain holes of suitable size to allow drainage Test Considerations MIL-STD-810: Method 506 Rain to determine: The effectiveness of protective covers, cases, seals in preventing penetration of water The capability of the materiel to satisfy its performance requirements during and after exposure to water

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