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PDF to MS Word DOC or DOCX Conversion in .NET Applications ...
14 Jun 2013 ... This technical tip shows how to convert PDF file to DOC or DOCX format. Aspose. Pdf for .NET is flexible and supports a wide variety of ...

The kinetic chain length n of a radical chain polymerization is de ned as the average number of monomer molecules consumed (polymerized) per each radical, which initiates a polymer chain. This quantity will obviously be given by the ratio of the polymerization rate to the initiation rate or to the termination rate, since the latter two rates are equal.

(7.153)

1 2 3 4

n Rp Rp Ri Rt 3-95

+ zl{w)8{w -

n kp M 2kt M 3-96

(7.154) (7.155)

3-97

Substituting (7.154) and (7.155) in (7.149), we get the following equation involving Zl{W):



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For polymerization initiated by the thermal homolysis of an initiator, Eq. 3-22 is substituted into Eq. 3-97 to yield

2wG2 (w -w c)al{w) = _C- a1 {w) dvla{vW w + Wc -00 + Ga{w)zl{W).

n kp M 2 fkd kt I 1=2 3-98

(7.156)

The number-average degree of polymerization X n , de ned as the average number of monomer molecules contained in a polymer molecule, is related to the kinetic chain length. If the propagating radicals terminate by coupling (Eq. 3-16a), a dead polymer molecule is composed of two kinetic chain lengths and

a{w)zl{W)

For termination by disproportionation (Eq. 3-16b) the kinetic chain length is synonymous with the number-average degree of polymerization

Click the File tab. Click New. Click Blank database. Type a name for the database in the File Name field.





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Jul 13, 2015 · Convert PDF to Word Using C# The first step will be to get the PdfBox package using the Nuget Package Manager. Now, import the following DLLs into your .cs file: The third step will be to install the DocX NuGet Package from the NuGet Package Manager: Let's read a PDF file and try to get the text from it.

Fig. 7-4 Temperature dependence of the equilibrium monomer concentration in THF polymerization by fN PF . After Dreyfuss and Dreyfuss [1966] (by permission of Wiley-Interscience, New York). 6 2

= ~ (w K, K,

subsequently decreases at higher temperatures Termination is relatively unaffected at the lower temperatures but increases with temperature at the higher temperatures [Burrows and Crowe, 1962] Table 7-2 shows a decrease in the ultimate conversion of monomer to polymer for the oxetane polymerization as the reaction temperature is increased In this polymerization the effect appears to be due to thermal destruction of the initiator [Rose, 1956] The same trend is observed for most cyclic ether and acetal polymerizations but for a different reason Increased temperature usually decreases the conversion of monomer to polymer by a ceiling temperature effect The propagation depropagation equilibrium (Eq 7-41) is shifted to the left with increasing temperature The equilibrium monomer concentration increases with increasing temperature in accord with Eq 3-178 (keep in mind that H is negative) Figure 7-4 shows this effect for THF polymerization in bulk using benzene diazonium hexa uorophosphate as the initiator.

wo) la{w)12,

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7-2b-6-b Thermodynamics of Polymerization The enthalpies and entropies of polymerization for various cyclic ethers and acetals are shown in Table 7-3 Data for formaldehyde and chloral are also included A comparison of the H and S values for alkenes, carbonyl monomers, and the cyclic monomers can be made from Tables 7-3 and 3-14 The H for the 3- and 4-membered cyclics are comparable to those for alkenes, and both are appreciably larger than the values for the two carbonyl monomers The conversion of a carbonyl p-bond to a s-bond is not as exothermic as the corresponding conversion of an alkene p-bond The H values for the larger-sized cyclic monomers are much lower than those for alkenes The S value is considerably smaller for most cyclic monomers compared to the alkenes and carbonyls.

(7.157) (7.158)

The cyclic monomers, having less degrees of freedom to begin with, have S values indicating that the loss in disorder on polymerization is less than for noncyclic monomers Ethylene oxide is an exception because of the highly strained nature of the 3-membered ring The S values for a few of the cyclic monomers, THF and 3,3-bis (chloromethyl)oxetane, are similar to the lowest values observed for alkene monomers..

~(w+wo)la{-w)12,

TABLE 7-3 DH and DS of Polymerization of Cyclic Ethers and Acetalsa Monomer Ethylene oxide Oxetane 3,3-Bis(chloromethyl)oxetane Tetrahydrofuranb 1,3-Dioxolanec 4-Methyl-1,3-dioxolanec Trioxane 1,3-Dioxepaned 2-Methyl-1,3-dioxepaned 4-Methyl-1,3-dioxepaned 1,3-Dioxocane 1,3,6-Trioxocanee 2-n-Butyl-1,3,6-trioxocanee 1,3,6,9-Tetraoxacycloundecanef Formaldehyde Chloral

= w -Gwca1 {w) + 2wcG2 wo~ [a{w)a*{-w) + a{-w)a*{w)]al{w).

H (kJ mol 1 ) 94.5 81 84.5 23.4 17.6 13.4 4.5 15.1 8.8 9.2 18.3 13.0 7.9 8.0 31.1 20

(7.159)

S (J mol 1 K 1 ) 174 83 82.4 47.7 53.1 18 48.1 37.2 38.9 21.3 16.3 6.2 79.2 95

To change the folder in which the database file will be stored, click the Browse button ( ). Access launches the File New Database dialog box.

The rest of the calculation is very analogous to what we have done for the matter Hamiltonian. From (7.147) we find an equation for lal(wW. As the phase is arbitrary (we can include any phase in the definition of the operator a), we choose it conveniently so that al (w) is given simply by

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How do I convert a given PDF File to Word File in C# .NET (ASP. ... Thanks Leon D. I'm trying to find free open source that can do the same. 0 ...












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