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(5.31) The reason for the v'2 factor will become evident soon. For each of the two pairs ofreal variables (qr,Pr) and (qi,Pi) in (5.31), we have a pair of driven harmonic oscillator equations qr= - , and where (5.34) The equations of motion (5.32) and (5.33) can be obtained from a Hamiltonian such as (5.24). As they are all independent variables, the four equations of motion can be

C CZ 5-94

. qi Pi =-,

P K M CZ K M CZ 5-95 5-96

(5.32)

5-97

(5.33)



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app Equations 5-92 and 5-97 allow one to obtain kp , kp , and K from kp values obtained in app the absence and presence of added common ion. A plot of kp obtained in the absence of added common ion versus M 1=2 yields a straight line whose slope and intercept are app kp kp K 1=2 and kp , respectively. A plot of kp obtained in the presence of added com 1 mon ion versus [CZ] yields a straight line whose slope and intercept are kp kp K and kp , respectively. Figures 5-5 and 5-6 show these plots for polystyryl sodium in 3-methyltetrahydrofuran at 20 C. The combination of the two slopes and two intercepts allows the individual calculation of kp , kp , and K. [Note: K as well as [P ] and [P (C )] can also be independently determined from conductivity measurements.]





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5-3d-2-b Reactivity in Anionic Polymerization. Table 5-11 shows the values of K and the propagation rate constants for free ions and ion pairs in styrene polymerization in THF at 25 C with various alkali metal counterions [Bhattacharyya et al., 1965a,b]. The cor responding kp values in dioxane are also presented. The values of K and kp in dioxane could not be obtained as conductivity measurements indicated no detectable dissociation of ion pairs to free ions in dioxane. A consideration of the data in Table 5-11 allows an understanding of reactivity in anionic polymerization. The polymerization data show the much greater reactivity of the free ion compared to any of the ion pairs. The value of kp is 4 1 1 2 3 6:5 10 L mol s which is larger by a factor of 10 10 than the kp values. Similar

_P;'

Fig. 5-5 Polymerization of styrene by sodium naphthalene in 3-methyltetrahydrofuran at 20 C. After Schmitt and Schulz [1975] (by permission of Pergamon Press and Elsevier, Oxford).

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differences between kp and kp have been observed in polymerizations of methyl methacrylate (MMA), 2-vinylpyridine (2VP), and isoprene (IP) [Bywater, 1985; Jeuk and Muller, 1982; Van Beylen et al., 1988]. For reference, kp has values of 3:8 103 , 1:0 105 , and 2:0 103 L mol 1 s 1 for IP (25 C), 2VP (25 C), MMA ( 98 C), respectivley, all measured in THF [Bywater, 1985].

. 81i Pr = - 8qr'

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Fig. 5-6 Polymerization of styrene by sodium naphthalene in 3-methyltetrahydrofuran at 20 C in the presence of sodium tetraphenylborate. After Schmitt and Schulz [1975] (by permission of Pergamon Press and Elsevier, Oxford).

(5.35)

TABLE 5-11 Effect of Counterion on Anionic Polymerization of Styrenea; b Polymerization in Tetrahydrofuran K 107 kp kp 9 160 2.2 > > > > 80 1.5 = 60 80 0.8 6:5 104 > > > 50 80 0.1 > ; 22 0.02

with the equations of motion given by 811. . qr = -8 ' Pr and (5.36)

0.94 3.4 19.8 21.5 24.5

(5.37)

Units of K are mol L 1 ; rate constants are L mol 1 s 1 . Data from Bhattacharyya et al. [1965a,b].

11. =

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