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PDF files is widely used for its convenience and safety on the Internet, meanwhile in daily work DOC files is more common in their degree of versatility and ...

6-4 IONIC COPOLYMERIZATION Ionic copolymerizations are different from radical copolymerizations in several respects. Ionic copolymerizations are much more selective. The number of comonomer pairs that undergo either cationic or anionic copolymerization is relatively limited because of the wider range of monomer reactivities in ionic copolymerization [Bywater, 1976; Kennedy and Marechal, 1983; Morton, 1983]. Cationic copolymerization is limited to monomers with electron-donating substituents and anionic copolymerization to monomers with electronwithdrawing substituents. For comonomer pairs that undergo ionic copolymerization, the general tendency is toward the ideal type of behavior (Sec. 6-2c-1), with the r1 r2 product approaching unity, where the relative reactivities of the two monomers toward the two different ionic propagating centers are approximately the same. There is a general lack of any tendency toward alternation. Furthermore, quite a few copolymerizations proceed with r1 r2



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How to convert PDF to Word in C# - YouTube
Nov 8, 2012 · PDF Focus.Net - How to convert PDF to Word using C#. SautinSoft.Duration: 4:17 Posted: Nov 8, 2012

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3 Aug 2016 ... With Aspose . Pdf for .NET - just add 2 lines of code and convert PDF files to Word Documents (DOC, DOCX) in .NET. The conversion is Fast, Accurate and Reliable and developers can easily manipulate Text, Tables, Images and other formatting. Explore Aspose . PDF for .NET with numerous advanced PDF manipulation features.

values greater than unity. Thus there are relatively few monomer pairs that yield copolymers containing large proportions of both monomers. Another characteristic feature of ionic copolymerizations is the sensitivity of the monomer reactivity ratios to changes in the initiator, reaction medium, or temperature. This is quite different from the general behavior observed in radical copolymerization. Monomer reactivity ratios in radical copolymerization are far less dependent on reaction conditions.

(7.7)





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After you add text to a slide (as described in the preceding section, Add and Edit Slide Text ), you can change the slide text s font, size, colour and style to alter its appearance. For example, you might choose to increase the size of a slide s title text in order to draw attention to it or change the font of the body text to match the font used in your company logo. Alternatively, you might change the text s colour to make it stand out against the background colour. You can also apply formatting to the text, such as bold, italics, underlining, shadow or strikethrough.

6-4a 6-4a-1

is the Rabi frequency of the guest atom located at whose electric dipole moment strength is d. This model is much simpler than it seems on a first impression. To see how simple it really is, let us first use the delta function in (7.2) to do the integral in (7.6) explicitly. Then the Hamiltonian becomes

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The effect of a substituent on the reactivity of a monomer in cationic copolymerization depends on the extent to which it increases the electron density on the double bond and on its ability to resonance stabilize the carbocation that is formed. However, the order of monomer reactivities in cationic copolymerization (as in anionic copolymerization) is not nearly as well de ned as in radical copolymerization. Reactivity is often in uenced to a larger degree by the reaction conditions (solvent, counterion, temperature) than by the structure of the monomer. There are relatively few reports in the literature in which monomer reactivity has been studied for a wide range of different monomers under conditions of the same solvent, counterion, and reaction temperature. Among the most extensive studies of monomer reactivity have been those involving the copolymerization of various meta- and para-substituted styrenes with other styrene monomers (styrene, a-methylstyrene, and p-chlorostyrene) as the reference monomer [Kennedy and Marechal, 1983]. The relative reactivities of the various substituted styrenes have been correlated by the Hammett sigma rho relationship:

(9.40)

1 log rs r1 6-73

a n2(k) = [an, a(k)]

For example, log 1=r1 values for a series of meta- and para-substituted styrenes copolymerized with styrene were plotted against the sigma substituent constants to yield a straight line with slope r of negative sign. The sigma value of a substituent is a quantitative measure of that substituent s total electron-donating or electron-withdrawing effect by both resonance and induction. Electron-withdrawing and electron-donating substituents have positive and negative sigma constants, respectively. A negative value of r means 1=r1 is increased by electron-donating substituents as expected for cationic polymerization. (A positive value of r would mean 1=r1 is increased by electron-withdrawing substituents.) Substituents increase the reactivity of styrene in the approximate order

_ 1 - - - - /fsin([k + kn]L) e -ikL .c (k)

0:27 0:17 0 0:23 0:37 0:71

(9.41 )

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Program Guide for .NET · Conversion ... Convert HTML String to PDF in C# ... Convert the PDF to word, HTML, SVG, XPS and save them to stream · Convert PDF ...












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