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customer's payment card It basically contains information about the account, the issuing financial institution, and other cryptographic information The merchant certificate assures the consumer that merchant is authorized to accept payment-card purchases It contains information about the merchant, the merchant's bank, and the financial institution issuing the certificate SET specifies the legal meaning of the certificates held by each party and the apportionment of liabilities connected with a transaction [Abbott 1999] In a SET transaction, the customer's payment-card number is passed to the merchant's bank without the merchant ever seeing the number in plain text This feature prevents fraudulent or careless merchants from stealing or accidentally leaking the payment-card number



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In 1995, a surprising and unprecedented optical effect was discovered in polymer thin lms containing the azo chromophore Disperse Red 1 (DR1), shown in Fig. 4.1. The Natansohn/Rochon (Rochon et al., 1995) research team and the Tripathy/Kumar collaboration (Kim et al., 1995b) simultaneously and independently discovered a large-scale surface mass transport when the lms were irradiated with a light interference pattern. In a typical experiment, two coherent laser beams, with a wavelength in the azo absorption band, are intersected at the sample surface (Fig. 4.2a, b). The sample usually consists of a thin spin-cast lm (10 1000 nm) of an amorphous azopolymer on a transparent substrate. The sinusoidal light interference pattern at the sample surface leads to a sinusoidal surface patterning, that is, a surface relief grating (SRG). These gratings were found to be extremely large, up to hundreds of nanometers, as con rmed by atomic force microscopy (AFM) (Fig. 4.3). The SRGs diffract very ef ciently, and in retrospect it is clear that many reports of large diffraction ef ciency before 1995, attributed to birefringence, were in fact due to surface gratings. The process occurs readily at room temperature [well below the glass-to-rubber transition temperature (Tg) of the amorphous polymers used] with moderate irradiation (1 100 mW/cm2) over seconds to minutes. The phenomenon is a reversible mass transport, not irreversible material ablation, since a at lm with the original thickness is recovered upon heating above Tg. Critically, it requires the presence and isomerization of azobenzene chromophores. Other absorbing but nonisomerizing chromophores do not produce SRGs. Many other systems can exhibit optical surface patterning (Yamaki et al., 2000), but the





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A SET transaction uses three software components:

Smart Light Responsive Materials. Edited by Yue Zhao and Tomiki Ikeda Copyright r 2009 John Wiley & Sons, Inc.

Browser wallet: The browser wallet application is integrated with the browser and provides the customer with storage and management of payment cards and certificates while shopping It responds to SET messages from the merchant, prompting the customer to select a payment card for payment Merchant server: The merchant server is the merchandizing and fulfillment engine for merchants selling on the Web For payments, it processes cardholder transactions and communicates with the merchant's bank or approval and subsequent payment capture Acquirer gateway: The acquirer gateway is the software component at the merchant's bank It processes the merchant's payment card transaction for authorization and payment

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In what follows, we give a highly simplified overview of the SET protocol In reality, the protocol is substantially more complex

N(CH2CH3)

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Suppose Bob wants to purchase a good over the Internet from Alice Incorporated 1 Bob indicates to Alice that he is interested in making a credit card purchase 2 Alice sends the customer an invoice and a unique transaction identifier 3 Alice sends Bob the merchant's certificate which includes the merchant's public key Alice also sends the certificate for her bank, which includes the bank's public key Both of these certificates are encrypted with the private key of a certifying authority 4 Bob uses the certifying authority's public key to decrypt the two certificates Bob now has Alice's public key and the bank's public key 5 Bob generates two packages of information: the order information (OI) package and the purchase instructions (PI) package The OI, destined for Alice, contains the transaction identifier and brand of card being used; it does not include Bob's card number The PI, destined for Alice's bank, contains the transaction identifier, the card number and the purchase amount agreed to Bob The OI and PI are dual encrypted: the OI is encrypted with Alice's public key; the PI is encrypted with Alice's bank's public key (We are bending the truth here in order to see the big

Figure 4.1. Chemical structure of poly(Disperse Red 1) acrylate, pdr1a, a pseudostilbene side-chain azopolymer that generates high quality surface relief structures.

file:///D|/Downloads/Livros/computa o/Computer%20Net20Approach%20Featuring%20the%20Internet/Icommercehtm (7 of 9)20/11/2004 15:53:09

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amplitude of the modi cation is much smaller, does not involve mass transport, and usually requires additional processing steps. The all-optical patterning unique to azobenzenes has been studied intensively since its discovery, yet the mechanism remains controversial. The competing interpretations will be discussed and evaluated here. Many reviews of the remarkable body of experimental results are available (Natansohn and Rochon, 2002; Yager and Barrett, 2001; Delaire and Nakatani, 2000; Viswanathan et al., 1999b).

6 7

1.4 1.2 1 Absorbance (a.u.) 0.8 0.6 0.4 0.2 0 250 [C12E4]

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