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Message types 128-129 are the familiar Echo RequesdReply messages that are similar to their counterparts in IPv4 Message types 130-1 32 are defined by the Multicast Listener Discovery Protocol, and message types 133-137 are defined by the Neighbor Discovery Protocol Both of these are examples of extensions to the ICMPv6 message set Elements from the Internet Group Management Protocol version 3 (IGMPv~), specified in RFC 3376, were merged into a new protocol called Multicast Listener Discovery (MLD), which is documented in RFC 27 10 [6331 MLD is considered to be a subprotocol of ICMPv6 The purpose of MLD is to enable IPv6 routers to discover nodes that wish to receive multicast packets on its directly attached links, and to discover which multicast addresses are of interest to those neighboring nodes.



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The discovered information is then provided to the multicast routing protocol that is being used by that router so that it can deliver the multicast information to all of its links on which there are nodes that wish to listen These nodes are called Mu1ticast Listeners There are three types of Multicast Listener Discovery Messages: Query, Report, and Done The Multicast Listener Query is used to learn if a particular multicast address or addresses has listener(s) on a specific link There are two subtypes of Query messages: the General Query, which is used to learn which multicast addresses have listeners on a specific link; and the Multicast Address-Specific Query, which is used to learn if a particular multicast address has any listeners on an attached link General Queries are sent to the Link-Local all-nodes multicast address (FF02::1), as discussed in Section 6429 above.





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Nodes respond to a Query by generating a Multicast Listener Report message The address being reported is carried in both the IPv6 Destination Address field and the MLD Multicast Address field When a node ceases to listen to a multicast address on an interface, it should send a Multicast Listener Done message to the link-local all-routers multicast address (FF02::2), with the address that it is ceasing to listen to in its Multicast Address field The Neighbor Discovery Protocol, defined in RFC 2461 [6-341,combines the functions of three IPv4 mechanisms: the Address Resolution Protocol (ARP), from RFC 826; ICMP Router Discovery messages, from W C 1256; and the ICMP Redirect message, from RFC 792 Nodes (hosts or routers) use Neighbor Discovery to determine the Data Link Layer addresses for their neighbors on attached links, and to purge cached values that are no longer valid.

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The 11a-epimers 171 and 173 are much less reactive than their corresponding 11b-epimers. The unfavorable in uence from the 11a-substituents can also be found in other examples.200 This lower reactivity may be attributed to the steric hindrance around the O-1 atom in 11a-epimers, which blocks the way for Fe(II) to attack O-1 (Figure 5-5). These experimental results show that the cleavage of peroxide with Fe(II) and then the formation of C-centered free radical, especially primary C-centered radical, is essential for the antimalarial activity. Posner et al. have synthesized the 3-methyl-derivatives of qinghaosu and found that the antimalarial activity of 3b-methyl derivative in vitro was about the same as qinghaosu; however, the activity of the 3a-methyl- or 3,3-dimethy-derivative was at least two orders less than that of qinghaosu. This difference was supposed to come from the availability of the C-3 free radical for the later derivatives, but it was not mentioned whether these bio-inactive compounds were also inert in the reaction with ferrous ion.288 5.6.5 Interaction of Biomolecules with Carbon-Centered Free Radical

Nodes also use this protocol to actively track which neighbors are reachable and which are not, and also to detect Data Link Layer addresses that have changed Hosts use Neighbor Discovery to find neighbor-.

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