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A recent study (Seppelt and Oberhammer, 1985) showed that, according to spectroscopic data including electron diffraction, the isomer pentafluoroselenium cyanate SeFSOCN is favored; this compound had previously been described as pentafluoroselenium isocyanate 0 Systems containing thiocyanate ligands have been studied extensively The stretching vibrations of the linear SCN group are affected differently by linkages via nitrogen or sulfur The frequencies in the spectrum of the ion are: ul: 2053 cm ( q c , ~ ) ) ; u3: 750 cm-' (qcs)); 480 cm-' (S(SCN)), v3: In S-bonded complexes, the intensive CN vibration is shifted to slightly higher frequencies (2 110 cm-') than in N-bonded systems (2 100 cm-I).



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However, a more definitive measure is provided by the CS frequency, which is generally of weak intensity: its frequency increases in the case of N-coordination (800 cm I ) , while a decrease is observed in compounds with metal-sulfur bonds (720 cm- I ) These frequency shifts can be explained by changes in the bonding, illustrated by the following structures: -S-C=N and S=C=N- In this, as in many other cases, the results obtained by vibrational spectroscopy were shown to be reliable by determining the crystal structures of particular examples by X-ray methods To obtain information about the geometry of molecules, eg, about the number of AB bonds in an AB, system, the spectra have to be analyzed more carefully In a non-linear molecular compound, the total number of vibrations is 3n- 6 ( n = number of atoms).

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In order to discuss the geometry, one must first look at the number of stretching vibrations This number corresponds to the number of AB bonds As a result of the symmetry, the number of observed stretching vibrations is sometimes smaller, eg, only two vibrations are usually observed for ALI-systems, since one of them is doubly degenerate This is true for species with D3h- and with C3,-symmetry The observability of vibrations in the Raman and/or IR spectrum, the polarization of the vibrations, and the distribution in different representations can be deduced from the.

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though WAP was quite different in reach, technology, and performance from the World Wide Web. The WAP Forum has consolidated into the Open Mobile Alliance (OMA) [1], and no longer exists as an independent organization. We don t count WAP as a successful technology, but rather as one of the many failed attempts in the telecom industry to provide data services without adequate bandwidth [2].

Out of the box, Management Studio s Query Editor does not provide automatic formatting of T-SQL. There are some free websites that enable you to submit a SQL statement and will then format the code, but I ve been using SQL Prompt from Red Gate and I ve come to depend on it for consistent formatting. Highly recommended.

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