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It is a historical unit of the exposure and characterizes the radiation incident on an absorbing material without regard to the character of the absorber The unit was formalized in 1928 as The amount of radiation which produces one electrostatic unit of ions (esu), either positive or negative, per cubic centimeter of air at standard temperature and pressure Translated in modern units: 1 roentgen 2:58 10 4 coulomb=kg-air 0:3336 nC=cm3 at STP This value corresponds to an absorbed energy of approximately 88 mJ/kg using the effective ionization energy of 34 eV per ion pair in air The roentgen is most often used to describe the intensity of a photon source such as a medical X-ray machine or other irradiator The exposure should be measured at some distance from the source so that the radiation eld is uniform compared to the dimensions of the detector.



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A differential encoder could be applied to the input of the PTCM encoder, and a differential decoder to the output of the PTCM decoder The PTCM 8-PSK system is partially transparent to /2, and , but not to the remaining four phases: /4, 3 /4 A special two-dimensional differential encoder/decoder pair can be used to remove the /2 and ambiguities, then the remaining ones are removed by the Viterbi decoder's path metric monitoring circuit..





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The detector is usually an ion chamber lled with dry air that is sensitive to pico-coulombs of charge As studies of the effects of exposure to all types of radiation went on, it became clear that these effects were correlated with the amount of absorbed energy, which is generally less than the exposure In 1962 the rad was formally de ned as a special unit of energy called the radiation absorbed dose with a value of 100 ergs per gram of absorbing material The rad is a convenient physical standard that correlates well.

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Apart from the problems discussed above, deviations from the Lambert-Beer law have to be expected in many analyses, because, due to differences in the interactions between molecules in the standard and the unknown sample, the law looses validity over a larger concentration range. In these cases it is therefore necessary to prepare a number of standards at concentrations covering the entire expected range, and to calculate the absorption coeffient of the analyte at the given wavenumber. The plot of the measured absorbance values against the known concentrations of the analyte yields the so-called calibration function. If the Lambert-Beer law applies, the calibration function will be linear. The slope of the straight line can be related to the sensitivity of the analysis (see Sec. 3.3.5). It is worthwhile calculating the functional relation between absorbance and concentration of the calibration function by the least squares fit method and then to calculate the concentrations of the unknown samples on the basis of this relation, rather than through readings from the graph. For statistical analysis it is necessary to prepare and to measure each standard at least twice. In routine analysis, carried out according to carefully prepared guidelines, confidence limits are P = 0.95, based on the standard distribution. In all other cases, especially in solving discrepancies between analytical results or for preparing instructions, confidence limits of P = 0.95 or P = 0.99, based on the t distribution, are used. The confidence intervals decrease somewhat more as the number of measurements increases, up to about 6. Above this number the effect is negligible. It can be shown that at a given number of measurements the confidence limit of the final result will be at its minimum if the number of calibration standards equals the number of sample measurements (Weitkamp and Barth, 1976).

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