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In the laboratories of BASF (Badische Anilin- and Soda-Fabrik) at Ludwigshafen, the importance of infrared spectroscopy for industrial purposes was realized as early as the 1930 s The first 1R instrument with a modulated beam was built by Lehrer in 1937 and modified to a double beam instrument with optical compensation in 1942 Luft described the first non-dispersive infrared analyzer in 1943 He used the gas to be analyzed as absorber in a photo-acoustic detector cell Thus, the instrument was sensitive only to this gas He also provided a survey of early industrial applications of infrared spectroscopy (Luft, 1947) Based on the servo techniques developed during the Second World War automatically recording infrared spectrometers were introduced to the market in the United States Especially the Perkin-Elmer Model 2 1 stimulated the application of infrared spectrometry worldwide.



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In 1957, some 100 Model 21 spectrometers were sold along with about 300 of the low-cost Model 137, Infracord During the 1960s further improvements made infrared spectroscopy a very useful tool used worldwide in the analytical routine laboratory as well as in many fields of science Grating spectrometers replaced the prism instruments due to their larger optical conductance (which is explained in Sec 3 of this book) The even larger optical conductance of interferometers could be employed after computers became available in the laboratory and algorithms which made Fourier transformation of interferograms into spectra a routine The computers which became a necessary component of the spectrometers made new powerful methods of evaluation possible, such as spectral subtraction and library search The Raman effect also allows the observation of vibrational spectra; it provides information which complements that obtained by 1R spectroscopy This effect had been repeatedly predicted.





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Lommel (I 878) described certain anomalies of fluorescence, the color of which is dependent on the nature of the sample and the frequency of the exciting radiation, with the necessity of bands with the frequency v iw , if a damped anharmonic oscillator of the frequency w is irradiated with light of the frequency v Smekal (1923), Kramers and Heisenberg (1925), Schrodinger (1 926), and Dirac (1927) predicted the Raman effect by applying quantum mechanics to molecules Raman was looking for the optical analogue of the Compton effect, when, on February 7, 1928, his co-workers Krishnan and Venkateswaran observed modified scattering of sunlight, which Raman identified as Kramers-Heisenberg effect A short paper describing A New Type of Secondary Radiation by Raman and Krishnan was cabled to Nature on February 16th, 1928 Other papers followed (Raman et al, 1928).

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Insert Function dialog box, open the list box, type the first letter of the function name, and then scroll to the desired function. For example, if you select the All category and want to insert the SIN function, click anywhere on the Select a function list box and press S. Excel selects the first function that begins with S. Keep pressing S until you reach the SIN function.

In France, Rocard (1 928) immediately attributed this novel effect to optical modulation by the oscillating molecule Cabannes (1 928) described the new effect as optical beating and predicted the existence of pure rotational Raman scattering in anisotropic molecules In the Soviet Union, Landsberg and Mandelstam (1928) published their results on the light scattering of quartz, describing lines which differed from those expected by Debye s theory They explained this phenomenon as inelastic scattering of light quanta In the United States, Wood ( 1 928) realized that he had already recorded Raman lines on his photographic plates when he investigated resonance fluorescence He introduced the term anti Stokes for scattered light, whose quanta have a higher energy than those of the exciting light (see Sec 24)..

ii) A PCM system designed for analogue message transmission is readily adapted to other input signals. iii) PCM has the capability of regeneration and is very attractive for communication systems having many repeater stations. PCM is often applied at voice channel level in connection with time-division multiplexing (TDM). Another use of PCM is the direct encoding/decoding of a frequency-division multiplexed (FDM) signal by the use of a transmultiplexer. To provide improved performance for voice signals, the quantization steps are not evenly spaced: logarithmic compression and expansion are applied respectively at the transmit and receive sides. This is called instantaneous companding. The so-called A and laws, shown below, are functions defining this companding operation for voice PCM applications:

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