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The basic relationships of electrochemical kinetics are identical with those of chemical kinetics. Electrochemical kinetics involves an additional parameter, the electrode potential, on which the rate of the electrode reaction depends. The rate of the electrode process is proportional to the current density at the studied electrode. As it is assumed that electrode reactions are, in general, reversible, i.e. that both the anodic and the opposite cathodic processes occur simultaneously at a given electrode, the current density depends on the rate of the oxidation (anodic) process, va, and of the reduction (cathodic) process, vC9 according to the relationship j = nF(va-vc) (5.2.1)



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64 bytes from 192.168.0.4: icmp_seq=5 ttl=64 time<10ms. ---- 192.168.0.4 PING Statistics ---5 packets transmitted, 5 packets received, 0.00% packet loss round-trip min < 10ms, avg < 10ms, max < 10ms, stddev < 10ms *A:CE1#





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File Numbering allows you some exibility in the way les are labeled when they are written to the memory card When you rst turn on your PowerShot G11 and take a picture, that le is 0001 You can choose from these two options: Continuous With Continuous numbering, images are numbered sequentially using a unique four-digit number from 0001 to 9999 With unique lenames, managing and organizing images on the computer is easy because you don t have to worry about images having duplicate lenames If you insert a memory card that already has images on it taken with the G11, the camera then starts numbering with the highest number either that was used on the stored images on the card or that was last captured This happens even if you switch to cards from another PowerShot camera Continuous le numbering is the default setting on the G11 Auto Reset.

where n is the charge number of the electrode reaction appearing in the general equation 2 v/(r Red, < 2 v,.oOx, + ne (5.2.2)

*A:CE1# traceroute 192.168.0.4 traceroute to 192.168.0.4, 30 hops max, 40 byte packets 1 192.168.0.4 (192.168.0.4) <10 ms <10 ms <10 ms *A:CE1#

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254 The rates of the partial anodic and cathodic processes at a given electrode potential can often be expressed by the relationships

1a. How many routers does CE1 see between itself and Device4 1b. Does CE1 see the connection to Device4 as routed or switched (at Layer 2) Explain your answer. 2. On CE1 or Device1, try to ping any of the interfaces on PE1 or PE2. 2a. Are any PE interfaces reachable 3. (Optional) If Device4 has OSPF configured, check the adjacencies and LSA database on CE1 and Device4. (Refer to Lab Section 9.1 in 9.) 3a. How many OSPF adjacencies are there on each CE device 3b. Are there any adjacencies with, or LSAs from, the PE routers 3c. From CE1, which system interfaces can you ping PE1 PE2 Device4 3d. Explain the results. 3e. Are the OSPF sessions on the CE devices connected in any way to the OSPF sessions on the PE devices 4. On one of the PE devices, shut down the SDP to the other PE device. Repeat Steps 1 3 above.

(5.2.3)

*B:PE1# configure service sdp 12 shutdown *B:PE1#

If you use Auto Reset, both le and folder numbering restarts when you insert another memory card If you prefer to organize images by memory card, then Auto Reset is a useful option Folder numbers begin with 100, and le numbering begins with 0001, unless the card contains a previous image, in which case numbering begins with the highest le number in the highest numbered folder on the memory card However, multiple images on your computer will have the same lename but will be stored in different folders Because of this, you should create separate folders on the computer and other devices for each download and otherwise follow careful folder organization to avoid lename con icts and the potential overwriting of special images on the computer.

vc=K n c, '

4a. Explain the results. (Hint: Check the status of the VPLS service.)

where ka is the potential-dependent rate constant of the anodic process, kc is the potential-dependent rate constant of the cathodic process, c, is the concentration of reactant i, and the order of the electrode reaction with respect to the ith reactant, v/ta or v /c , is given by the relationships v, a = dlnu c (5.2.4)

5. Re-enable the SDP that you shut down in the previous step. You may need to wait a few moments for everything to return to its previous state.

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