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480. W. Pauli. General Principles of Quantum Mechanics. Springer-Verlag, Berlin, 1980. 481. W. Pauli. Electrodynamics, volume 1 of Pauli Lectures on Physics. Dover, Mineola, NY, 2000. 482. S. Pearlmutter et at. Measurements of wand), from 42 high-redshift supernovae. Astrophysical Journal, 517:565-586, June 1999. 483. P. J. E. Peebles and B. Ratra. The cosmological constant and dark energy. Reviews of Modern Physics, 75(3):559-606, April 2003. 484. D. T. Pegg and S. M. Barnett. Tutorial review: Quantum optical phase. Journal of Modern Optics, 44(2):225-264, February 1, 1997. 485. R. Peierls. Surprises in Theoretical Physics. Princeton Series In Physics. Princeton University Press, Princeton, NJ, 1979. 486. R. E. Peierls, A. Salam, P. T. Matthews, and G. Feldman. A survey of field theory. Reports on Progress in Physics, 18:423-477,1955. 487. T. Pellizzari and H. Ritsch. Photon statistics of the three-level one-atom laser. Journal of Modern Optics, 41(3):609-623, March 1994. 488. T. Pellizzari and H. Ritsch. Preparation of stationary Fock states in a one-atom Raman laser. Physical Review Letters, 72(25):3973-3976, June 20, 1994. 489. A. Peres. Proposed test for complex versus quaternion quantum theory. Physical Review Letters, 42(11):683-686, March 12, 1979. 490. V. Pennovii, A. 1998. 491. K. Petermann. Calculated spontaneous emission factor for double-heterostructure injection lasers with gain-induced waveguiding. IEEE Journal of Quantum Electronics, 15(7):566-570, July 1979. 492. E. R. Pike and S. Sarkar. The Quantum Theory of Radiation. International Series of Monographs on Physics. Clarendon Press, Oxford, 1995.



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Calculated from Eq. 2-148 0.879 0.916 0.843 0.955

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Data from Flory [1941].

Luk~, and J. Penna. Phase in Optics, volume 15 of World Scientific Series in Contemporary Chemical Physics. World Scientific, Singapore,





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The observed pc values in Table 2-9 as in many other similar systems fall approximately midway between the two calculated values The Carothers equation gives a high value of pc for reasons mentioned above The experimental pc values are close to but always higher than those calculated from Eq 2-148 There are two reasons for this difference: the occurrence of intramolecular cyclization and unequal functional group reactivity Both factors were ignored in the theoretical derivations of pc Intramolecular cyclization reactions between functional groups are wasteful of the reactants and require the polymerization to be carried out to a greater extent of reaction to reach the gel point Stockmayer [1945] showed this to be the case for the reaction of pentaerythritol, C(CH2OH)4 f 4 with adipic acid.

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493 R Podolny Something Called Nothing- Physical Vacuum: What Is It Mir, Moscow, 1986 English translation of the Russian original, 1983 494 A M Polyakov Particle spectrum in the quantum field theory JETP Letters, 20:194-195,1974 English translation of the Russian original published in Zhurnal Eksperimental'noi i Teoreticheskoi Fiziki Pis'ma, 20, 430-433, 1974 Reprinted in A S Goldhaber and W P Trower, Magnetic Monopoles, American Association of Physics Teachers, 1991, pp 103-104; and in G Soliani, Solitons and Particles, World Scientific, Singapore, 1985, pp 522-523 495 E A Power and T Thirunamachandran Quantum electrodynamics in a cavity Physical Review A, 25(5):2473-2484, May 1982 496 R E Prange Tunneling from a many-particle point of view Physical Review, 131(3):1083-1086,August 1,1963 497 A Proca Sur une explication possible de la difference de masse entre Ie photon et l'electron Journal de Physique Ser VII, 3(2):83-101, February 1932 498 A Proca.

Gelation was studied as a function of concentration and the results extrapolated to in nite concentration where intramolecular reactions would be expected to be nil The experimental pc value of 0:578 0:005 compared exceptionally well with the theoretial value of 0577 The value of pc calculated by the Carothers equation is 075 for this system In many reaction systems the difference between the observed pc values and those calculated from Eq 2-148 are at least partially ascribed to the failure of the assumption of equal reactivity of all functional groups of the same type An example is the glycerol-phthalic acid system previously mentioned The difference between the calculated and observed values of pc (0709 vs 0765) would be decreased, but not eliminated, if the calculation were corrected for the known lower reactivity of the secondary hydroxyl group of glycerol.

Sur la theorie ondulatoire des electrons positifs et negatifs Journal de Physique, 7:347-353, 1936 499 A Proca Sur les equations fondamentales des particules elementaires Comptes Rendus, 202:1490-1492,1936 500 A M Prokhorov Molecular amplifier and generator for submillimeter waves Soviet Physics JETP, 7:1140-1141, December 1958 English translation of the Russian original: JETP (USSR), 34:1658-1659, June 1958 501 M H L Pryce The mass-centre in the restricted theory of relativity and its connexion with the quantum theory of elementary particles Proceedings of the Royal Society of London, Series A, 195:62-81, 1948 502 E M Purcell Spontaneous emission probabilities at radio frequencies Physical Review, 69:681, 1946 503 J-M Raimond Entanglement and decoherence studies in cavity QED experiments Short course given in the NATO-Advanced Study Institute on New Directions in Mesoscopic Physics (towards Nanoscience) at the Ettore Majorana Centre in Erice (Sicily), Italy, July 20-August 1, 2002.

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