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133 196 in Progress in Polymer Science, Vol 9, A D Jenkins and V T Stannett, eds, Pergamon Press, London, 1983 Grattan, D W and P H Plesch, Makromol Chem, 181, 751 (1980) Gulino, D, J P Pascault, and Q T Pham, Makromol Chem, 182, 2321 (1981) Hadjichristidis, N, S Pispas, M Pitsikalis, H Iatrou, and C Vlahos, Adv Polym Sci, 142, 71 (1999) Hadjichristidis, N, H Iatrou, S Pispas, and M Pitsikalis, J Polym Sci Polym Chem Ed, 38, 3211 (2000) Hadjichristidis, N, M Pitsikalis, S Pispas, and H Iatrou, Chem Rev, 101, 3747 (2001) Hadjichristidis, N, S Pispas, and G Floudas, Block Copolymers: Synthetic Strategies, Physical Properties, and Applications, Wiley, New York, 2002 Hadjikyriacou, S and R Faust, Macromolecules, 33, 730 (2000) Hashimoto, K, H Sumitomo, and S Ohsawa, J Polym Sci Polym Chem Ed.



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(5.128)

, 14, 1221 (1976); 16, 435 (1978) Hatada, K, T Kitayama, and H Yuki, Polym Bull, 2, 15 (1980) Hay, J N, D S Harris, and M Wiley, Polymer, 17, 613 (1976) Hayashi, K, K Hayashi, and S Okamura, J Polym Sci, A-1(9), 2305 (1971)..

So the Hamiltonian in the new gauge will only be an observable when explicit function of time. Now consider the typical Hamiltonian for an atom or molecule:





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Hayashi, K, H Yamazawa, T Takagaki, F Williams, K Hayashi, and S Okamura, Trans Faraday Soc, 63, 1489 (1967) Hertler, W R, Macromol Symp, 88, 55 (1994); Group Transfer Polymerization, Chap 2 in Silicon in Polymer Synthesis, H R Kricheldorf, ed, Springer-Verlag, Berlin, 1996 Higashimura, T and M Sawamoto, Makromol Chem Suppl, 12, 153 (1985); private communication (1989) Higashimura, T, S Aoshima, and M Sawamoto, Makromol Chem Macromol Symp, 13/14, 457 (1988) Higashimura, T, O Kishiro, and T Takeda, J Polym Sci Polym Chem Ed, 14, 1089 (1976) Higashimura, T, H Kusano, T Masuda, and S Okamura, J Polym Sci Polym Lett Ed, 9, 463 (1971) Higginson, W C and N S Wooding, J Chem Soc, 760, 1178 (1952) Hogen-Esch, T E and J Smid, eds, Recent Advances in Anionic Polymerization, Elsevier, New York, 1987.

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Hrdlovic, P, J Trekoval, and I Lukac, Eur Polym J, 15, 229 (1979) Hsieh, W C, H Kubota, D R Squire, and V Stannett, J Polym Sci Polym Chem Ed, 18, 2773 (1980) Hsieh, H L, Industrial Applications of Anionic Polymerization: An Introduction, in Applications of Anionic Polymerization Research, R P Quirk, ed, Am Chem Soc Symp Ser, Vol 686, American Chemical Society, Washington, DC, 1998 Hsieh, H L and R P Quirk, Anionic Polymerization: Principles and Practical Applications, Marcel Dekker, New York, 1996 Hui, K M and Y K Ong, J Polym Sci Polym Chem Ed, 14, 1311 (1976) Hurley, S A and P J T Tait, J Polym Sci Polym Chem Ed, 14, 1565 (1976) Imanishi, Y, Carbanionic Polymerization: Hydrogen Migration Polymerization, pp 451 455 in Comprehensive Polymer Science, Vol 3, G C Eastmond, A Ledwith, S.

(5.129)

Russo, and P Sigwalt, eds, Pergamon Press, London, 1989 Imanishi, Y, T Higashimura, and S Okamura, Chem High Polym (Tokyo), 18, 333 (1961) Inoue, S, J Polym Sci Polym Chem Ed, 38, 2861 (2000) Inoue, S, T Aida, M Kuroki, and Y Hosokawa, Makromol Chem Macromol Symp, 32, 255 (1990) Jenkinson, D H and D C Pepper, Proc Roy Soc (London), A263, 82 (1961) Jerome, R, Ph Teyssie, B Vuillemin, T Zundel, and C Zune, J Polym Sci Polym Chem Ed, 37, 1 (1999) Jeuk, H and A H E Muller, Makromol Chem Rapid Commun, 3, 121 (1982) Johnson, A F and D A Pearce, J Polym Sci Polym Symp, 56, 57 (1976) Johnson, A F and R N Young, J Polym Sci Symp, 56, 211 (1976) Jolly, W L, Modern Inorganic Chemistry, McGraw-Hill, New York, 1984.

+ LqacP(ra,t).

Kanoh, N, T Higashimura, and S Okamura, Makromol Chem, 56, 65 (1962) Kanoh, N, A Gotoh, T Higashimura, and S Okamura, Makromol Chem, 63, 115 (1963) Kanoh, N, K Ikeda, A Gotoh, T Higashimura, and S Okamura, Makromol Chem, 86, 200 (1965) Kaszas, G, J E Puskas, C C Chen, and J P Kennedy, Macromolecules, 23, 3909 (1990) Katayama, H, M Kamigato, and M Sawamoto, J Polym Sci Polym Chem Ed, 39, 1249, 1258 (2001) Kennedy, J P, J Polym Sci, A-1(6), 3139 (1968); Cationic Polymerization of Ole ns: A Critical Inventory, Wiley-Interscience, New York, 1975; J Polym Sci Symp 56, 1 (1976); Polym J, 17, 29 (1985); Makromol Chem Macromol Symp, 32, 119 (1990); J Polym Sci Polym Chem Ed, 37, 2285 (1999) Kennedy, J P and S C Feinberg, J Polym Sci Polym Chem.

For instance, the Hamiltonian for the hydrogen atom that is studied in elementary quantum mechanics has this form. What happens when we make the general gauge change (5.122) Substituting cP by cP' given by (5.122) in the Hamiltonian (5.129), we find the following expression for the atomic Hamiltonian in the new gauge: (5.130) Comparing (5.128) and (5.130), we see that we must take (5.131) Unfortunately, this does not work, as the resulting t yields (5.132) which can be rewritten as

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