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nanocrystals (Ubukata et al., 2004) (Fig. 8.13, right) can also be conveyed. The conveying action may be widely applicable to many other kinds of functional materials that are themselves inert to light. A great advantage of using the instant migration system is that only small amounts of light are required, which would not damage the host materials. 8.4.4.3. Supramolecular Mass Migration Systems. Azobenzene unit is essential for the photoinduced mass migration, but after the relief formation, the existence of this strongly light-absorbing chromophore will be a drawback for many optical applications. To overcome these contradictory requirements, a system in which the Az unit can be detached after the relief formation is proposed (Zettsu et al., 2007b). Here the Az unit is not necessarily linked to the polymer backbone, but the supramolecular LC framework via hydrogen bonding (Kato system) (Kato, 2002; Kato and Frechet, 1989) is applied. After the cross-linking mentioned earlier, the Az unit is readily removed from the lm with retention of the morphological feature of the relief structure (scheme shown in Fig. 8.14). The structures of the polymer and guest compound used in this study are also shown in Fig. 8.14. An Az compound, 8Az-4Im, with an imidazole base at the terminus and a random copolymer consisting of poly(acrylate) with 4-oxybenzoic acid moiety should work as the H-bonding acceptor and donor, respectively. The H-bonded complex is prepared from a mixed pyridine solution containing 8Az-4Im and pBA6Ac-PE4.5. Infrared spectroscopy and thermal analysis indicate that the hydrogen bonding actually occurs between imidazole and benzoic acid.



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file:///D|/Downloads/Livros/computa o/Computer%20Net-Down%20Approach%20Featuring%20the%20Internet/ftphtm (4 of 4)20/11/2004 15:51:54

Along with the Web, electronic mail is one of the most popular Internet applications Just like ordinary "snail mail," email is asynchronous -- people send and read messages when it is convenient for them, without having to coordinate with other peoples' schedules In contrast with snail mail, electronic mail is fast, easy to distribute, and inexpensive Moreover, modern electronic mail messages can include hyperlinks, HTML formatted text, images, sound and even video In this section we will examine the application-layer protocols that are at the heart of Internet electronic mail But before we jump into an in-depth discussion of these protocols, let's take a bird's eye view of the Internet mail system and its key components

Figure 8.14. Chemical structure of H-bonded supramolecular LC polymer lm and scheme of the strategy for selective detachment of Az unit after the relief formation.





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MIL-STD-781E is a standard developed by the US military over a period of years to use an analytical bottom-up approach to predicting reliability. This method uses a component count to build up an analysis of the reliability of a unit. This approach has probably best been applied to electronics over the years as the use of electronic components within a design tends to be replicated within a design and across a family of designs. This method uses type of component, environment and quality factor as major discriminators in predicting the failure of a particular component, module and ultimately subsystem. Component failure rates are extracted from the US military standard and then applied with the appropriate factors to establish the predicted value as shown in the simpli ed example below: Failure Rate Where

Figure 24-1: A bird's eye view of the Internet e-mail system Figure 24-1 presents a high-level view of the Internet mail system We see from this diagram that it has three major components: user agents, mail servers, and the Simple Mail Transfer Protocol (SMTP) We now describe each of these

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The mass migration is readily formed also for this supramolecular system. This fact implies an important issue that the covalent linkage of the Az unit to the polymer chain is not necessary to cause the ef cient phototriggered material transfer, but H-bonding can be the exact alternative. As a control experiment, 8Az-4ImBr (Fig. 8.14), a precursor compound of the imidazol compound, is also examined. No SRG formation is observed, obviously showing the importance of H-bond formation.

, sending an email message to a recipient, Bob User agents components in the context of a sender, Alice allow users to read, reply to, forward, save, and compose messages (User agents for electronic mail are sometimes called mail readers, although we will generally avoid this term in this book) When Alice is finished composing her message, her user agent sends the message to her mail server, where the message is placed in the mail server's outgoing message queue When Bob wants to read a message, his user agent obtains the message from his mailbox in his mail server In the late 1990s, GUI (graphical user interface) user agents became popular, allowing users to view and compose multimedia messages Currently, Eudora, Microsoft's Outlook Express, and Netscape's Messenger are among the popular GUI user agents for email There are also many text-based email user interfaces in the public domain, including mail, pine and elm

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