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Figure 12.10 presents a PEO-based azo LCBC lm, which exhibits wellordered hydrophilic PEO nanocylinders with hexagonal packing embedded in an azo LC matrix. The anisotropic PEO nanocylinders can be used as ion-conductive channels since PEO has been widely used as a solid electrolyte (Fig. 12.22). By incorporating LiCF3SO3 into the PEO nanocylinders, a supramolecular complexed structure and anisotropic ion transportation were achieved on the basis of the azo LCBC nanotemplate (Li et al., 2007a). Highly ordered ion-conducting PEO nanocylinder arrays with perpendicular orientation were formed by coordination between the lithium cations and the ether oxygens of the PEO blocks. At low- and medium salt concentration, selective complexation of Li+ with the PEO phase leads to the formation of an ordered array of ion-conducting PEO nanocylinders, which are perpendicular to the substrate surface, and on the right-hand side of Fig. 12.22, there is a 3-D illustration of the corresponding phase-segregated structure, in which anisotropic ion transport is observed. At high salt concentration, the lithium salt is dissolved in both PEO and azo domains. This decreases LC ordering and disturbs microphase separation. An array of tilted and distorted nanocylinders is formed with poor regularity. Consequently, the anisotropic value of ion conductivity is reduced (Breiner, 2007). On the surface of PEO-based azo LCBC lms, each hydrophilic PEO domain appears as a circular hollow surrounded by the hydrophobic azo matrix. These amphiphilic properties enable the selective absorption of Au nanoparticles with hydrophilic or hydrophobic surface modi cations. Of course, the surface properties of the gold nanoparticles are a critical factor in this nanofabrication (Watanabe et al., 2007). To extend site coverage further and favor high selectivity,



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There are two main types of refrigeration systems in use: Air cycle refrigeration systems Vapour cycle refrigeration systems

Figure 53-4: A simple CDMA example: sender encoding, receiver decoding To illustrate how CDMA works, let us focus on the ith data bit, di For the mth mini-slot of the bit-transmission time of di, the output of the CDMA encoder, Zi,m, is the value of di multiplied by the mth bit in the assigned CDMA code, c m: Zi,m = di

Figure 12.22. Schematic illustration of anisotropic ionic conduction in nanochannels with nanotemplates of azo LCBC lms. The complexes PEO+LiCF3SO3 were prepared at low-, medium-, and high salt concentration. Source: Reproduced from Li et al., 2007a.

(Equation 53-1)





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the gold nanoparticles should be modi ed by additional functional ligands, which provide electrostatic and hydrogen bond interactions. As shown in Fig. 12.23, sitespeci c recognition of gold nanoparticles was obtained in the nanocylinder domains of PEO blocks or the azo continuous domains. The on-site coverage and selective effects of the surface properties, the concentration of gold nanoparticles, the dipping time, and the composition of the dispersion medium were investigated by a simple dip coating method. Then the ordering of the gold nanoparticles from the template was transferred to the substrate by the inexpensive VUV approach, which was effective in removing the templates without destroying the regularity of the assembled nanoparticles. Such facile transfer is characteristic of soft (organic) templates compared with hard (inorganic) templates. The sol gel process can also be incorporated with azo BC lm lithography. A hexagonally ordered SiO2 nanorod array with mesochannels aligned along the longitudinal axes was obtained for the rst time, as shown in Fig. 12.24 (Chen et al., 2008). The mesochannels inside the SiO2 nanorods were aligned perpendicularly to the substrate and had a diameter of B2 nm. The aspect ratio of the SiO2 nanorods was controlled by the immersion time and the lm thickness. A height of several hundreds of nanometers can be achieved. This hierarchically ordered

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In a simple world, with no interfering senders, the receiver would receive the encoded bits, Zi,m, and recover the original data bit, di, by computing: di = (1/M) m=1,M Zi,m cm (Equation 53-2)

VUV(172 nm)

The basic principle is that energy (heat) is removed by a heat exchanger from compressed air which then performs work by passing through a turbine which drives the compressor, and hence energy is transferred resulting in a reduction in temperature and pressure. The resultant air is then at a temperature (and to a small extent pressure) below that at which it entered the compressor. Air cycle refrigeration systems are used to cool engine bleed air down to temperatures required for cabin and equipment conditioning. Since engine bleed air is generally available, air cycle refrigeration is used because it is the simplest solution to the cooling problem, ful lling both cooling and cabin pressurisation requirements in an integrated system. However, although lighter and more compact than vapour cycle, air cycle systems have their limitations. Very large air ows are required in high heat load applications which require large diameter ducts with the corresponding problems of installation in the

The reader might want to work through the details of the example in Figure 53-4 to see that the original data bits are indeed correctly recovered at the receiver using Equation 53-2

Figure 12.23. Scheme of selective absorption of Au nanoparticles on amphiphilic surfaces of azo LCBC lms with well-ordered microphase separation. D is the diameter of irradiated area. Source: Reproduced with modi cations from Watanabe et al., 2007.

file:///D|/Downloads/Livros/computa o/Computer%20NeDown%20Approach%20Featuring%20the%20Internet/LANhtm (5 of 16)20/11/2004 15:52:35

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