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one syn conformer that has a meso-like structure analogous to the meso-CS ansa metallocenes and two anti enantiomeric conformers that together have a rac-like structure analogous to the rac-C2 ansa metallocenes. The mechanism originally proposed to explain the formation of isotactic atactic stereoblock polymer involved a slow rate of interconversion of the anti (rac) and syn (meso) conformers, a rate slower than the propagation rate, but faster than the chain breaking reactions. During the lifetime of a propagating chain, the propagating species alternates between the anti (rac) and syn (meso) conformers. The conformers are chiral and achiral, respectively, analogous to the corresponding isoselective rac-C2 ansa metallocene and aselective meso CS ansa metallocene. The result is a stereoblock polymer with alternating isotactic and atactic blocks. The (m) fraction is in the range 0.6 0.7 for polymerization at high monomer concentration in the temperature range 25 to 25 C [Resconi et al., 2000]. Substituents on the phenyl groups of the 2-phenylindene ligands, especially meta substituents, slow down the conformational interconversion, and this increases the isotacticity of the polymerization. Both steric and electronic factors operate to affect the interconversion of conformers. Bis(2-phenylindene)zirconium dichloride/MAO yields polypropene with (mmmm) 0.33 for polymerization of liquid propene at 20 C. 3,5-Di-t-butyl and 3,5-di uoromethyl substituents increase (mmmm) above 0.70 [Lin and Waymouth, 2002; Wilmes et al., 2002a,b].



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12 10

More recent work indicates that the conformational equilibrium is not between rac and meso conformers, but between the two enantiomeric anti conformers of the rac mixture [Busico et al., 2002]. The prime support for this interpretation is the nature of the stereoerrors in the isotactic sequences of the polymer. The stereoerrors are XXXV instead of XXXVI. The isotactic sequences consist of all-R isotactic blocks alternating with all-S isotactic blocks.

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Polymerization with oscillating metallocenes is complicated because solvent fractionation of the polymer product shows separate fractions highly atactic, mostly isotactic, and isotactic atactic stereoblock. The mechanism of this phenomenon is not clear. It may result from the initiators not being perfectly single-site initiators. There is some evidence that a metallocene initiator may consist of more than one species, and that each species produces a different stereochemical result (Sec. 8-5g-1, 8-5h-1).





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Steps to convert excel document to PDF program matically:
Steps to convert excel document to PDF program matically:

As the Report Wizard guides you through the steps for building a report, you are asked to decide upon a sort order. You can sort records by up to four fields, in ascending or descending order. The wizard also prompts you to select a layout for the report. Options include Stepped, Block and Outline, in either portrait or landscape mode. (Note that you can change other design aspects of the report by opening it in Design view.) After you create the report, you can print it.

250 500 750 1000

8-5g 8-5g-1

Coinitiators Methylaluminoxane (MAO)

6 4 2 0 250 500 750 1000

MAO, the most widely used Lewis acid coinitiator (activator) (Eq. 8-52), is obtained by a controlled hydrolysis of trimethylaluminum (TMA). In spite of considerable research, the detailed structure of MAO remains unclear [Chen and Marks, 2000; Kissin and Brandolini, 2003; Pedeutour et al., 2001; Wang et al., 2001; Ystenes et al., 2000]. MAO is probably a mixture of linear, cyclic, and three-dimensional structures containing the repeat unit XXXVII with n 5 20.

....,

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How to convert Excel to PDF using C# and VB.NET | WinForms - PDF
Oct 31, 2018 · Steps to convert excel document to PDF programmatically: Create a new C# console application project. Install the Syncfusion.ExcelToPdfConverter.WinForms NuGet packages as reference to your .NET Framework application from NuGet.org. Include the following namespaces in the Program.cs file.

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Convert Excel file to PDF in C# and VB.NET. GemBox. Spreadsheet enables you to easily convert an Excel file to different file formats in C# and VB.NET. For example, you can convert Excel file to a different spreadsheet format (XLSX, XLS , ODS, CSV, or HTML) or to PDF , XPS, and image formats.
Convert Excel file to PDF in C# and VB.NET. GemBox. Spreadsheet enables you to easily convert an Excel file to different file formats in C# and VB.NET. For example, you can convert Excel file to a different spreadsheet format (XLSX, XLS , ODS, CSV, or HTML) or to PDF , XPS, and image formats.

The exact composition in terms of the relative amounts of linear, cyclic, and three-dimensional structures and molecular weight probably varies with the detailed method of preparation. Most workers favor a three-dimensional spherical cagelike structure as the structure responsible for MAO s coinitiator property. However, this may be an oversimpli cation, and more than one structure may be responsible for the observed activation of metallocenes by MAO. After activation of a metallocene initiator, MAO forms the basis of the counterion, (ClMAO) or (CH3 MAO) . MAO normally contains TMA in two forms: free TMA and

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associated TMA. Free TMA is undesirable since it decreases initiator activity and polymer molecular weight and also changes the kinetic pro le from decay to buildup (behaviors 4 and 1-3, respectively, in Fig. 8-15). Free TMA can be removed by vacuum drying. It is very dif cult to remove the associated TMA and MAO preparations almost always contain associated TMA. In fact, associated TMA may be important in the overall role of MAO as a coinitiator. MAO is needed in large excess relative to the metallocene initiator, usually 102 104 : 1, to achieve high activities and stable kinetic pro les. MAO is usually added rst in a polymerization system, and a portion may actually serve the function of destroying deleterious impurities prior to the addition of the metallocene initiator. Otherwise, the impurities would destroy the metallocene if the metallocene were added rst. The structure of MAO is poorly de ned and varies with preparation conditions, but it performs well in activating the metallocene initiator. The use of MAO is complicated by its lack of long-term storage stability. It is usually supplied by manufacturers as a cloudy solution of MAO in toluene; MAO has very low solubility in aliphatic solvents. Precipitation is often observed on long standing, especially if the container is frequently opened and exposed to moisture and oxygen. This precipitation, if not too extensive, may not affect the utility of the MAO as a coinitiator. A modi ed MAO, known as MMAO, offers some improvement in storage stability and improved solubility in aliphatics. MMAO is prepared by controlled hydrolysis of a mixture of trimethylaluminum and triisobutylaluminum.

interaction time. In (a) and (b), gtint = 22, corresponding to about 3.5 Rabi cycles. In (c) and (d), gtint = 0.2, which corresponds to a Rabi oscillation of only about 11.5 degrees.

CH3 Al(CH3)2 CH3 XXXIX [CH3MAO]

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Excel to PDF C# library - Stack Overflow
Interop.Excel.Application excelApplication; Microsoft.Office.Interop.Excel.​Workbook ... DisplayAlerts = false; // Open the workbook that you wish to export to PDF ...

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Lightweight and fast library written in C# for reading Microsoft Excel files (2.0-​2007). ... convert and print spreadsheet files (XLSX, XLS, ODS, CSV, HTML, PDF or ...












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