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New twist for magnetic monopoles Physics World, 17(l): 18-19, January 2004 422 E Mach The Principles of Physical Optics: An Historical and Philosophical Treatment Dover, New York, 1961 Reprint of the 1926 edition of this book 423 J Maddox The wonders of the microlaser Nature, 373(6510):101,January 12, 1995 424 T H Maiman Stimulated optical radiation in ruby Nature, 187(4736):49~94, August 6, 1960 Online at http://wwwcosetiorg/maimanhtm 425 M A Maize and C A Burkholder Electric polarizability and the solution of an inhomogeneous differential equation American Journal of Physics, 63(3):244247, March 1995 426 M A Maize, S Paulson, and A D' Avanti Electric polarizability of a relativistic particle American Journal of Physics, 65(9):888-892, September 1997 427 V Majernik Quaternionic formulation of the classical fields Advances in Applied Clifford Algebras, 9(1): 119-130, 1999 428 L Mandel Configuration-space photon number operators in quantum optics Physical Review, 144(4):1071-1077, April 29, 1966 429.



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where n may have any value from zero to in nity. The multifunctional monomer Af is considered a branch unit, while the segments between branch units are de ned as chain segments. The branch units occur on a polymer chain at the branch points (Fig. 1-2). In nite networks are formed when n number of chains or chain segments give rise to more than n chains through branching of some of them. The criterion for gelation in a system containing a reactant of functionality f is that at least one of the f 1 chain segments radiating from a branch unit will in turn be connected to another branch unit. The probability for this occurring is simply 1= f 1 and the critical branching coef cient ac for gel formation is





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L Mandel and E Wolf Optical Coherence and Quantum Optics Cambridge University Press, Cambridge, 1995 430 P D Mannheim The physics behind path integrals in quantum mechanics American Journal of Physics, 51(4):328-334, April 1983..

ac 1 f 1 2-145

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The f in Eq. 2-145 is the functionality of the branch units, that is, of the monomer with functionality greater than 2. It is not the average functionality favg from the Carothers equation. If more than one type of multifunctional branch unit is present an average f value of all the monomer molecules with functionality greater than 2 is used in Eq. 2-145. When a f 1 equals 1 a chain segment will, on the average, be succeeded by a f 1 chains. Of these a f 1 chains a portion a will each end in a branch point so that a2 f 1 2 more chains are created. The branching process continues with the number of succeeding chains becoming progressively greater through each succeeding branching reaction. The growth of the polymer is limited only by the boundaries of the reaction vessel. If, on the other hand, a f 1 is less than 1, chain segments will not be likely to end in branch units. For a trifunctional reactant f 3 the critical value of a is 1. 2 The probability a is now related to the extent of reaction by determining the probability of obtaining a chain segment of the type shown in Eq. 2-144. The extents of reaction of A and B functional groups are pA and pB , respectively. The ratio of all A groups, both reacted and unreacted, that are part of branch units, to the total number of all A groups in the mixture is de ned by r. This corresponds to the same de nition of r as in Eq. 2-143. The probability that a B group has reacted with a branch unit is pB r. The probability that a B group has

431 M A M Marte and S Stenholm Paraxial light and atom optics: The optical SchrOdingerequation and beyond Physical Review A, 56(4):2940-2953, October 1997 432 L Martin-Moreno, F J Garcia-Vidal, H J Lezec, K M Pellerin, T Thio, J B Pendry, and T W Ebbesen Theory of extraordinary optical transmission through subwavelength hole arrays Physical Review Letters, 86(6): 1114-1117, February 5,2001 433 J Mathews and R L Walker Mathematical Methods of Physics AddisonWesley, Menlo Park, CA, 2nd edition, 1973 434 J C Maxwell On physical lines of force: I The theory of molecular vortices applied to magnetic phenomena Philosophical Magazine, Fourth Series, 21(139):161-175, March 1861 435 J C Maxwell On physical lines of force: II The theory of molecular vortices applied to electric currents Philosophical Magazine, Fourth Series, 21(140141):281-291,338-348, April-May 1861 See also the first part of this paper [434] 436 J McKeever, A Boca, A D Boozer, J R.

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