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TABLE 3-9 Retarder/Inhibitor Chain-Transfer Constantsa;b Monomer Acrylonitrile Methyl methacrylate Compound Aniline p-Benzoquinone Aniline (60 C) p-Benzoquinone Hydroquinone (45 C) Phenol Pyrogallol (45 C) 4-t-Butyl catechol (45 C) Aniline p-Benzoquinone (60 C) Hydroquinone (60 C) Phenol (60 C) 2,4,6-Trinitrophenol Pyrogallol (60 C) 4-t-Butyl catechol (60 C) Aniline Hydroquinone Phenol (45 C) p-Nitrophenol Pyrogallol 4-t-Butyl catechol (60 C) CZ 104 44 1:3 104 4.2 4:5 104 7.0 2.5 26 45 20 23 105 3.6 14 2:1 105 370 36 102 149 70 102 120 8:9 104 50 103 36 102

(F.38)



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Sep 27, 2013 · Basically, I just want to convert an image to a PDF exactly as is (copying the page size from the image size and with no margin). The first step…

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Diallyl (iso)phthalate, see Allyl resins Diastereotopic, 666 667 Dicalite, 308 Diels-Alder dimer, 226 227 Diels-Alder reaction, 155, 183 Diene: copolymerization crosslinking, 521 523 cyclopolymerization, 524 527 crosslinking of polymer, 738 742. See also Crosslinking polymerization, 310 311, 689 695 stereoisomerism, 689 695. See also Stereoisomerism in polymers; Stereoselective polymerization Differential scanning calorimetry, 29 32 Diffusion clock method, 393 396 Diffusion-controlled termination: radical copolymerization, 505 506 radical polymerization, 282 289 Diffusion in coordination polymerization, 658 659, 661 662 a-Diimine chelate initiator, 686 688 Diisotactic polymer, 624 626 Dilatometry, 209 N,N,N,N-Dimethyldiallylammonium chloride, see Allyl resin Dimethylketene polymerization, Diol prepolymer, 131 Dispersant, see Surfactant Dispersion polymerization, 298 Disproportionation, 205 206, 239 240 Dissociative GTP, 421 422 Disyndiotactic polymer, 624 626 Ditacticity, 624 Divergent synthesis, 177 180 DMT process, 93 Dopant, 164 Double-brush polymer, 759 Double-strand polymer, see Ladder polymer Drying, 120, 737 738 Drying oil, 119 DSC, see Thermal analysis DT, see Degenerative transfer Dual-side metallocene, 674 Durel, 141 Dyad, 635 Dyad tacticity, 635 637 Dylene, 304 Dynel, 308 EB, see electron beam technology Ekonol, 159





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Then, as f(x)

Elastic elongation, 34 Elastomer, crosslinking, 738 742 commercial, 35 36, 142 143, 698 699, 738 properties, 34 35 Electrochemical polymerization, see Electroinitiated polymerization Electroinitiated polymerization, 165 166, 227 228, 380 381, 414 416 Electrolytic polymerization, see Electroinitiated polymerization Electron beam technology, 226 Electron spin resonance spectroscopy, 234 235 Electron transfer, 414 416 Electrostatic effect, 733 735 Elongation, 34 Elvax, 530 Emeraldine salt, 165 166 Emulsi er, see Surfactant Emulsion polymerization: chain transfer, 361 compartmentalization, 357, 365 366 components, 351 353, 364 emulsi er, 328, 351, 363 364 energetics, 365 initiation, 363 intervals, 356 inverse emulsion system, 367 kinetics, 354 360 living, 368 369 mechanism, 353 356 micelle, 352 microemulsion, 367 miniemulsion, 367 miscellaneous components, 351 352, 364 molecular weight, 360 361 molecular weight distribution, 365 366 monomer droplet, 352 353 number of radicals per particle, 357 358 Ostwald ripening, 367 particle nucleation, 354 particle number, 354 356, 362 363 particle size distribution, 365 366 propagation, 364 radical absorption, 358 radical desorption, 357 359 rate, 354 360 Smith-Ewart behavior, 351, 358 surfactant, 328, 351, 363 364 surfactant-free system, 366 367 termination, 364 utility, 350 351 Enantiomer, 621

0, we can write (F.39)

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Enantiomer-differentiating polymerization, 705 706 Enantioselective, 666 667 Enantiomorphic site control, 642 644 statistical model, 711 712 Enantiotopic, 643, 666 667 End-blocking, 448 449 End-capping, 448 449 End-group, 74 End unit, 467 Energetics of polymerization, see Activation energies; Thermodynamics of polymerization Engineering plastic, 96 Enolate anion, Enthalphy, 88, 275 Entropy, 275 Enzymatic polymerization, 180 182, 584 585 Enzyme, 180 EPDM rubber, see Ethylene-propylene-diene monomers polymer Epichlorohydrin, 128 130 Epiclomer, 569 EPM rubber, see Ethylene-propylene monomers polymer Episul de, 588 Epoxide polymerization, see Anionic ring-opening polymerization; Cationic ring-opening polymerization; Stereoselecctive polymerization Epoxy polymer, 128 130, 548 554 Equal reactivity of functional groups, 41 44, 54 57 Equilibrium monomer concentration, 280 Equilibrium polymerization, see Depropagation, Reversible polymerization Erythro, 625 626, 632 Erythrodiisostactic polymer, 625 626, 632 Erythrodisyndiotactic polymer, 625 626, 632 Escorene, 530 Estamid, 143 Estane, 142 Ethylene copolymer, 530 531 Ethylene-propylene-diene monomer rubbers, 698, 738 Ethylene-propylene monomers rubber, 698 Ethylene-vinyl acetate copolymer, 530 531 Ethylene-vinyl alcohol copolymer, 530 531, 748 EVA, see Ethylene-vinyl acetate copolymer EVOH, see Ethylene-vinyl alcohol copolymer Exchange reaction, 83, 144 Expandable polystyrene, 304 Explicit penultimate model, 513 515 Extended chain crystallinity, 26 27

Another way to justify (F.39) is to remember that the delta function is the derivative ofthe Heaviside step function O(x). So if we write

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