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Data Field (46 to 1500 bytes): This field carries the IP datagram The Maximum Transfer Unit (MTU) of Ethernet is 1500 bytes This means that if the IP datagram exceeds 1500 bytes, then the host has to fragment the datagram, as discussed in Section 44 The minimum size of the data field is 46 bytes This means that if the IP datagram is less than 46 bytes, the data field has to be "stuffed" to fill it out to 46 bytes When stuffing is used, the data passed to the network layer contains the stuffing as well as an IP datagram The network layer uses the length field in the IP datagram header to remove the stuffing Destination Address (6 bytes): This field contains the LAN address of the destination adapter, namely, BB-BB-BB-BB-BB-BB When adapter B receives an Ethernet frame with destination address other than its own physical address, BB-BB-BB-BB-BB-BB, or the LAN broadcast address, it discards the frame Otherwise, it passes the contents of the data field to the network layer Source Address (6 bytes): This field contains the LAN address of the adapter that transmits the frame onto the LAN, namely, AA-AA-AA-AA-AA-AA Type Field (two bytes): The type field permits Ethernet to "multiplex" network-layer protocols To understand this idea, we need to keep in mind that hosts can use other network-layer protocols besides IP In fact, a given host may support multiple network layer protocols, and use different protocols for different applications For this reason, when the Ethernet frame arrives at adapter B, adapter B needs to know to which network-layer protocol it should pass the contents of the data field IP and other data-link layer protocols (eg, Novell IPX or AppleTalk) each have there own, standardized type number Furthermore, the ARP protocol (discussed in the previous section) has its own type number Note that the type field is analogous to the protocol field in the networklayer datagram and the port number fields in the transport-layer segment; all of these fields serve to glue a protocol at one layer to a protocol at the layer above.



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Figure 13.5. Supramolecular structures formed by self-directed assembly in trans (left) or cis (right) forms.

file:///D|/Downloads/Livros/computa o/Computer%20Net%20Approach%20Featuring%20the%20Internet/ethernethtm (3 of 12)20/11/2004 15:52:37

The cards enable the pilot to locate the caption rapidly and to read from the cards a series of corrective actions Aircraft being built today tend to use Multi-Function Displays (MFDs) units.

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Brinker and coworkers proposed the structures of the trans and cis supramolecular assemblies (Fig. 13.5) (Liu et al., 2002). The two urea groups in a BSUA molecule form multiple intermolecular hydrogen-bonding which, in combination with the p p stacking of the azobenzene group, drives the selfassembly of BSUA into a highly ordered lamellar structure. As detected using XRD, the d-spacings of the cis assembly and the trans assembly are ca. 1.9 and 2.2 nm, respectively. Because of the extensive hydrogen-bonding interactions, the trans2cis isomerization is severely inhibited in the supramolecular solids. This result indicates that realization of the full potential of transduction of optical excitation into work for applications in nanomechanical devices will require BSUA to be suf ciently dilute or chemically modi ed to prevent extensive hydrogen-bonding. Polarized light microscopy images (Fig. 13.4, right column) shows that BSUA solids are bright and colorful, demonstrating that they have the birefringence that is very common in crystals. The anisotropic property of the BSUA compound is indicative of an ordered molecular assembly in which the light propagation in the direction parallel to the azobenzene axis is different from that perpendicular to the azobenzene axis.

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Cyclic Redundancy Check (CRC) (4 bytes): As discussed in section 52, the purpose of the CRC field is to allow the receiving adapter, adapter B, to detect whether any errors have been introduced into the frame, ie, if bits in the frame have been toggled Causes of bit errors include attenuation in signal strength and ambient electromagnetic energy that leaks into the Ethernet cables and interface cards Error detection is performed as follows When host A constructs the Ethernet frame, it calculates a CRC field, which is obtained from a mapping of the other bits in frame (except for the preamble bits) When host B receives the frame, it applies the same mapping to the frame and checks to see if the result of the mapping is equal to what is in the CRC field This operation at the receiving host is called the CRC check If the CRC check fails (that is, if the result of the mapping does not equal the contents of the CRC field), then host B knows that there is an error in the frame Preamble: (8 bytes) The Ethernet frame begins with an eight-byte preamble field Each of the first seven bytes of the preamble is 10101010; the last byte is 10101011 The first seven bytes of the preamble serve to "wake up" the receiving adapters and to synchronize their clocks to that of the sender's clock Why should the clocks be out of synchronization Keep in mind that adapter A aims to transmit the frame at 10 Mbps, 100 Mbps or 1 Gbps, depending on the type of Ethernet LAN However, because nothing is absolutely perfect, adapter A will not transmit the frame at exactly the target rate; there will always be some drift from the target rate, a drift which is not known a priori by the other adapters on the LAN A receiving adapter can lock onto adapter A's clock by simply locking onto the bits in the first seven bytes of the preamble The last two bits of the eighth byte of the preamble (the first two consecutive 1s) alert adapter B that the "important stuff" is about to come When host B sees the two consecutive 1s, it know that the next six bytes is the destination address An adapter can tell when a frame ends by simply detecting absence of current.

In 1992, Kresge and coworkers at Mobil invented the so-called MCM-41 mesoporous materials that have a hexagonal arrangement of monosized mesopores with pore size adjustable from 1.5 nm to 10 nm (Kresge et al., 1992).

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