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cis conformation in the as-prepared lm. Using a molar absorption coef cient (e) of 2.59 104 M 1 cm 1 for the trans isomer of TSUA, the concentration of the trans isomer in the lm was estimated to be 0.27, 0.22, 0.20, and 0.17 M for lm samples in Fig. 13.25d, a, c and b, respectively. It is dif cult to estimate the concentration of the cis isomer in the lm because the e value of the n p* transition of the cis isomer is unknown. It is reasonable that a portion of the azobenzene ligands are in the cis conformation because the gel shrinkage during the lm formation process caused by ethanol evaporation leads to a portion of the azobenzene ligands adopting the cis conformation with shorter molecular length. Only upon powerful stimulation (heat) to overcome the force (B200 pN/ azobenzene ligand [Hugel et al., 2002]) involved in the conformational change does the cis isomer change to the trans isomer that has a longer molecular length. 13.4.2.3. Stress Development and Relaxation of Azobenzene-Modi ed Polysilsesquioxane Gels. The dimensional change associated with the trans 2cis isomerization of the azobenzene ligands contained in the polysilsesquioxane gel lms causes the gel network to shrink or expand in response to light stimuli, which involves stress development and relaxation of the lm. Brinker and coworkers used a homemade beam bending setup to observe the stress behavior in response to UV light irradiation. The in-plane stress during alternating UV light exposure and dark exposure is calculated from Stoney s equation as follows: s Es ds2 d Vs df



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[Nerds] Triumph of the Nerds, Web site for PBS television special, http://wwwpbsorg/nerds [FRForum] Frame Relay Forum, http://wwwfrforumcom [Hill] Hill Associates Web site, http://wwwhillcom [Goralski] W Goralski, Frame Relay for High-Speed Networks, John Wiley, New York, 1999 [RFC 2427] C Brown and A Malis, "Multiprotocol Interconnect over Frame Relay," RFC 2427, September 1998

3L2 1

By contrast with the bleed air system already described which provides energy or power for a number of diverse aircraft systems, the pitot static system is an instrumentation system used to sense air data parameters of the air through which the aircraft is ying. Without the reliable provision of air data the aircraft is unable safely continue ight. The pitot static system is therefore a high integrity system with high levels of redundancy.

file:///D|/Downloads/Livros/computa o/Computer%20Netw20Approach%20Featuring%20the%20Internet/frameRelayhtm (5 of 5)20/11/2004 15:52:44

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where s is the in plane biaxial stress, Es is Young s modulus of the silicon substrate (1.48 1012 dynes/cm2), ds is the substrate thickness (75 mm), L is the substrate length, Vs is Poisson s ratio of the silicon substrate (0.18), df is the lm thickness, and d is the measured de ection of the silicon substrate (Fig. 13.26). Tensile stress corresponds to a positive de ection (d), which is in an upward direction. Negative d generates contraction stress. Stoney s equation is valid, provided dscdf, dscd, L is greater than twice the width of the substrate, and the elastic modulus of the substrate is much larger than that of the lm. The photoresponsive gel lms were deposited on the silicon substrates using the casting or dip-coating methods. Figure 13.27 shows a typical stress response of the photoresponsive gel lms (225 nm in thickness) in situ during UV light exposure. Before the UV light (l = 320 nm) was turned on, the beam-bending system was zeroed by stabilizing it for half an hour. After the UV light was turned on, the tensile stress (positive direction) that comes from the trans-cis isomerization of the azobenzene ligands increases rapidly to a plateau value of ca. 0.58 MPa in 2 min. The extended UV light irradiation for ca. 26 min did not change the plateau value, which was the photostationary state of the trans-cis isomerization. Then the UV light was turned off and the whole system was kept in the dark. The corresponding cis-trans thermal isomerization caused the stress

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relaxation. The stress decreased gradually to a new plateau value of 0.20 MPa in ca. 70 min, which was related to the equilibrium state of the cis-trans thermal isomerization. This stress development and relaxation triggered by UV light was repeated for three cycles. In the latter two cycles, the stress curves were almost the same, demonstrating that the stress development and relaxation in response to UV light are reversible and reproducible.

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There are two key parameters which the pitot static system senses: Total pressure Pt is the sum of local static pressure and the pressure caused by the forward ight of the aircraft. The pressure related to the forward motion of the aircraft by the following formula: Pressure = V2 Where the velocity is the air density of the surrounding air and V is

Stress (MPa)

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