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The principle and applications of classical Raman scattering are discussed in previous chapters. Using this technique there are, however, some serious problems to deal with: The poor efficiency of the Raman effect, where even in favorable cases the conversion of the incident laser photons into the Raman signal is only of the order of 10 ', makes it very difficult to record Raman spectra from poor scatterers or from materials with very low concentration values. In molecules belonging to specific point groups (e. g. Cg, Dg, Cgv, C4h, Dzh, D 3 h , D 6 h , etc.) there exist silent vibrational modes which are neither Raman nor IR active. Certain molecular systems exhibit high fluorescence quantum yield and even weak fluorescence signals may be strong enough to totally obscure the Raman signal. In classical Raman spectroscopy the spectral resolution of the observed bands is often limited by the resolution of the monochromator, whereas the laser line width in most cases is small enough and does not contribute appreciably to the observed Raman band width. There are several techniques to avoid or overcome one or the other problem. Resonance Raman scattering, for instance, is able to enhance the Raman scattering cross section by orders of magnitude. The resonance Raman effect can be observed when the exciting frequency is close to (pre-resonance Raman effect) or even coincides (rigorous resonance Raman effect) with dipole allowed electronic transitions in the molecule un-

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Because VLL CAC is a control plane booking function and does not track the BW consumption in the data plane, all three SDPs consider that the LSP s bandwidth is their own, as if there are three 100-Mbps LSPs SDP can also use LDP-LSPs or GRE tunnels as transport tunnels LDP-LSPs and GRE tunnels do not have tunnel bandwidth reservation capability Therefore, an SDP using GRE or LDP tunneling has zero available bandwidth from VLL CAC s perspective However, if a VLL pseudowire with bandwidth booking is established over (bound to) an SDP using GRE or LDP tunneling, the pseudowire will come operationally up This is because the system is aware that the SDP is LDP- or GREtunneled even though the CAC fails The system then generates warnings and traps to notify the system of the CAC failure Static-LSP can also be added into RSVP-TE LSP-tunneled SDPs.

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What is tolerably clear, therefore, is that once architects and engineers are actually or constructively aware of a defect in the design, or in the works as they are being constructed, they ought then to decide what proper steps should be taken or recommended to investigate the problem and to remedy it; and they should advise their clients and instruct the builder accordingly. However, after practical completion the position will very much turn on the proper construction of the contractual arrangements. There may be no duty to review the design, even though there may be a duty to inspect for defects in workmanship and materials. If there is a duty to review the design post-practical completion, it is a duty (subject to any express terms to the contrary) that may arise only if there is good reason to review the design, and, as it was explained in New Islington: What is a good reason must be determined objectively, and the standard is set by reference to what a reasonably competent architect would do in the circumstances.

Note that static-LSP has no BW reservation and its addition into an SDP does not increase the SDP s maximum or available BW If VLL CAC is performed on an SDP with all static-LSPs, the VLL CAC will fail, and the pseudowire is flagged as pseudowire not forwarding..

JAXP stands for Java API for XML Processing. It is a set of Java classes and interfaces specifically designed to be used in a program to make it capable of reading, manipulating, and writing XML-formatted data. It includes complete parsers for SAX1 and SAX2 and the two types of DOM: DOM Level 1 and DOM Level 2. Most of this book explores the use of parsers in extracting

Motivation (Why)

BRDY#

As mentioned, a fourth type of dimer reactivity is dissociation of a CO ligand from the dimer. Generally, this type of reactivity increases in e ciency relative to M M photolysis as the radiation energy increases.28 In solution, this type of reactivity generally leads to substitution. However, in the case of the Cp2Mo2(CO)6 molecule, the reaction in equation 21 occurs.24 (Among the dimers, this reaction to form a triply bonded product is unique to the Mo and W species.)

400 Wavelength (nm)

TCP normally establishes a connection by a threeway handshake (Figure2.50)

26

# /etc/services: # service-name port/protocol [aliases ...] [# comment] chargen 19/tcp ttytst source chargen 19/udp ttytst source ftp-data 20/tcp ftp-data 20/udp # 21 is registered to ftp, but also used by fsp ftp 21/tcp ftp 21/udp fsp fspd ssh 22/tcp # SSH Remote Login Protocol ssh 22/udp # SSH Remote Login Protocol telnet 23/tcp telnet 23/udp # 24 - private mail system smtp 25/tcp mail

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