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From the right-hand side of the first line of (C.4) and the last line, we obtain, after canceling out p, (C.5) ei9 = cos () + i sin ().

where a0 is the absolute value (without sign) of a for the pure enantiomer. Combination of Eqs. 8-80 through 8-82 yields

1 p r 1 1 a=a0 2 r 1 S r 0 r 1 a=a0 R 0 R 0 S 0 r 1 8-83



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This is Euler's famous equation that unites algebra and geometry. It is such a remarkable formula that Feynman even called it a mathematical jewel (see Chap. 22 of [205]). Hamilton knew this beautiful geometrical interpretation of complex numbers and wanted to generalize it to our three-dimensional space. He long tried to find the number that would produce a rotation out of the two-dimensional complex plane into a third dimension. When he finally cracked this problem, he discovered that in order to carry on with the assumed connection between rotation and multiplication, his generalization of complex numbers had to have/our rather than just three dimensions. This is one of the best documented discoveries in mathematics. The very moment of discovery is almost something out of a Hollywood film, as can be seen from this extract from a letter by Hamilton to his son Archibald telling of the quatemion discovery [267]:





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TABLE 3-1 Types of Chain Polymerization Undergone by Various Unsaturated Monomers Type of Initiation Radical Cationic Anionica

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... (you) used to ask me, "Well. Papa. can you multiply triplets " Whereto I was always obliged to reply, with a sad shake of the head: "No. I can only add and subtract them." But on the 16th day of the same month-which happened to be a Monday. and a Council day of the Royal Irish Academy-I was walking in to attend and preside, and your mother was walking with me, along the Royal Canal ... An electric circuit seemed to close; and a spark flashed forth, the herald (as I foresaw, immediately) of many long years to come of definitely directed thought and work, by myself if spared. and at all events on the part of others, if I should even be allowed to live long enough distinctly to communicate the discovery. Nor could I resist the impulse-unphilosophical as it may have been-to cut with a knife on a stone of Brougham Bridge.7 as we passed it, the fundamental fonnula with the symbols, i, j, k; namely. i 2 = j2 = k 2 = ijk = -1 which contains the solution of the Problem....

Monomers Ethylene 1-Alkyl alkenes (a-ole ns) 1,1-Dialkyl alkenes 1,3-Dienes Styrene, a-methyl styrene Halogenated alkenes Vinyl esters (CH2 CHOCOR) Acrylates, methacrylates Acrylonitrile, methacrylonitrile Acrylamide, methacrylamide Vinyl ethers N-Vinyl carbazole N-Vinyl pyrrolidone Aldehydes, ketones

To wrap column text around a picture or other object, click the picture or object, click the Format tab, click the Wrap Text button and then click the type of wrapping that you want to apply.

So what is this solution of the problem Hamilton's line of thought is clearly described in a letter he wrote to his friend John T. Graves, which was later published in the Philosophical Magazine [264]. Here we will argue differently. To extend the connection between multiplication by i and rotation in two dimensions to three dimensions, we must generalize the two-dimensional complex plane to include a third axis, orthogonal to both the real line and the ordinary i-imaginary line, as shown in Figure C.3. To rotate a vector on the real line by 90 degrees to take it to this new axis, we multiply the vector by a new number which we will call j. So any vector on the third axis is a real number multiplied by j. Notice that this third axis must be an imaginary rather than real axis; that is,

Includes anionic coordination initiation (Chap. 8).

(C.6)

polymerization. The polymerization of the carbon carbon double bond is by far the most important of the two types of monomers. The carbonyl group is not prone to polymerization by radical initiators because of its polarized nature:

as multiplying by j twice, just like multiplying by i twice, must correspond to rotation by 180 degrees because the new axis is also at 90 degrees from the real line. So far, all we have done has been to apply the same old idea of the ordinary imaginary line to a third dimension. But we cannot just apply that idea in a straightforward way, simply because with three dimensions we end up with two imaginary

3-3

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