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World Scientific, Singapore, 1998 Online at http://wwwnobelse 203 R P Feynman Quantum Electrodynamics Advanced Book Classics Perseus Publishing, Boulder, CO, January 1998 204 R P Feynman and A R Hibbs Quantum Mechanics and Path Integrals International Series in Pure and Applied Physics McGraw-Hill, New York, 1965 205 R P Feynman, R B Leighton, and M Sands The Feynman Lectures on Physics, volume 1 Addison-Wesley, Reading, MA, 1963 206 R P Feynman, R B Leighton, and M Sands The Feynman Lectures on Physics, volume 2 Addison-Wesley, Reading, MA, 1963 207 R P Feynman and S Weinberg Elementary Particles and the Laws of Physics: The 1986 Dirac Memorial Lectures Cambridge University Press, Cambridge, 1987 208 H Fielding The History of Tom Jones Penguin Popular Classics Penguin Books, London, 1994 This classic of eighteenth-century English comic novels is also available online at the Project Gutenberg Web site, http://gutenbergnet 209 P.



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Polycarbonates are polyesters of carbonic acid. The most important commercial polycarbonate is that based on 2,20 -bis(4-hydroxyphenyl)propane(bisphenol A) [Freitag et al., 1988; Sehanobish et al., 1996]. It has been synthesized by the reaction of the dihydric phenol with phosgene or by ester interchange with diphenyl carbonate:

Filipowicz, J Javanainen, and P Meystre Theory of a microscopic maser Physical Review A, 34(4):3077-3087, October 1986..

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Polymerization by the ester interchange route is carried out as a two-stage melt polymerization very similar to that described for poly(ethylene terephthalate) However, most industrial processes involve the phosgene reaction in a stirred interfacial polymerization Overall economics and easier control of polymer molecular weight favor the phosgene process over ester interchange Organic solvents such as chlorobenzene, 1,2-dichloroethane, tetrahydrofuran (THF), anisole, and dioxane are used The bisphenol A is usually dissolved in aqueous alkali to form the phenolate salt and then the organic solvent added followed by phosgene The organic solvent prevents the loss of phosgene by hydrolysis and precipitation of the polymer before it has reached the desired molecular weight Reaction temperatures in the range 0 50 C are used.

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Figure B.B Here we repeat the plots of Figure 8.7, adding polarization decay according to the theory described in Section 8.6. The solid line is the curve of the average number of photons. and the dotted line that of the Fano parameter. In (a), r = 103 and w = 10- 1 , resulting in the typical ordinary laser behavior with a well-defined threshold. In (b), r = 1.8 and w = 20, leading to complete disappearance of the laser threshold [174].

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Phase-transfer catalysts, such as quaternary ammonium and sulfonium salts and crown ethers, may be added to enhance the transfer of the phenolate salt across the interfacial boundary into the organic phase The polymerization is usually a two-stage reaction Oligomers are formed in the rst stage Tertiary amines are added in the second stage to catalyze the further reaction to high-molecular-weight polymer (An alternate route to polycarbonates, the ring-opening polymerization of cyclic polycarbonate oligomers, has some potential advantages over the step polymerization route; see Sec 7-5c) The IUPAC name of the polycarbonate based on bisphenol A is poly(oxycarbonyloxy-1,4phenylenedimethylmethylene-1,4-phenylene) (trade names: Lexan, Merlon, Calibre); it is usually referred to as polycarbonate or PC Although it can be crystallized Tm 270 C , most polycarbonates are amorphous Tg 150 C .

Recent advances in cooling and in optical mirror coating technologies have allowed the realization of a long-dreamed goal in cavity QED: to build a laser with a gain medium consisting of a single atom trapped inside a high-Q cavity, where it interacts with the single-mode radiation field in the strong-coupling regime [436] In ordinary lasers, masers, and even in the micromaser, the field is built up in the cavity by the contributions of many individual atoms In lasers, these atoms are usually all inside the cavity at the same time But the distances between atoms are large enough for them to interact with the field independently rather than cooperatively as in superradiance [255] This lack of cooperativity leads to the same sort of field buildup that is achieved in the micromaser, where atoms go through the cavity one at a time [214, 417].

Chain stiffening due to a combination of the benzene rings and bulky tetrasubstituted carbons in the polymer chain and the high Tg result in a good combination of mechanical properties over a considerable temperature range (15 130 C) PC has excellent resistance to acids and oxidants, better than PET, but is somewhat less resistant to bases compared to PET Polycarbonate is comparable to PET in resistance to organic solvents at ambient temperature At higher temperatures, PC is more resistant to aliphatic and aromatic solvents but less resistant to polar organic solvents Although its upper temperature limit (120 C for reinforced grades) and resistance to some solvents are low compared to other engineering plastics, polycarbonate nds many uses because of its exceptional transparency and impact resistance (toughness) as well as good dimensional and creep resistances.

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