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Figure 3.2. Synthesis route of poly(amide acid) gels containing azobenzene groups in their backbones and cross-linked with TAPB. Source: Hosono et al., 2007.



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(a) For a given audio application suppose four packets have arrived at the receiver with sample delays r4 - t4 , r3 - t3 , r2 - t2 , r1 - t1 Express the estimate of delay d in terms of the four samples (b) Generalize your formula for n sample delays (c) For the formula in part (b) let n approach infinity and give the resulting formula omment on why this averaging procedure is called an exponential moving average





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Seki and coworkers (2007) developed a new type of photoresponsive polymer gel by introducing an azobenzene moiety on the mobile cyclodextrin part as the sliding cross-linking unit. The synthesis scheme of the gel is shown in Fig. 3.3. The polyrotaxane (PR) was composed of a noncovalent complex between poly(ethylene oxide) and a-cyclodextrin (a-CD, lling ratio: 28% of full complexation) capped with an adamantanamine unit at each end. Onto the sliding ring of CD, three types of azobenzene derivatives (6Az10-, 6Az(EO)3-, and CNAz(EO)3-) were linked by esteri cation. Gelation reactions, namely, formation of gure-of-eight sliding cross-linkages of the azobenzene-linked PR, were performed with 1,1carbonyl diimidazole in dimethyl-sulfoxide (DMSO). Figure 3.4 indicates volume changes of the gels in DMSO upon irradiation of alternate UV and visible light. For all three systems, irradiation of UV light induced expansion of the gels, and visible light the reverse. The change in D/D0 for 6Az10-PR gel reached 25%, which corresponds to a volume change of 80% 100%. It is inferred that such an effective molecule-to-material transformation can be ascribed to the dynamic nature of the cross-linkers (Sakai et al., 2007).

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6) Repeat the above question for the estimate of average delay deviation 7) Compare the procedure described in Section 63 for estimating average delay with the procedure in Section 35 for estimating round-trip time What do the procedures have in common How are they different 8) Consider the adaptive playout strategy described in Section 63 (a) How can two successive packets received at the destination have timestamps that differ by more than 20 msecs when the two packets belong to the same talkspurt (b) How can the receiver use sequence numbers to determine whether a packet is the first packet in a talkspurt Be specific 9) Recall the two FEC schemes for Internet phone described in Section 63 Suppose that the first scheme generates a redundant chunk for every four original chunks Suppose the second scheme uses a low-bit-rate encoding whose transmission rate is 25% the transmission rate of nominal stream (a) How much additional bandwidth does each scheme require How much playback delay does each scheme add (b) How do the two schemes perform if at most one packet is lost in every group of five packets Which scheme will have better audio quality (c) How do the two schemes perform if at most one packet is lost in every group of two packets Which scheme will have better audio quality

CH3(CH2)5

10) How is the interarrival time jitter calculated in the RTCP reception report Hint: Read the RTP RFC 11) Suppose in a RTP session there are S senders and R receivers Use the formulas at the end of Section 64 to show that RTCP limits its traffic to 5% of the session bandwidth 12) (a) How is RSTP similar to HTTP Does RSTP have methods Can HTTP be used to

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6Az(EO)3

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CNAz(EO)3

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Figure 3.3. Synthesis scheme of azobenzene-containing slide-ring gels. Source: Sakai et al., 2007.

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