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assembly produced by an electrostatic LbL technique. LbL deposition was introduced in the early 1990s (Lvov et al., 1993) and has since gained a great popularity in the fabrication of thin lms of different materials from simple ionic species to colloidal particles and biological macromolecules (Hammond, 2000; Decher et al., 1998). These solid lms consist of adjacent layers of oppositely charged polyelectrolytes and different other low molecular materials, nanoparticles, colloids, etc. In this case, ionic interaction is not only used to form a molecular complex but also results in layered structure at a molecular level. The lms are manufactured by subsequent dipping of a substrate in solutions of these oppositely charged species (Fig. 2.6). According to the authors, LbL lms, which are self-assembled layered structures, could be considered as solid-state supramolecular complexes formed by ionic interactions. Azobenzene-containing materials also found their place with this popular technique and could be divided from chemical point of view to azobenzene-containing polyelectrolytes (Aldea et al., 2007; He et al., 2004; Wang et al., 2004a,b, 1998; Zucolotto et al., 2004b, 2002; Wu et al., 2001; Lee et al., 2000; Balasubramanian et al., 1998; Lvov et al., 1997), with azobenzene moieties in main- or side chain, and low-molecular-weight azobenzene derivatives (Zucolotto et al., 2003; dos Santos et al., 2002; Shinbo et al., 2002; Ziegler et al., 2002; Dragan et al., 2001; He et al., 2000; Advincula et al., 1999; Saremi and Tieke, 1998); some of them are conventional ionic azodyes. The requirement and restriction to azodye in this method is a presence of at least two charged groups to be able to bind to oppositely charged sites in the polyelectolyte chains from two different adjacent layers (Fig. 2.6). As second nonactive component, usual polyelectrolytes such as PDADMAC, PAH, PEI,



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Figure 63-3: Sending interleaved audio Interleaving can significantly improve the perceived quality of an audio stream [Perkins 1998] The obvious disadvantage of interleaving is that it increases latency This limits its use for interactive applications such as Internet phone, although it can perform well for streaming stored audio The major advantage of interleaving is that it does not increase the bandwidth requirements of a stream Receiver-based repair of damaged audio streams Receiver-based recovery schemes attempt to produce a replacement for a lost packet that is similar to the original As discussed in [Perkins 1998], this is possible since audio signals, and in particular speech, exhibit large amounts of short-term self similarity As such, these techniques work for relatively small loss rates (less than 15%), and for small packets (4-40ms) When the loss length approaches the length of a phoneme (5-100ms) these techniques breakdown, since whole phonemes may be missed by the listener A simple form of receiver-based recovery is packet repetition Packet repetition replaces lost packets with copies of the packets that arrived immediately before the loss It has low computational complexity and performs reasonably well Another form of receiver-based recovery is interpolation, which uses audio before and after the loss to interpolate a suitable packet to cover the loss It performs somewhat better than packet repetition, but is significantly more computationally intensive [Perkins 1998]

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Figure 9.19 EH 101 simpli ed electrical system (Courtesy of AGUSTA WESTLAND)

Figure 2.6. Schematic illustration of the preparation of alternate polycation polyanion multilayer assemblies onto a negatively charged substrate.

We conclude this section with a few words about streaming stored audio and video Streaming stored audio/video can also use sequence numbers, timestamps, and playout delay to alleviate or even eliminate the effects of network jitter However, there is an important difference between realtime interactive audio/video and streaming stored audio/video Specifically, streaming of stored audio/video can tolerate significantly larger delays Indeed, when a user requests an audio/video clip, the user may find it acceptable to wait five seconds or more before playback begins And most users can tolerate similar delays after interactive actions such as a temporal jump to the future This greater tolerance for delay gives the application developer greater flexibility when designing an stored media applications References [Bolot 1994] J-C Bolot and T Turletti, "A rate control scheme for packet video in the Internet," Proceedings of IEEE Infocom, 1994, pp 12161223 [Bolot 1996] J-C Bolot and Andreas Vega-Garcia, "Control Mechanisms for Packet Audio in the Internet," Proceedings of IEEE Infocom, 1996, pp 232-239 [Ramjee 1994] R Ramjee, J Kurose, D Towsley, and H Schulzrinn, "Adaptive Playout Mechanisms for Packetized Audio Applications in WideArea Networks," Proceedings of IEEE INFOCOM, 1994, pp 680-688 [Perkins 1998] C Perkins, O Hodson and V Hardman, "A Survey of Packet Loss Recovery Techniques for Streaming Audio," IEEE Network Magazine, September/October 1998, pp 40-47

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