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In the present example of 191Ir decay at room temperature, kBT 0025 eV, Eg0 01294 MeV, and mc 2 191 9315 MeV, which combine to give s 7 1022 eV, which, although small and an upper limit for gaseous atoms, is still six orders of magnitude larger than the natural linewidth of the state Therefore, it is not very often that we will be able to actually observe the natural linewidth of a g-ray emitting state This broadening works in favor of the absorption of a photon because it allows the thermal motion to help match the energy of the whole system, nucleus in the atom, to the photon energy In addition, as we have already discussed, the emission of a photon induces a recoil by the nucleus in order to conserve momentum.



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The energy of the photon is less than the energy of the nuclear transition by the amount Tr E2 /(2mc 2) g Notice that to conserve energy and momentum in the reverse process of g-ray absorption, a nucleus initially at rest will recoil with the same value of the recoil energy after absorbing a photon In the present example of 191Ir, the recoil energy is Tr 47 1022 eV and is a similar magnitude to the thermal Doppler shift for a gas We probably can expect the radioactive platinum atoms to be in a metal lattice so their motion would correspond to lattice vibrational motion and be somewhat less than that in a gas The relative energy distributions expected for the emitted and absorbed photons are shown in Figure 99 using the estimate of the thermal widths.

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Notice that the recoil energy moves the peaks apart, and the thermal width provides only a partial overlap It is these photons in the overlap region that have the proper energy to be absorbed; they must encounter a nucleus, of course, in order to actually be absorbed We might imagine that we could prepare a system that physically moves the source of the radiation toward the absorbing nuclei with suf cient speed that the Doppler shift compensates for the energy difference Restricting the motion.

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