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Hydrogen- and oxygen-terminated diamond surfaces are the most common stable terminations Recently, other surface terminations such as F-termination [21, 22], Cl-termination [22, 23], and NH2 -termination [22], have been reported H-termination of the diamond surface can be obtained upon exposure of the surface to H radicals, and is the usual termination of as-grown CVD diamond as it comes out of the growth reactor [24] This termination is generally stable under atmospheric conditions, and is also thought to be stable in aqueous electrolytes Upon hydrogenation, diamond surfaces are hydrophobic, with typical contact angles of around 90 The most striking feature of H-terminated surfaces is their surface conductivity, which is developed when the surface is exposed to atmosphere and is related to the C H surface dipole and the existence of surface adsorbates [7, 25] (see also the chapter by Ley in this book).



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The surface conductivity has enabled the design of diamond biosensors based on H-terminated surfaces O-terminated diamond surfaces can be obtained by different methods, such as O2 plasma, ozone exposure, wet oxidation, anodic electrochemical oxidation, etc The nature of the surface O-groups (ether, carbonyl, hydroxyl, etc) depends on the oxidation process, the surface orientation, and the sp2 /sp3 ratio [26] O-Terminated surfaces are hydrophilic, but the degree of hydrophilicity obviously depends on the type of terminal O-group When hydroxyl groups predominate, the surfaces are very hydrophilic with contact angles below 5 Depending on the O-groups at the surface, different reactivities towards functionalization are expected for the O-terminated surfaces The surface conductivity vanishes upon oxidation of diamond, which allows an easy method for the generation of conductive/nonconductive patterns at the surface F-termination of diamond has not received much attention, although it has been known for a long time [21].





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F-Terminated surfaces can be obtained upon exposure to F radicals; so far, atomic and molecular beams [21], as well as CF4 and C4 F8 plasmas [27 30] have been used F-Terminated surfaces have been reported to be stable in atmosphere and in aqueous electrolytes Notably, the uorination of diamond electrodes results in a much larger electrochemical potential window [30, 31] In addition, the high hydrophobicity of F-terminated electrodes is interesting for tribological applications, and could be used to control adsorption of biomolecules Cl-terminated diamond surfaces have been obtained by different methods, such as plasma and photochemical or thermal decomposition of Cl-contaning gases [22, 23, 32] Cl-Terminated surfaces are also hydrophobic, but their stability is an issue: C Cl surfaces can react in air or water to form C OH However, this high reactivity of C Cl surface bonds can be used as an intermediate state for surface functionalization [22, 33].

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NH 2 -terminated diamond surfaces have been prepared by the reaction of Cl-terminated or H-terminated surfaces with NH3 gas under UV irradiation [22] They have been proposed as intermediate states for further modi cation of diamond surfaces [34], as well as useful functional groups controlling the pH sensitivity of diamond surfaces [35]..

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Example 12.31 Suppose the same code and input sequence as in Example 12.13 is used. The following traces the execution of the algorithm when the scaled (integer) metric of Example 12.29 is used with A = 10. The step number n is printed every time the algorithm passes through point A in the flow chart.

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