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The di culty in isolation of cyclobutadiene lies not with any intrinsic instability of the molecule but with the self-reactivity which arises from an extremely narrow HOMO LUMO gap A second class of compounds also falls in this category, coordinatively unsaturated transition metal complexes In transition metals, the atomic n d orbital set may be partially occupied and/or nearly degenerate with the partially occupied n 1 sp n set Such a con guration permits exceptional reactivity, even toward C H and C C bonds These systems are treated separately in 13..



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axis, non-speci c attening of the T wave in the inferolateral leads (attributed to the horizontal displacement of the heart) and voltage criteria for left atrial enlargement (Otto et al., 2007). An increased incidence of false-positive criteria for inferior myocardial infarction has been described in obese individuals, probably due to diaphragmatic elevation (as also occurs in women in the nal trimester of pregnancy) (Figure 12.14). Obesity is also associated with increased occurrence of abnormal small highfrequency ECG potentials (SAECG) (Gami et al., 2007) and with abnormal late potentials that outlast the normal QRS period during sinus rhythm. All these abnormalities are found in obese patients with and without hypertension and/or diabetes. and often in the absence of clinical evidence of cardiac disease.

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491 Shearing Interferometry The interest in detecting fainter sources and smaller details has, in the recent years, fostered the development of large diameter optical systems, including those with segmented and diluted primaries These con gurations usually require the fabrication and guring of the relatively large diameter off-axis optical elements Testing is very dif cult because the common established interferometric techniques, in general, require the existence of a well-formed reference component Thus, the optical designs that are to be fabricated require the availability of appropriate test components and supplies In the shearing interferometers, the amplitude of the wavefront under test is split into two parts: one half is left unchanged, while a key parameter is modi ed in the other half The most signi cant feature of the shearing interferometers is that they do not require a reference wavefront, because the wavefront under test is compared with itself.

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Those portions of the wavefronts that maintain the same polarization are recombined in the detection plane, where they form an interference pattern There exist three basic types of shearing interferometers: the lateral, the radial, and the rotational The wavefront inversion interferometer has been shown to be a special case of the rotational-shearing one, with a shearing angle of 180 We have recently developed an interferogram interpretation method that allows phase reconstruction even from very high-density fringe patterns The input to the algorithm is the vectorial derivative of the phase function Therefore, the shearing interferometry is a particularly useful way of recording the input intensity data, avoiding the noise increase, exhibited when taking derivative of noisy data In a (displacement) shearing interferometer, the phase derivative along the shear direction is the measured quantity One of its salient characteristics is that the derivative is taken along a single direction.

We developed a new type of interferometer, where a derivative is taken along an arbitrary direction, under the operator s control The known incremental displacements in the two perpendicular directions, x and y, allow the determination of a two-dimensional derivative of the phase function along the direction The wavefront its replica displaced along vector r, and a representative interferogram, are illustrated in Figure 452, for the coma The possibility of taking a derivative along a speci c direction is most bene cial when testing asymmetrical components, where the fringe density in one direction is extremely high, forming the moire patterns where no phase has been recorded This is particularly useful when employing the method of phase reconstruction upon the line-integration of its gradient With the possibility of choosing the path of the line integral, this may always be selected along a favorable direction.

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