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The relative volatilities are BA = 5 and CA = 3, and the chemical equilibrium constant Keq = 5. Figure 4.27 shows residue curve maps for the reactive reboiler at three different Damk hler numbers. In the nonreactive case (Da = 0; Fig. 4.27(a)), the map topology is structured by one unstable node (pure B), one saddle point (pure C), and one stable node (pure A). Since pure A is the only stable node of nonreactive distillation, this is the feasible bottom product to be expected in a continuous distillation process. In a kinetically controlled chemical reaction (Da = 1; Fig. 4.27(b)), the stable node moves from the pure A vertex into the composition triangle. In an equilibrium-controlled chemical reaction (Da ; Fig. 4.27(c)), the reaction approaches its chemical equilibrium, and therefore the stable node is located on the equilibrium surface. In analogous manner, residue curve maps of the reactive membrane separation process can be predicted. First, a diagonal [ ]-matrix is considered with xCC = 5 and xBB = 1 that is, the undesired byproduct C permeates preferentially through the membrane, while A and B are assumed to have the same mass transfer coefficients. Figure 4.28(a) illustrates the effect of the membrane at nonreactive conditions. The trajectories move from pure C to pure A, while in nonreactive distillation (Fig. 4.27(a)) they move from pure B to pure A. Thus, by application of a C-selective membrane, the C vertex becomes an unstable node, while the B vertex becomes a saddle point. This is due to the fact that the membrane changes the effective volatilities (i.e., the products xii iA) of the reaction system such that xCC CA > xBB BA.

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Does the evaluation team have the expertise needed to do the evaluation For example, if no one has used models to evaluate systems before, then basing an evaluation on this approach is not sensible. It is no use planning to use experts to review an interface if none are available. Similarly, running usability tests requires expertise. Analyzing video can take many hours, so someone with appropriate expertise and equipment must be available to do it. If statistics are to be used, then a statistician should be consulted before starting the evaluation and then again later for analysis, if appropriate.

The interested reader can nd the remaining details for minimizing equation system (7.41), which requires also nding 1 as a solution to a corresponding discrepancy function, in Bodurtha and Jermakyan s paper, which applies the methodology to Chicago Board Options Exchange (CBOE) S&P 500 option transactions.

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a regular composition, HgCl2(OCH2CH2)4, whose unit cell involves 4 HgCl2 mole cules and 16 (OCH2CH2) units.7 Three of every four G-forms transform to T-, T G forms (G and G are dextrorotatory and sinistrorotatory gauche-forms); as a result, the chain in the complex has the T5GT5 G-conformation with an increased portion of convolute (gauche) con gurations, and the PEG unit transforms from monoclinic to orthorhombic. Moreover, the linear shape of the HgCl2 molecule slightly distorts (ClHgCl angle 176 ). The period of identity of the macromolecule changes and includes 4 monomer units instead of 7 as in the initial lattice, where each unit in the complex is more elongated (Fig. 1).

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The aim of this chapter was to introduce basic evaluation concepts that will be revisited and built on in the next four chapters. We selected the HutchWorld case study because it illustrates how a team of designers evaluated a novel system and coped with a variety of practical constraints. It also shows how different techniques are needed for different purposes and how techniques are used together to gain different perspectives on a product's usability. This study highlights how the development team paid careful attention to usability and user experience goals a s they designed and evaluated their system.

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