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112 a2 = - ( U 3 - 2) = 2.12 : 16



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308 (a) Ho mann, R, J Am Chem Soc, 1968, 90, 1475 (b) Fueno, T; Nagase, S; Tatsumi, K; Yamaguchi, K, Theor Chim Acta, 1972, 26, 43 309 (a) Houk, K N; Rondan, N G; Mareda, J, J Am Chem Soc, 1984, 106, 4291 (b) Houk, K N; Rondan, N G, J Am Chem Soc, 1984, 106, 4293 310 Dobson, R C; Hayes, D M; Ho mann, R, J Am Chem Soc, 1971, 93, 6188 311 Ho mann, R; Gleiter, R; Mallory, F B, J Am Chem Soc, 1970, 92, 1460 312 See, for example, Zaklika, K A; Thayer, A L; Schaap, A P, J Am Chem Soc, 1978, 100, 4916 4918 313 Dewar, M J S; Kirschner, S, J Am Chem Soc.

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, 1974, 96, 7578 7579, and references therein 314 Calvert, J G; Pitts, Jr, J N, Photochemistry, Wiley, New York, 1966, p 280 315 (a) Frisch, M J; Trucks, G W; Head-Gordon, M; Gill, P M W; Wong, M W; Foresman, J B; Johnson, B G; Schlegel, H B; Robb, M A; Repogle, E S; Gomperts, R; Andres, J L; Raghavachari, K; Binkley, J S; Gonzalez, C; Martin, R L; Fox, D J; Defrees, D J; Baker J; Stewart, J J P; Pople, J A, Gaussian 92, Revision A, Gaussian, Pittsburgh, PA, 1992 (b) Frisch, M J; Trucks, G W; Schlegel, H B; Gill, P M W; Johnson, B G; Robb, M A; Cheeseman, J R; Keith, T A.

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; Petersson, G A; Montgomery, J A; Raghavachari, K; Al- Laham, M A; Zakrewski, V G; Ortiz, J V; Foresman, J B; Cioslowski, J; Stefanov, B B; Nanayakkara, A; Challacombe, M; Peng, C Y; Ayala, P Y; Chen, W; Wong, M W; Andres, J L; Replogle, E S; Gomperts, R; Martin, R L; Fox, D J; Binkley, J S; Defrees, D J; Baker, J; Stewart, J P; Head-Gordon, M; Gonzalez, C; Pople, J A, Gaussian 94, (SGI-Revision B3), Gaussian, Pittsburgh PA, 1995 316 Jensen, F, Introduction to Computational Chemistry, Wiley, New York, 1999 317 Allen, L C, J Am Chem Soc, 1992, 114, 1510 318 Allen, L C, J Am Chem Soc, 1989, 111, 9003 319.

The prefactor is always very close to one as the particle masses are so similar. The exponential factor is also close to one as long as the temperature exceeds the proton-neutron mass difference of 1.3 MeV, so while kBT (m n - m p )c2 the numbers of protons and of neutrons in the Universe will be almost identical. The reactions converting neutrons to protons and vice versa are

(a) Pauling, L, J Am Chem Soc, 1932, 54, 3570 (b) Allred, A L, J Inorg Nucl Chem, 1961, 17, 215 320 Allred, A L; Rochow, E G, J Inorg Nucl Chem, 1957, 5, 264 321 For an additional discussion of electronegativities and an extensive list of references, see Luo, Y-R; Benson, S W, Acc Chem Res, 1992, 25, 375 322 Langho , S R; Davidson, E R, Int J Quantum Chem, 1974, 8, 61 323 Slater, J C, Phys Rev, 1951, 81, 385 324 Kohn, W; Sham, L J, Phys Rev A, 1965, 140, 1133 1138 325 Pople, J A; Gill, P M W; Johnson, B G, Chem Phys Lett, 1992, 199, 557 560 326 Vosko, S H; Wilk, L; Nusair, M, Can J.

Phys, 1980, 2, 1200 327 Becke, A D, Phys Rev A, 1988, 38, 3098 328 (a) Perdew, J P, Phys Rev B, 1986, 33, 8822 (b) Perdew, J P, Phys Rev B, 1986, 34, 7046 329 Colle, R; Salvetti, O, J Chem Phys, 1983, 79, 1404 330 Lee, C; Yang, W; Parr, R G, Phys Rev B, 1988, 37, 785 789 331 Becke, A D, J Chem Phys, 1988, 88, 1053 332 Sule, P; Gritsenko, O V; Nagy, A; Baerends, E J, J Chem Phys, 1995, 103, 10085 10094 333 (a) Baerends, E J; Ellis, D E; Ros, P, Chem Phys, 1973, 2, 41 (b) teVelde, G; Baerends, E J, J Comp Phys, 1992, 99, 84 334 Becke, A D, J Chem Phys.

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