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This system produced PP with an activity of 5 105 g PP/mol Zr h. The product was 62% i-PP which had a melting point of 140 C, [mmmm] = 90%, a molecular weight of 2.5 104, and a molecular weight distribution ratio of 3.1. Soga and coworkers29 created polydimethylsiloxane-supported systems containing zirconocene derivatives. These systems polymerized ethylene with activities of 2 to 4 106 g PE/mol Zr h. The same system was used to polymerize propylene. The activities were lower than those of the analogous homogeneous systems. The systems produced 40 60% PP with a [mmmm] of about 90% and melting points in the range of 142 to 154 C. A juxtaposition of the bridging backbone atoms occurs to arrange the zirconocene in some rac-like and meso-like structures that are believed to produce isotactic and atactic PP stereochemistries. Other inorganic polymer supports have been used. Zeolites have large surface areas, narrow pore-size distributions, and well de ned structures. Woo and coworkers35,36 studied the catalytic activity of bound zirconocenes on several zeolites. Little or no activity was found when the zeolite cage size was too small to readily accommodate the catalyst, monomer, and growing chain. Two zeolite-like supports with larger pore sizes, 130 nm and 400 nm, were studied. These supported catalysts polymerized propylene much like the same catalyst in solution with respect to activity, molecular weight, and homosteric pentad population. Stork and coworkers37 constructed a zirconocene dichloride catalysts system supported on a crosslinked polystyrene as described in scheme 6. The crosslinking



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The volatilities used are forward rate volatilities, the volatility of the future spot LIBOR rate at time ti 1 covering the period [ti 1, ti] conditional on the information at time t. This volatility is time-dependent and exhibits a pronounced hump effect, especially in the cap markets. Note that we assumed that the forward LIBOR rate was lognormally distributed. This assumption is consistent with the lognormal LIBOR Brace, Gatarek, and Musiela (BGM) (market) model of the term structure of interest rates. However, it is possible to value caplets and oorlets as options on zero-coupon bonds and assume that the bond price is lognormal. This assumption is consistent with the Gaussian Heath-Jarrow-Morton (HJM) (Hull-White extended Vasicek) model of the term structure of interest rates. An alternative way to price caplets and caps is to use no-arbitrage arguments following the results of Harrison and Kreps (1979). In any market where there is no arbitrage, for any given numeraire security whose price is g(t) there exists a measure for which S(t)/g(t) is a martingale for all security prices S(t). Denote this measure M{g(t)}. If we let the discount bond with maturity ti be the numeraire that is, g(t) = P(t, ti) then: S(t ) P(t , ti ) is a martingale for all security prices S(t). Thus, S(t ) S(0) = Ei P(0, ti ) P(t , ti )

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