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contour analysis, we should like to refer to the PR separations for the bands of linear and spherical molecules mentioned earlier Several attempts have been made to quantify these features of symmetric and asymmetric tops A classical review paper is that of Seth-Paul ( 1969) which provides useful approximations for vibrational assignment The large number of investigations of gaseous compounds in the infrared, make it impossible to present a compressed, complete overview on this subject The state of the science up to 1945 has been described comprehensively in the classic books by Herzberg (1945, 1950) who compiled an excellent source of information on individual molecules Today, there is an abundance of publications on high resolution studies by means of FT-IR spectrometers and diode lasers.

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The learning problem can be formulated as a maximum-likelihood estimation (MLE), where the log likelihood of the sequence pk observed is maximized over the dynamic parameters. For this purpose, in the following we ontline the approach described in more detail by Blake and Isard [43, Chap. 11]. Starting from the one-dimensional case, if we assume temporarily that the mean value is p = 0, then the scalar quantity pk F 1 pk 1 F 2 pk 2 is a Gaussian 2 N 0, (W 0 ) . Since wk are also independent, the likelihood of the sequence observed is expressed by

Special techniques of simplifying infrared spectra by using free jet expansions for rotational and vibrational cooling of the investigated molecule have been developed (see, eg, Davies and Morton-Jones, 1987) The overall complexity of rotation-vibration spectra has been demonstrated in an impressive manner by Graner (1981), who illuminates the essentials of high resolution work This publication describes the investigations of methyl bromide spectra with all its isotopic varieties critically considers perturbations, and aims at an almost complete set of harmonic and anharmonic constants Using the rotation-vibration interaction parameters, the equilibrium rotational constants A , and B, of each of the isotopic molecules were evaluated, enabling the corresponding equilibrium structure for the CH3Br molecule to be calculated A comprehensive publication by Heise et al (1981) demonstrates the value of medium resolution work for the assignment of fundamentals of a larger, nine-atom molecule like CH3CHzCN and its isotopic species.

In this case, complete consideration of combination bands is of great assistance In order to calculate a valence force field, the waveiiuinbers of the fundamentals have, as in most cases, not been corrected for anharmonicities and evident Fermi resonance effects This gains an added degree of complexity as the molecular size increases An extensive and regularly updated database listing line frequencies, broadening parameters and intensities of a variety of molecules with a small number of atoms has been compiled This database is particularly valuable for atmospheric studies and fundamental laboratory spectroscopy research The most recent contribution by Rothman et al (1987) also provides an extensive list of references, adding further details to the original studies In this context, we would like to recommend a publication by Pugh and Rao (1976), which reviews intensity data, ie.

, infrared band strengths of molecular vibrations, and provides an extensive list and description of the pertinent measurement techniques..

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