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The Planck length (the smallest measurement of length that has meaning) One fermi (aka a femtometer: a unit suitable to express the size of atomic nuclei) Diameter of proton Classical diameter of neutron Diameter of the nucleus of a helium atom Classical diameter of an electron Diameter of the nucleus of an aluminum atom Diameter of the nucleus of a gold atom Wavelength of rays Diameter of ourine ion Most likely distance from electron to nucleus in a hydrogen atom (bohr radius) Distance between bonded hydrogen atoms One angstrom Van der Waals radius of hydrogen atoms (max distance between atoms that are not bonded) Resolution (size of smallest visible object) of a transmission electron microscope Distance between bonded iron atoms Van der Waals radius of potassium atoms (max distance between atoms that are not bonded) Diameter of water molecule Distance between base pairs in a DNA molecule Diameter of xenon ion Distance between bonded cesium atoms One nanometer Size of glucose molecule Diameter of DNA helix Diameter of insulin molecule Diameter of a hemoglobin molecule Thickness of cell wall (Gram-negative bacteria) Size of typical virus Thickness of gold leaf Diameter of smallest bacteria Resolution (size of smallest visible object) of an optical microscope Length of the smallest transistor in a Pentium 3 chip Wavelength of violet light Wavelength of red light One micrometer (micron) Size of typical bacterium Diameter of average human cell nucleus Thickness of typical red blood cell Length of the smallest transistor in an Intel 286 chip Diameter of typical capillary Length of the smallest transistor in an Intel 8086 chip Diameter of a single yeast organism



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Figure 12-5

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There s only so much information you can add to one of these diagrams, however. Even this relatively simple diagram is pretty big if you add data type and required data. Usually it s better to stick to the simpler version and put additional information in separate documents. As is the case with all models, you should write down notes to record any information that is not fully captured by the diagram alone. For example, Figure 5-28 does not show which elds are required, their meanings (what does Sku mean, anyway ), more precise cardinalities (what if one-to-many should really be one-to-four ), and so forth. Though the gure gives data types for each of the tables elds, that does not necessarily completely specify the elds domains. For example, the Zip eld should contain a 5-digit ZIP Code or a Zip+4 Code

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Precision relates to the random error of a measurement system (see Figure 8) and is a component of MU (see also Section 822 and Figure) [2] Trueness is expressed in terms of bias or percentages of error Bias is the difference between the mean value determined for the analyte of interest and the accepted true value or known level actually present [87] It represents the systematic deviation of the measured result from the true result Method trueness is an indicator also for utility and applicability of that method with real samples [88] Different sources of systematic errors contribute to the overall bias (Figure 8) Thompson and Wood [8] describe persistant bias as the bias affecting all data of the analytical system over longer periods of time and being relatively small but continuously present.

Different components contribute to the persistant bias, such as laboratory bias, method bias, and the matrix variation effect Next to persistant bias, the larger run effect is the bias of the analytical system during a particular run [4, 8, 15] One or more of these bias components are encountered when analyzing RMs In general, RMs are divided into certi ed RMs (CRMs, either pure substances/solutions or matrix CRMs) and (noncerti ed) laboratory RMs (LRMs), also called QC samples [89] CRMs can address all aspects of bias (method, laboratory, and run bias); they are de ned with a statement of uncertainty and traceable to international standards Therefore, CRMs are considered useful tools to achieve traceability in analytical measurements, to calibrat equipment and methods (in certain cases), to monitor laboratory performance, to validate methods, and to allow comparison of methods [4, 15, 30].

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