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BP-AZ-CA colloids can also lead to the same conclusion. It has been discussed in Section 5.3.4 that the hybrid colloids are formed by gradual assembly from the cores to shell, where the more hydrophobic PEAPE chains compose the inner parts and the BP-AZ-CA chains form the shells. The photoisomerization study is consistent with this core shell structure model. As the HEAZ moieties are con ned in the cores, the isomerization cannot have the same free volume as the HEAZ moieties in the shells. Compared with the PEAPE colloids, where a fraction of HEAZ chromophores is distributed in the shells, the free volume for the photoisomerization in hybrid colloids is reduced. This factor can cause the photoisomerization rate of the hybrid colloids to become obviously lower than that of the PEAPE colloids. Although the hybrid colloids can be deformed by the light irradiation, TEM observation shows that the deformed colloids re ect a morphology obviously different from that of the elongated BP-AZ-CA colloids. Typical appearance possesses a circle core with higher contrast and tails stretched from the core. Considering the photoresponsive behavior of both polymers, it can be concluded that the core and tails are composed of PEAPE and BP-AZ-CA components, respectively. The result implies an interesting effect that the light force can cause



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The TCP/IP protocol suite was integrated into all of the most popular operating systems Companies began to transact commerce (e-commerce) over the Internet Residential Internet access became very cheap Many wonderful desktop applications were developed for TCP/IP networks, including the World Wide Web, Internet phone, and interactive streaming video Thousands of companies are currently developing new applications and services for the Internet

A more user friendly de nition quoted in words as used by the Civil Airworthiness Authority (CAA) may be: Catastrophic: less than 1 10 9 ; extremely improbable Hazardous: between 1 10 9 and 1 10 7 ; extremely remote Major: between 1 10 7 and 1 10 5 ; remote Minor: between 1 10 5 and 1 10 3 ; reasonably probable greater than 1 10 3 ; frequent





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Furthermore, throughout the 1990s, several low-cost high-speed LAN technologies were developed, including 100 Mbps Ethernet and more recently Gigabit Ethernet, mitigating the need for ATM use in high-speed LAN applications Today, we live in a world where almost all networking application products interface directly with TCP/IP Nevertheless, ATM switches can switch packets at very high rates, and consequently has been deployed in Internet backbone networks, where the need to transport traffic at high rates is most acute We will discuss the topic of IP over ATM in Section 58

the separation of PEAPE and BP-AZ-CA components in case they are not mixed with each at molecular level.

We shall discuss ATM in some detail in subsequent chapters For now we briefly outline its principle characteristics:

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Recently, construction of 2-D and 3-D periodic structures from monodispersed colloidal spheres has aroused tremendous research enthusiasm for their selfassembled architecture and fascinating applications (Xia et al., 2000). The colloidal crystals can be obtained by methods such as transferring the colloidal array formed at the air liquid interface, exploiting the capillary forces to drive the assembly, and using electrophoretic deposition or sedimentation in a force eld (see, e.g., Cheng et al., 1999; Jiang et al., 1999a; Park and Xia, 1999; Dimitrov and Nagayama, 1996). The colloidal spheres discussed in the preceding sections can be used as a new type of the building block to construct colloidal crystal through selfassembling methods.

The ATM standard defines a full suite of communication protocols, from the transport layer all the way down through the physical layer It uses packet switching with fixed length packets of 53 bytes In ATM jargon these packets are called cells Each cell has 5 bytes of header and 48 bytes of "payload" The fixed length cells and simple headers have facilitated high-speed switching ATM uses virtual circuits (VCs) In ATM jargon, virtual circuits are called virtual channels The ATM header includes a field for the virtual channel number, which is called the virtual channel identifier (VCI) in ATM jargon As discussed in Section 13, packet switches use the VCI to route cells towards their destinations; ATM switches also perform VCI translation ATM provides no retransmissions on a link-by-link basis If a switch detects an error in an ATM cell, it attempts to correct the error using error correcting codes If it cannot correct the error, it drops the cell and does not ask the preceding switch to retransmit the cell ATM provides congestion control on an end-to-end basis That is, the transmission of ATM cells is not directly regulated by the switches in times of congestion However, the network switches themselves do provide feedback to a sending end system to help it regulate its transmission rate when the network becomes congested ATM can run over just about any physical layer It often runs over fiber optics using the SONET standard at speeds of 15552 Mbps, 622 Mbps and higher

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