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The Internet (and more generally TCP/IP networks) makes available two transport protocols to applications, namely, UDP (User Datagram Protocol) and TCP (Transmission Control Protocol) When a developer creates a new application for the Internet, one of the first decisions that the developer must make is whether to use UDP or TCP Each of these protocols offers a different service model to the invoking applications

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for the encapsulation of hydrophobic and hydrophilic agents, respectively (polymer vesicles can also load hydrophobic agents in the membrane, which is not depicted in Fig. 6.1). Upon illumination with UV light, azobenzene moieties can be converted to the cis isomer. To shift the hydrophilic hydrophobic balance towards the destabilization (dissociation) of the micelles, obviously the cis isomer of azobenzene must be signi cantly more polar than the trans isomer. This is possible by appropriate choice of substitutions on azobenzene. A hint comes from azobenzene without substitution, for which it is known that the elongated trans form has a zero dipole moment, while the bent cis form has a dipole moment of B3 D (Kumar and Neckers, 1989). To obtain a small (near zero) dipole moment for trans-azobenzene linked to the polymer chain backbone, the use of the same substitution groups on the para positions of azobenzene would be most useful since this substitution pattern gives a nearly symmetrical structure for the trans isomer, with no separation of positive and negative charge centers. On the other hand, the cis isomer should have an increased dipole moment owing to the conformational (shape) change. On the contrary, azobenzene structures with strong electron-donor and electron-acceptor groups on the para positions, which would have a higher dipole





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The TCP service model includes a connection-oriented service and a reliable data transfer service When an application invokes TCP for its transport protocol, the application receives both of these services from TCP

0.01 0 200 400 600 800 Relaxation time (s) 1000 1200

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Connection-oriented service: TCP has the client and server exchange transport-layer control information with each other before the application-level messages begin to flow This so-called handshaking procedure (that is part of the TCP protocol) alerts the client and server, allowing them to prepare for an onslaught of packets After the handshaking phase, a TCP connection is said to exist between the sockets of the two processes The connection is a full-duplex connection in that the two processes can send messages to each other over the connection at the same time When the application is finished sending messages, it must tear down the connection The service is referred to as a "connection-oriented" service rather than a "connection" service (or a "virtual circuit" service), because the two processes are connected in a very loose manner In 3 we will discuss connection-oriented service in detail and examine how it is implemented Reliable transport service: The communicating processes can rely on TCP to to deliver all messages sent without error and in the proper order When one side of the application passes a stream of bytes into a socket, it can count on TCP to deliver the same stream of data to the receiving socket, with no missing or duplicate bytes

TCP also includes a congestion control mechanism, a service for the general welfare of the Internet rather than for the direct benefit of the communicating processes The TCP congestion control mechanism throttles a process (client or server) when the network is congested In particular, as we shall see in 3, TCP congestion control attempts to limit each TCP connection to its fair share of network bandwidth The throttling of the transmission rate can have a very harmful effect on real-time audio and video applications that have minimum bandwidth requirements Moreover, real-time applications are losstolerant and do not need a fully reliable transport service In fact, the TCP acknowledgments and retransmissions that provide the reliable transport service (discussed in 3) can further slow down the transmission rate of useful real-time data For these reasons, developers of real-time applications usually run their applications over UDP rather than TCP

Figure 7.10. The effect of light on the dynamic properties of physical cross-links between azobenzene-modi ed poly(acrylate) and poly(cyclodextrin). The relaxation modulus in stress relaxation experiments is plotted after application at time zero of a xed strain to a 0.7% polymer solution in water (polymer structure, cf. Fig. 7.1, with n = 11 and x = 3) with polycyclodextrin at 0.25% (lower curves) or 0.5% (higher moduli). The sample was either incubated for 24 h in the dark (dark-adapted, closed symbols) or continuously exposed to UV before and after loading in the rheometer (open symbols). Details on the samples composition are given in Pouliquen et al. (2007).

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