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I am trying to convert a series of images taken from OpenFileDialog() to one PDF using iTextSharp in C# . Here is what I'm running. When I ...

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However, a different trend is seen when B 0 is in excess PDI increases with a limiting value at complete B conversion of 2 or greater than 2 depending on whether the difference in reactivity of B and B0 is less than or greater than 2..

Po;,s = -N Eo;,s,



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Several considerations are common to all processes for step polymerizations in order to achieve high molecular weights. One needs to employ a reaction with an absence or at least a minimum of side reactions, which would limit high conversions. Polymerizations are carried out at high concentrations to minimize cyclization and maximize the reaction rate. Highpurity reactants in stoichiometric or near-stoichiometric amounts are required. The molecular weight is controlled by the presence of controlled amounts of monofunctional reagents or an excess of one of the bifunctional reagents. Equilibrium considerations are also of prime importance. Since many step polymerizations are equilibrium reactions, appropriate means must be employed to displace the equilibrium in the direction of the polymer product. Distillation of water or other small molecule products from the reaction mixture by suitable reaction temperatures and reduced pressures are often employed for this purpose. Table 2-8 shows values of some kinetic and thermodynamic characteristics of typical step polymerizatiosn [Bekhli et al., 1967; Chelnokova et al., 1949; Fukumoto, 1956; Hamann et al., 1968; Malhotra and Avinash, 1975, 1976; Ravens and Ward, 1961; Saunders and Dobinson, 1976; Stevenson, 1969; Ueberreiter and Engel, 1977]. These data have implications on the temperature at which polymerization is carried out. Most step polymerizations





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I've come up with a way to do this using PDFSharp, hopefully will be useful for others as well. // Convert to PDF and delete image PdfHelper.

(2.130)

88 T ( C) Ea (kJ mol 1) 59.4 10.9 41 188 58.6 100.4 24 0.40e 0.23f 1.1g 0.048g 31.4 35.0 77.4 76.6 161 161 150 58.8 275 275 185 1.0 107 108 235 60 60 75 75 7.5 10 2 1.6 2.9 0.5 10 k 103 (L mol 1 s 1) H (kJ mol 1)

where a = R, I with R standing for real component and I for imaginary component. With these new variables, for each k and polarization s, we have four equations of motion (2.131) These are Hamilton's dynamical equations of motion for two (a = R, I) harmonic oscillators of frequency ek and unit mass. The Hamiltonian from which these equations of motion can be derived is given by (2.132) For the Hamiltonian also to be the energy,

Polyester HO(CH2)10OH HOOC(CH2)4COOH HO(CH2)10OH HOOC(CH2)4COOHc HOCH2CH2OH p-HOOC f COOH HO(CH2)6OH ClOC(CH2)8COCl p-HOCH2CH2OOC COOCH2CH2OH f COOCH2CH2OHd p-HOCH2CH2OOC f Polyamide H2N(CH2)6NH2 HOOC(CH2)8COOH f Cl Piperazine p-Cl CO CO H2N(CH2)5COOH Polyurethane f m-OCN NCO HOCH2CH2OCO(CH2)4COOCH2CH2OH NCO HOCH2CH2OCO(CH2)4COOCH2CH2OH m-OCN f Phenol-formaldehyde polymer f OH H2COc f OH H2COh

811" 11"2

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Uncatalyzed unless otherwise noted. 1 cal 4.184 J. Acid-catalyzed. d Catalyzed by Sb2O3. e k1 value. f k2 value. g Average k for all functional groups. h Base-catalyzed.

{E2 +B2} 2 + IBI2}

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proceed at relatively slow rates at ordinary temperatures High temperatures in the range of 150 200 C and higher are frequently used to obtain reasonable polymerization rates Table 2-8 shows that the rate constants are not large even at these temperatures Typical rate constants are of the order of 10 3 L mol 1 s 1 There are a few exceptions of step polymerizations with signi cantly larger k values, for example, the polymerization reaction between acid halides and alcohols The need to use higher temperatures can present several problems, including loss of one or the other reactant by degradation or volatilization Oxidative degradation of polymer is also a potential problem in some cases The use of an inert atmosphere (N2, CO2) can minimize oxidative degradation.

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