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aramids illustrates that one can have too much of a good thing None of these polymers can be melt processed since they undergo decomposition before melting (Tm > 500 C) The aramids are spin processed into bers using lyotropic solutions in sulfuric acid It would be preferable to melt-process the polymers or, at least, to use a less aggressive or less dangerous solvent, but these options do not exist Poly(1,4-oxybenzoyl) (Ekonol) has found limited utility due to a lack of easy processability It does not have suf cient solubility even in an aggressive solvent to allow solution processing It can be processed by plasma spraying or powder sintering There is a need to decrease the crystalline melting temperature in such very-high-melting LC polymers to achieve a degree of processability.



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Copolymerization is used to alter the polymer chains in the direction of decreased rigidity but one needs to do it carefully to retain as high modulus, strength, and Tm as possible Chain rigidity can be lowered by reducing molecular linearity by incorporating a less symmetric comonomer unit (o- and m- instead of p- or naphthalene rings, other than 1,4-disubstituted, instead of the 1,4-phenylene unit), a comonomer containing a exible spacer (single bond, oxygen, or methylene between mesogenic monomer units) or a comonomer with exible side groups [Jin and Kang, 1997; Yamanaka et al, 1999] This approach has been successfully applied to poly(1,4-oxybenzoyl) Two copolyesters are commercial products Vecta is a copolymer of p-hydroxybenzoic acid with 6-hydroxy-2-naphthoic acid; Xydar is a copolymer of p-hydroxybenzoic acid with p; p0 biphenol and terephthalic acid.

7r 2 1ic Pcas(x, y) = -z240l 4 '





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These polymers have continuous service temperatures up to 240 C and nd applications for microwave ovenware, automotive components, components for chemical pumps and distillation towers, and electronic devices Many of the polymers discussed in the following sections exhibit liquid crystal behavior..

Polyimides are obtained from amine and carboxyl reactants when the ratio of amine to acid functional groups is 1 : 2. If reactants with the reverse ratio of amine to acid functional groups are employed, polybenzimidazoles (PBI) are produced; for instance, polymerization of 3,30 diaminobenzidine and diphenyl isophthalate yields poly[(5,50 -bi-1H-benzimidazole]2,20 -diyl)-1,3-phenylene] (LIIIa) (Eq. 2-216) [Buckley et al., 1988; Hergenrother, 1987;

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To insert a preset Quick Part, click the Insert tab on the Ribbon, click the Quick Parts button and click Building Blocks Organizer. Locate the Quick Part you want to insert, click it and click Insert.

IUPAC name for this polymer is poly(oxycarbonyloxy-1,4-phenylenedimethylmethylene1,4-phenylene).

which confirms the result of Section 2.5.1, showing that the pressure on the plate at z = l is directed toward the other plate (Le., it is attractive) and has a magnitude of 7r 2 1ic/240l 4

C(CH3)2

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As in most of physics only energy differences are important, one frequently eliminates the zero-point energy by shifting the origin of energy [ie, by adding a constant (but infinite) term to the Hamiltonian of the electromagnetic field] In general relativity, however, one cannot shift the origin of energy, as according to Einstein, energy is equivalent to mass and must generate a gravitational field So not only the electromagnetic zero-point energy, but the zero-point energies of all the fundamental boson fields of nature (including that of the graviton if it really exists) should give rise to a gravitational field: Interestingly, fermion fields would tend to cancel this effect, as their zero-point energy is negative Some versions of supersymnietry that predict a fermion partner for every boson would then lead to no gravitational effect [5].

1-3 LINEAR, BRANCHED, AND CROSSLINKED POLYMERS Polymers can be classi ed as linear, branched, or crosslinked polymers depending on their structure. In the previous discussion on the different types of polymers and polymerizations we have considered only those polymers in which the monomer molecules have been linked together in one continuous length to form the polymer molecule. Such polymers are termed

But despite intense experimental effort, no supersymmetry partners of the known elementary particles have been observed yet If they do exist at large energy scales than are now accessible, the effect would be the same as that of a cutoff to the zero-point spectrum at these energies In empty space, the electromagnetic vacuum zero-point energy is uniform The same can be assumed for the zero-point energies of the other fields in nature What kind of observable gravitational effect would such uniform energy distribution produce As a simple example, we can consider the effect of this uniform density on the motion of the outer planets of our solar system [5] Unlike the inner planets, which are significantly affected by the other planets (and in the case of our Earth, by the Moon), the motion of the outer planets is dominated by the Sun.

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