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whether symmetric such as triallylcyanurate and tetraallyl ammonium bromide or unsymmetric such as diallyl maleate, behave similarly with the formation of crosslinked network structures. The extent of cyclization decreases quite sharply as one goes to ring sizes of 7 or more atoms. However, contrary to expectations, the extent of cyclization is still quite signi cant for many monomers. Thus the extent of cyclization (measured as the percent of monomer units that are cyclized) is 15 20% for diallyl esters giving ring structures containing up to 17 atoms [Holt and Simpson, 1956]. The polymerization of o-diallyl phthalate yields a polymer with more than 40% cyclization [Eaton et al., 1989; Matsumoto et al., 1980]. Cyclopolymerizations yielding more complex ring structures have also been reported [Butler, 19896, 1989]. For example, 1,4-dienes such as divinyl ether yield uncrosslinked products with little or no unsaturation and possessing different bicylic structures. The formation of one of the bicyclic structures is shown in Eq. 6-107 [Tsukino and Kunitake, 1979].



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6-107

(O~ - w 2 )2 (02 _ w2)2 + 4w2G/2 '

You can move any slide element, such as a text box, table, chart, picture, video clip or any other element, to reposition it in the slide. (These slide elements are often referred to as objects.) For example, you might move a text box to make room for a clip-art object or move a picture to improve the overall appearance of the slide. One way to move a slide object is to use the standard Office Cut and Paste buttons, discussed in 2. Another is to drag and drop the object, as discussed in this section.

Cyclocopolymerization is cyclopolymerization of a pair of monomers [Butler, 2000]. An example is the generation of pyran rings by copolymerization between maleic anhydride and the two double bonds of divinyl ether:

(7.66)

6-108

(7.67)





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Recall the discussion in Sec. 2-3 concerning the competition between linear polymerization and cyclization in step polymerizations. Cyclization is not competitive with linear polymerization for ring sizes greater than 7 atoms. Further, even for most of the reactants, which would yield rings of 5, 6, or 7 atoms if they cyclized, linear polymerization can be made to predominate because of the interconvertibility of the cyclic and linear structures. The difference in behavior between chain and step polymerizations arises because the cyclic structures in chain polymerization do not depropagate under the reaction conditions; that is, the cyclic structure does not interconvert with the linear structure. 6-6c Interpenetrating Polymer Networks

'-..-'

An interpenetrating polymer network (IPN) (Sec. 2-13c-3) is obtained by carrying out a polymerization with crosslinking in the presence of another already crosslinked polymer [Klempner

e;:3/2

and Berkowski, 1987]. For example, a crosslinked polyurethane is swollen with a mixture of methyl methacrylate, trimethylolpropane trimethacrylate, and benzoyl peroxide and heated. The methacrylate system polymerizes to a crosslinked network which interpenetrates the polyurethane network. An IPN has the potential for combining the properties of two different crosslinked polymers. 6-7 OTHER COPOLYMERIZATIONS 6-7a Miscellaneous Copolymerizations of Alkenes

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The e;:3/2 contribution to the variance is the only one yielded by a theory where the macroscopic Maxwell equations for a nondispersive and non absorptive dielectric medium are quantized directly [237]. The last term on the right-hand side of (7.67) is the noise from the medium derived by Rosewarne [528], which cannot exist in a theory where the medium is only described by a dielectric pennittivity. Moreover, this noise is larger than the change 4G/2 / Wo caused by the medium in the unit permittivity of the vacuum. Does this result mean that all macroscopic versions of QED based only on a dielectric-pennittivity description of media are doomed to fail No. In the next section we show that the extra noise coming from the medium is in a very different frequency than that of the original field in the absence of a medium. So as long as the physical systems affected by the macroscopic field fluctuations are reasonably selective in frequency, they will not "feel" the noise of the medium if they are detuned from it.

A variety of reactants including sulfur dioxide, carbon monoxide, and oxygen, which do not homopolymerize undergo radical copolymerization with alkenes to form polymeric sulfones [Bae et al., 1988; Cais and O Donnell, 1976; Dainton and Ivin, 1958; Florjanczyk et al., 1987; Soares, 1997], ketones [Sommazzi and Garbassi, 1997; Starkweather, 1987, and peroxides [Cais and Bovey, 1977; Mukundan and Kishore, 1987; Nukui et al., 1982]:

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