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If azobenzene groups were the sole factor responsible for the second grating, the grating structure would disappear days after the holographic recording as a result of the thermally activated cis trans backisomerization, restoring the equilibrium concentration of trans-azobenzene throughout the whole lm What could be the structural rearrangement in a stretched ATE lm subjected to holographic recording that is responsible for the formation of the second grating On the basis of what is known about SBS, the following analysis can be proposed The ATE sample contains some 8% azobenzene polymer grafts chemically connected to the PB chains, with the azobenzene polymer forming microdomains embedded in the PB matrix In a stretched lm, in addition to the glassy PS cylindrical microdomains (Fig 117), the azo-SCLCP microdomains may also act as cross-links and support part of the extensional stress.



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Figure 15-1: Access networks Access networks can be loosely divided into three categories:

residential access networks, connecting a home end system into the network; institutional access networks, connecting an end system in a business or educational institution into the network; mobile access networks, connecting a mobile end system into the network

When the writing UV laser is turned on, the photoisomerization in the excited (reactive) regions converts oriented trans-azobenzene into disordered cis-azobenzene,.

These categories are not hard and fast; some corporate end systems may well use the access network technology that we ascribe to residential access networks, and vice versa Our descriptions below are meant to hold for the common (if not every) case





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corresponding to an isothermal photochemical phase transition from the LC to the isotropic phase As the azobenzene polymer in the isotropic phase is more uid than that in the LC state, its microdomains become less effective cross-linking points, which results in relaxation of oriented PB chains and release of the stress As this happens, the stress is no longer uniformly distributed in space as before irradiation, and local structural reorganization may follow to rebalance the stress along the SD This perturbation might be enough to disorder trans-azobenzene groups in nonexcited areas, which explains the erasure of the rst grating As the irradiation continues, the excited areas may undergo further structural changes because of the photoinduced isotropic state of the azobenzene polymer.

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IEEE 1394 as outlined previously de nes a media, topology and protocol for both a backplane physical layer or point-to-point serial cable interface; in aircraft system interconnections the latter is used. The interface is also called the High Performance Serial Bus (HPSB). The cable (differential) version operates at 100 Mbits/sec, 200 Mbits/sec, or 400 Mbits/sec; this increases to 800 Mbits/sec for 1394b. The baseline 1394 uses half-duplex or unidirectional transmission whereas 1394b is capable of full duplex or bi-directional transmission. The latest IEEE 1394b standard also allows transmission up to 800 Mbits/sec. The bus supports up to 63 devices at a maximum cable distance between devices of 4.5 metres. When the number of devices on the bus is limited to 16,

A residential access network connects a home end system (typically a PC, but perhaps a Web TV or other residential system) to an edge router Probably the most common form of home access is using a modem over a POTS (plain old telephone system) dialup line to an Internet service provider (ISP) The home modem converts the digital output of the PC into analog format for transmission over the analog phone line A modem in the ISP converts the analog signal back into digital form for input to the ISP router In this case, the "access network" is simply a point-to-point dialup link into an edge router The point-to-point link

In other words, similar to the effect of thermal annealing below Tg of PS, in the optically plasticized areas (excited areas), greater plastic ow of PS chains takes place and leads to greater PB chain orientation relaxation and rearrangement of the PS cylindrical domains (Pakula et al, 1985a,b) The formation dynamics of the second grating, arising from such structural changes, should be slow and dependent on the power of the writing beam, which indeed is the case Such a structural rearrangement induced by the photoisomerization of azobenzene mesogens in a stretched ATE lm paints a complicated picture for the possible changes in diffraction ef ciency upon elastic deformation In principle, the index modulation depth between irradiated and nonirradiated regions could come from three contributions: different PB chain orientations, different arrangements of PS cylindrical microdomains, and different azobenzene conformations and orientations.

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