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of thermal and mechanical stabilities, easy processing, and easy integration into devices. Preparation of the photoresponsive hybrid silica materials requires synthesis of azobenzene-containing organosilanes because they are not commercially available. The azobenzene-containing organosilanes were represented by the formula R-Si(ORu)3 in which R contains an azobenzene ligand and Ru is an ethyl or methyl group. After sol gel hydrolysis and condensation of the azobenzenecontaining organodilanes with other silica precursors, the azobenzene-containing R groups are covalently bonded to the silica matrix. Other than the conventional sol gel chemistries toward polysiloxane gels, cohydrolysis and cocondensation of organosilanes and alkyl silicate in the presence of acid or base catalysts and amphiphilic surfactant or block copolymer templates lead to self-assembled highly ordered hexagonal, cubic, or lamellar nanostructures. The nanostructures are controlled by several factors, such as the concentration of silicon precursors and catalyst, amounts of the template molecules, temperature, and aging time. After selective removal of the template molecules, the organofunctional hybrid nanoporous silica materials are created. This surfactant-directed self-assembly technique is utilized to synthesize photoresponsive nanoporous silica materials with azobenzene ligands positioned on the pore surfaces. Under UV and visible light irradiation, the azobenzene ligands undergo trans2cis isomerization and create novel properties of the hybrid silica materials, such as photoregulated mass transport and photocontrolled liquid adsorption. This chapter focuses on azobenzene-containing organosilanes that are precursors for preparing photoresponsive silica materials, mesoporous silica materials with azobenzene moieties on the pore surfaces, and azobenzene-modi ed polysilsesquioxane gels.



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Azobenzene-containing organic polymers have been widely investigated in the past several decades for their photoresponsive properties. However, research in azobenzene-containing inorganic polymers, such as sol gel materials, is very limited. As proposed by Ozin and colleagues, a wide range of organic and organometallic precurors are potentially suited for incorporation of organic groups with novel chemical and structural properties into sol gel materials (Maclachlan et al., 2000). Among these precursors, azobenzene-containing organosilane is of particular interest for the preparation of photoresponsive nanocomposite materials. Several efforts have been made to synthetically prepare pendant and bridged azobenzene-containing organosilanes, which are essential for the creation of photoresponsive nanocomposite sol gel materials. Ichimura and coworkers synthesized two organosilanes, 4-methoxy-4u(N-(3-triethoxysilylpropyl)carbamoylmethoxy)azobenzene (MTAB) and 4,4u-bis(N-(3-triethoxysilylpropyl)carbamoylmethoxy)azobenzene (DTAB), using the condensation reaction between carboxylic acid and amine in the presence of dicyclohexylcarbodiimide (DCC; Ueda et al., 1993). However, this synthetic route





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have LAN addresses as well There are several good answers to this question First, LANs are designed for "arbitrary" network-layer protocols, not just for IP If adapters were to get assigned IP addresses rather than "neutral" LAN addresses, then the adapters would not be able to easily support other networklayer protocols (eg, IPX or DECNet) Second, if adapters were to use IP addresses instead of LAN addresses, the IP address would have to stored in adapter RAM and configured every time the adapter were moved (or powered up) Another option is to not use any addresses in the adapters, and have each adapter pass the data (ie, the IP datagram) of each frame it receives to its parent node The parent node could then check for a matching IP address One problem with this option is that the parent node will be interrupted by every frame sent on the LAN, including by the frames that are destined for other nodes on the LAN As we described at the beginning of this section, when an adapter wants to send a frame to some destination adapter on the same LAN, the sending adapter inserts the destination LAN address into the frame When the destination adapter receives the frame, it extracts the enclosed datagram and passes the datagram up the protocol stack All the other adapters on the LAN also receive the frame; but these other adapters discard the frame without passing the network-layer datagram up the protocol stack Thus, these other adapters do not have to interrupt their hosts when they receive datagrams destined to other hosts Having said this, sometimes a sending adapter does want all the other adapters on the LAN to receive and process the frame it is about to send In this case, the sending adapter inserts a special LAN broadcast address into the destination address field of the frame For LANs that use the six-byte addresses (such as Ethernet and token-passing LANs), the broadcast address is a string of 48 consecutive 1s (ie, FF-FF-FF-FF-FF-FF in hexadecimal notation).

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is not preferable because of the high toxicity of the DCC compound and the low yields of MTAB and DTAB. Corriu and colleagues also synthesized an azobenzene-bridged organosilane, 4,4u-bis(3-triisopropoxysilylpropoxy)azobenzene (BSPA), and prepared the corresponding photoresponsive hybrid materials (Besson et al., 2005). BSPA was synthesized by reacting 4,4u-dihydroxyazobenzene with 3-iodopropyltriisoproxysilane in the presence of NaH at an elevated temperature of 601C with 70% yield after puri cation. However, two extra steps need to be adopted for the synthesis of 3-iodopropyltriisoproxysilane, which increases the complexity of the synthetic process. Brinker and coworkers designed and synthesized two organosilane precursors, 4-(3-triethoxysilylpropylureido)azobenzene (TSUA) and 4,4u-bis(3-triethoxysilylpropylureido)azobenzene (BSUA), for the preparation of photoresponsive nanocomposite materials (Liu et al., 2003b, 2002). The synthetic routes for TSUA and BSUA are more successful than those for other organosilanes in terms of purity, yield, and simplicity. TSUA and BSUA are new compounds. Some of their novel properties have also been studied.

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