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Kraft et al., 1998; Lowen and Van Dyke, 1990; Wei and Tian, 1993]. Reactions other than oxidative polymerization are also being studied for producing polyaniline and polythiophene [Kraft et al., 1998; Loewe et al., 2001]. An example is the Pd-catalyzed dehydrohalogenation between aryl dihalides and aryl primary diamines to synthesize polyanilines [Kanbara et al., 2000].

e!.c (if cos2 kz,m z ,

2-14j-2 Poly(p-phenylene) One of the earliest attempts to synthesize heat-resistant polymers was the oxidative polymerization of benzene to poly(p-phenylene) [IUPAC: poly(1,4-phenylene)] (Eq. 2-227) [Jones

Tf: I <P Ke;"c (i) 2 sin2 kz,m z ,

2-227



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and Kovacic, 1987; Kovacic and Jones, 1987]. The reaction requires the presence of both a Lewis acid catalyst and an oxidant, such as aluminum chloride and cupric chloride. Poly (p-phenylene) is of interest not only for heat resistance but also as a conducting polymer. Unfortunately, the oxidative route yields an insoluble and intractable product of low molecular weight and irregular structure (a mixture of o and p substitution). Similar results have been found for polymerization of biphenyl, p-terphenyl, and naphthalene. Alternate approaches to the poly(p-phenylene) system have been more successful [Kraft et al., 1998; Schluter, 2001]. The emphasis in these approaches has been on substituted poly(p-phenylene)s with suitable side groups that solubilize the polymer. Also of interest are chromophores as side groups to impart light-emitting properties for speci c wavelengths of light. One of the reactions successfully employed is the Suzuki coupling between arylboronic acids (or their esters) and aryl bromides (Eq. 2-228) [Hu, 2003; Schluter and Wegner, 1993]. Another useful reaction is the coupling of aryl dihalides with zinc (Eq. 2-229). These

{[1 + {[1 + I'

Pd(PPh3)4

1 + (~f cos2 kz,mz}, 2 2 k!;, 1 cos kz,mz + (~) 2 sin kz,m z },

2-228

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2-229

e~ac sin2 0 cos2 (kzz 8),

reactions have been adapted for synthesis of other conjugated polyaromatic polymers, for example, poly uorenes (LVII).

{(Xn' Boud (X3' Boud) = 8n3 / ' ~k e;acsin20sin2(kzz - 8),

2-14j-3 Poly(p-phenylene Vinylene) Poly(p-phenylene vinylene) [IUPAC: poly(1,4-phenyleneethene-1,2-diyl)] (PPV) (LVIII) is obtained by the sequence in Eq. 2-230 involving successive base- and heat-induced

(Eout ) = {Bout} =

2-230

I' I'

eliminations of dialkyl sul de and hydrogen halide [Cho, 2002; Kraft et al., 1998; Lenz et al., 1988; van Breemen et al., 2001]. PPV can also be synthesized by the Heck coupling of aryl halides with alkenes (Eq. 2-231).

{[1 + cos2 OJ sin2 (k z z - 8) + sin2 Ocos2 (kzz - 8)}, {[1 + cos2 OJ cos2 (kzz - 8) + sin2 Osin2 (kzz - 8)},

2-231

where E,B = Et + E,8 and B,B = Bt + B,8' Then substitute these expressions in (2.202) using (2.201) and derive (2.203).

The corresponding azomethine polymers (LIX) have been synthesized by the reaction of the appropriate diamine and dialdehyde [Farcas and Grigoras, 2001; Gutch et al., 2001; Morgan et al., 1987].

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2.13 Use the Euler-Maclaurin fonnula, as was done in Section 2.5.1, to show that (2.206) yields (2.207). 2.14 Using (2.175), show that the multiple reflections between the plates transmitted to the outside exactly cancel the reflection of the incident wave by the plate at z = l, when kz = mr / 1 and to ---* O. In other words, at the cavity resonances there is no reflected wave, just as Michael Berry suggested [50].

2-15

The drive for heat-resistant polymers has led to an exploration of polymers based on inorganic elements since bond energy considerations indicate that such polymers should be superior to organic polymers in thermal stability [Allcock et al., 2003; Archer, 2001; Manners, 1996; Nguyen et al., 1999; Ray, 1978]. Both inorganic and organometallic polymers have been studied. Inorganic polymers are polymers containing no organic groups, while organometallic polymers contain a combination of inorganic and organic groups. Inorganic and organometallic polymers would have potential for a variety of uses as partial or complete substitutes for organic bers, elastomers, and plastics where ame and heat resistance are important; as marine antifoulants, bactericides, medicinals, fungicides, adhesives, photoresists, photosensitizers, photostabilizers; and as conducting polymers. in general much of this potential is unrealized, although signi cant exceptions exist the polysiloxanes (Secs. 2-12f and 7-11a), poly(p-phenylene sul de) (Sec. 2-14d), polyphosphazenes (Sec. 7-11b), and polysilanes (Sec. 2-15b-3) are commercial polymers. 2-15a Inorganic Polymers

Cavity Quantum Electrodynamics: The Strange Theory of Light in a Box Sergio M. Dutra Copyright 2005 John Wiley & Sons, Inc.

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