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q", r", . -88 A(r", , t) - q", (r", . V) Aj (r", , t) - q", 88 Aj (r", , t), c r""j c , c t , ~--------------~.--------------~' .. , t) (q",/c) [r", A B(r", , t)l j q",E.L,j(r",

Date & Time Returns the current date Logical Returns one of two results that you specify based on whether the value is true or false Logical Returns true if all of the arguments are true, false if any is false Logical Returns true if any argument is true, false if all arguments are false



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Isocyanates are polymerized through the carbon nitrogen double bond to 1-nylons by anionic initiators such as metal alkyls, sodium naphthalene, and sodium cyanide [Bur and Fetters,

(5.111)

5-139

to recognize the firstterm on the right-hand side of equation (5.110) as the j component of magnetic force on charge q", [i.e., (q",/c) [r", A B(r", , t)l j ]. So equation (5.100) allows us to recover the Newton-Lorentz equations (5.71) and (5.72).

1976; Dabi and Zilka, 1980; Eromosele and Pepper, 1987; Kresta et al., 1979]. The polymerization has a low ceiling temperature and cyclotrimerization to the isocyanurate is the major reaction at ambient temperatures and above. 5-7d Monomers with Triple Bonds

We have shown that {ro:, Po:} and {A(k,t), H(k,t)} are canonical variables. Therefore, their fundamental Poisson brackets9 are given by [240]





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Alkynes have been polymerized using ionic and radical initiators, but the polymer molecular weights are low. High molecular weights are obtained by using Ziegler Natta coordination catalysts (Sec. 8-4d-2) [Chien et al., 1980]. The polymers are of considerable interest in terms of their potential as (semi)conducting materials.

(ro:,i, P{3,j) = t5o:{3 t5ij , (A (k, t), lI;,(k', t)) = 15 ,15 (k - k') ,

5-140

Nitriles have been polymerized by radical and ionic initiators. The polymer structures are often quite complex, although anionic polymerization yields the cleanest reaction [Wohrle, 1972, 1983; Wohrle and Knothe, 1988].

(5.112)

5-141

(5.113)

=AND(logical1,logical2,...)

Polymerization of isocyanides to polyiminomethylenes is best achieved with cationic initiators, although anionic and radical polymerizations also occur [Millich, 1988].

with all other Poisson brackets involvi.ng pairs of these variables vanishing. We can quantize the theory making the correspondence discussed in 2 between the Poisson brackets and the quantum commutators, that is,

5-142

(5.114)

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Aida, T and S Inoue, Acc Chem Res, 29, 39 (1996) Alev, S, A Collet, M Viguier, and F Schue, J Polym Sci Polym Chem Ed, 18, 1155 (1980) Allen, C C, W Oraby, T M A Hossain, E P Stahel, D R Squire, and V T Stannett, J Appl Polym Sci, 18, 709 (1974) Allen, G and J C Bevington, Chain Polymerization I, in Comprehensive Polymer Science, Vol 3, G C Eastmond, A Ledwith, S Russo, and P Sigwalt, eds, Pergamon Press, New York, 1990 Allen, G, G Gee, and C Stretch, J Polym Sci, 48, 189 (1960) Alward, D B, D J Kinning, E L Thomas, and L J Fetters, Macromolecules, 19, 215 (1986) Antonietti, M, D Ehlich, K J Folsch, H Sillescu, M Schmidt, and P Lindner, Macromolecules, 22, 2802 (1989) Aoshima, S and T.

[ro:,i,p{3,jJ = iMo:{3 t5ij ,

Higashimura, Macromolecules, 22, 1009 (1989) Bahadur, M, T D Shaffer, and J R Ashbaught, Macromolecules, 33, 9548 (2000) Baird, M C, Chem Rev, 100, 1471 (2000) Balogh, L, L Wang, and R Faust, Macromolecules, 27, 3453 (1994) Baskaran, D, Prog Polym Sci, 28, 521 (2003) Berger, W and H-J Adler, Makromol Chem, 3, 301 (1986) Bhattacharyya, D N, J Smid, and M Szwarc, J Am Chem Soc, 86, 5024 (1964) Bhattacharyya, D N, C L Lee, J Smid, and M Szwarc, J Phys Chem, 69, 612 (1965a) Bhattacharyya, D N, J Smid, and M Szwarc, J Phys Chem, 69, 624 (1965b) Biddulph, R H and P H Plesch, J Chem Soc, 3913 (1960) Biswas, M and K J John, J Polym Sci Polym Chem Ed, 16, 3025 (1978) Biswas, M and G M A.

[A (k),1I1,(k')] =iM ,t5(k-k').

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