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a polymer that has an appropriate pendant group (usually a phenyl) (Wang et al., 1997a,b,c). The rst method is preferred for its simplicity and control of sequence distribution. The second takes advantage of commonly available starting materials, but may require more reaction steps. Many different backbones have been used as scaffolds for azo moieties, including imides (Agolini and Gay, 1970), esters (Anderle et al., 1989), urethanes (Furukawa et al., 1967), ethers (Bignozzi et al., 1999), organometallic ferrocene polymers (Liu et al., 1997), dendrimers (Junge and McGrath, 1997; Mekelburger et al., 1993), and even conjugated polydiacetylenes (Sukwattanasinitt et al., 1998), polyacetylenes (Teraguchi and Masuda, 2000), and main-chain azobenzenes (Izumi et al., 2000a,b). The most common azo polymers are acrylates (Morino et al., 1998), methacrylates (Altomare et al., 2001), and isocyanates (Tsutsumi et al., 1996). Thin lms are usually prepared by spincoating (Han and Ichimura, 2001; Blinov et al., 1998; Weh et al., 1998; Ichimura et al., 1996), although there are also many examples of using solvent evaporation, the Langmuir Blodgett technique (Silva et al., 2002; Razna et al., 1999; Jianhua et al., 1998; Seki et al., 1993), and self-assembled monolayers (Evans et al., 1998). Spin-cast lms are typically annealed above the polymer glass transition temperature (Tg) to remove residual solvent and erase any hydrodynamically induced anisotropy. Recently molecular glasses have been investigated as alternatives to amorphous polymer systems (Mallia and Tamaoki, 2003). These monodisperse systems appear to maintain the desirable photomotions and photoswitching properties, while allowing precise control of molecular architecture and thus material properties (Naito and Miura, 1993).



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necessary link bandwidth Once the reservations are in place, it is up to the routers in the Internet to actually provide the reserved bandwidth to the data flows This provisioning is done with the scheduling mechanisms (prirority scheduling, weighted fair queuing, etc) discussed in Section 66 It is also important to understand that RSVP is not a routing protocol -- it does not determine the links in which the reservations are to be made Instead it depends on an underlying routing protocol (unicast or multicast) to determine the routes for the flows Once the routes are in place, RSVP can reserve bandwidth in the links along these routes (We shall see shortly that when a route changes, RSVP rereserves resources) And once the reservations are in place, the routers' packet schedulers can actually provide the reserved bandwidth to the data flows Thus, RSVP is only one piece - albeit an important piece - in the QoS guaranteee puzzle RSVP is sometimes referred to as a signaling protocol By this it is meant that RSVP is a protocol that allows hosts to establish and tear-down reservations for data flows The term "signaling protocol" comes from the jargon of the circuit-switched telephony community





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The tilt rotor concept as demonstrated by the Bell/Boeing V-22 is a concept that has been under development for almost half a century with a view to combining the most advantageous characteristics of both xed and rotary wing aircraft Fixed wing aircraft are ef cient in the cruise con guration when the propulsion and aerodynamic con gurations are operating somewhere near to optimum conditions The disadvantage of xed wing aircraft is that their ight characteristics are far from optimum during the low speed take-off and landing special provisions such as aps, slats and other similar high lift devices are required to reduce aircraft speed to acceptable levels during these critical stages of ight Helicopters suffer from the reverse problem, being extremely effective for low or zero speed vertical landing and take-off but very limited for high speed cruise, due to rotor tip stall and other features of the rotary wing.

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transport the material by light, certain stiffness is necessary to prevent any relaxation of the induced relief structure The compromise between these opposite effects has to be found for effective grating formation Thermal treatment is only one of the possible ways to shift this equilibrium As expected, the gratings recorded in ionic materials are thermally very stable After heating the sample to 1001C, they remained stable with ZnormE90%, where Znorm=Zheated/Zrecorded Heating to 1501C erased the grating to ZnormE75%, but even after heating the sample to 2001C, ZnormE40% retained The grating could not be written again onto the thermally treated lm that may be explained by further sol gel condensation, which increases the rigidity of the matrix Thus the latter approach combines a very high ef ciency of SRG formation with a high stability of the induced surface structures provided by the simultaneously formed polymer network.

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Another example of the additional functionalization of the supramolecular material presents the H-bonded system, where the azobenzene moieties can be detached from the polymer chains and even removed from the lm (Zettsu et al, 2008) The removal of the strongly colored azobenzene derivative is of particular advantage for the applications such as liquid crystal alignment layer Chemical structure of the H-bonded complex is shown in Fig 24c The complex exhibited a single glass transition at 91C and complicated subsequent mesophase at temperatures up to 1091C In the temperature region of liquid crystalline phase, a smectic phase was formed Spin-coated lms of typical thickness, 50 nm, were prepared Very characteristic for the material was that the E Z photoisomerization caused the phase transition from the liquid crystalline phase to isotropic melt in the lm.

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