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Higashimura, Macromolecules, 20, 916 (1987) Schappacher, M and A Def eux, Macromolecules, 33, 7371 (2000) Schlaad, H, Y Kwon, L Sipos, and R Faust, Macromolecules, 33, 8225 (2000) Schmitt, B J and G V Schulz, Eur Polym J, 11, 119 (1975) Schubert, W and F Bandermann, Makromol Chem, 190, 2721 (1989) Schulz, R C, Polymerization of Acrolein, Chap 7 in Vinyl Polymerization, Vol 1, Part I, G E Ham, ed, Marcel Dekker, New York, 1967 Sharkey, W H, Adv Polym Sci, 17, 73 (1975) Shimomura, T, J Smid, and M Szwarc, J Am Chem Soc, 89, 5743 (1967a) Shimomura, T, K J Tolle, J Smid, and M Szwarc, J Am Chem Soc, 89, 796 (1967b) Shin, Y-D, S-Y Kim, J-H Ahn, and J-S Lee, Macromolecules, 34, 2408 (2001) Sigwalt, P, J Polym Sci.



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Symp, 50, 95 (1975) Smid, J, J Polym Sci Polym Chem Ed, 40, 2101 (2002) Sogah, D Y and O W Webster, Macromolecules, 19, 1775 (1986) Sogah, D Y, W R Hertler, O W Webster, and G M Cohen, Macromolecules, 20, 1473 (1987) Sogah, D Y, W R Hertler, I B Dicker, P A DePra, and J R Butera, Makromol Chem Macromol Symp, 32, 75 (1990) Souel, T, F Schue, M Abadie, and D H Richards, Polymer, 18, 1293 (1977) Soum, A, M Fontanille, and P Sigwalt, J Polym Sci Polym Chem Ed, 15, 659 (1977) Spach, G, M Levy, and M Szwarc, J Chem Soc, 355 (1962) Stannett, V T, V H Garreau, C C Ma, J M Rooney, and D R Squire, J Polym Sci Symp, 56, 233 (1976) Stannett, V T, J.





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Looking at (283), we can see that unlike the infinite string, there are no traveling waves, only a standing wave 23 This happens because the ends of the string are fixed and reflect back the waves Moreover, there is now a sin(wL/v) in the denominator of the second term in (283) When this sine vanishes, the displacement actually becomes infinite This happens for wL/v = mr, where n is an integer These frequencies Wn = (1r / L )nv are the resonance frequencies of our one-dimensional resonator We have seen that the confinement makes the resonances appear Being resonant to specific discrete frequencies is a very important characteristic of resonators It is so important that it gave them their name The second important feature is the specific field patterns that form inside the resonator when it vibrates at one of its resonance frequencies (ie, the modes).

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Silverman, and J L Garnett, Polymerization by High-Energy Radiation, pp 317 336 in Comprehensive Polymer Science, Vol 4, G C Eastmond, A Ledwith, S Russo, and P Sigwalt, eds, Pergamon Press, London, 1989 Starr, J and O Vogl, Makromol Chem, 179, 2621 (1978); J Polym Sci Polym Chem Ed, 17, 1923 (1979) Steinbrecht, K and F Bandermann, Makromol Chem, 190, 2183 (1989) Storey, R F and A B Donnalley, Macromolecules, 33, 53 (2000) Stretch, C and G Allen, Polymer, 2, 151 (1961) Subira, F, G Sauvet, J P Vairon, and P Sigwalt, J Polym Sci Symp, 56, 221 (1976) Subira, F, J P Vairon, and P Sigwalt, Macromolecules, 21, 2339 (1988) Sudo, A and T Endo, J Polym Sci Polym Chem Ed, 40, 3103 (2002) Sugimoto, H and S Inoue, Adv Polym Sci, 146, 39 (1999) Szwarc, M, Adv Polym.

Unfortunately, we cannot see these patterns using (283), as this solution diverges when the driving force vibrates at one of the resonator resonances In practice, the displacement can become very large but never really diverges because of damping Real resonators are never perfect and always let the fields leak a bit from their interior (or even absorb them a little), which leads to the damping of the vibrations We could introduce damping, as is often done in textbook treatments of the harmonic oscillator, for example However, then the field patterns that we would see would not correspond to a mode of a perfect resonator, which clearly show the ideas we are discussing, but to a more complicated sort of mode We discuss damping in resonators later (you will get a flavor of it in 6 and a more detailed discussion will be given in 9).

Sci, 2, 275 (1960); Acc Chem Res, 2, 87 (1969); Adv Polym Sci, 49, 1 (1983); Makromol Chem, 190, 567 (1989) Szwarc, M, Carbanions, Living Polymers, and Electron-Transfer Processes, Wiley-Interscience, New York, 1968..

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